CAS: 25168-26-7; 6-Methylheptyl 2-(2,4-Dichlorophenoxy)Acetate

该化合物是一种高效的除草剂,广泛用于大叶杂草的紧急后控制,具有极强的稳定性和持久性,在农业和非农业环境中提供长期的除草控制,其低波动性和最小的环境影响使它成为可持续作物管理的首选选择.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

2,4-滴丁酯 Butyl 2,4-Dichlorophenoxyacetate 94-80-4
2,4-二氯苯氧乙酸异丙酯 Amchem Weed Killer 650 94-11-1
2,4-二氯苯氧乙酸甲酯 Methyl 2,4-Dichlorophenoxyacetate 1928-38-7
N-Butyl Phenoxyacetate 32001-59-5

合成工艺路线路线简述

    📜C7-9-烷基醇置于硫酸,Potassium Hydroxide体系中,用 水 用作溶剂,化学反应 4.5H,反应生成2,4-二氯苯氧乙酸异辛酯
    参考文献:一种2,4-二氯苯氧乙酸的制备方法
    标题:一种2,4-二氯苯氧乙酸的制备方法
    摘要:本发明提供了一种2,4‑二氯苯氧乙酸的制备方法,包括以下步骤,首先将醇和卤代乙酸反应后,得到卤代乙酸酯;将2,4‑二氯酚与碱反应后,得到2,4‑二氯酚盐;然后将上述步骤得到的卤代乙酸酯与2,4‑二氯酚盐进行反应,得到2,4‑二氯苯氧乙酸酯;再将上述步骤得到的2,4‑二氯苯氧乙酸酯进行水解反应,得到2,4‑二氯苯氧乙酸和醇;最后将上述步骤得到的醇回用于前述步骤,循环利用;所述醇为c原子数大于等于2的醇.本发明调整工艺路线,从基础上进行改进,反应过程清洁,产生的废水量少,水解副产物少,产品纯度高,转化率和收率较高;而且过程原料可循环利用,适合大规模工业化生产.

    海关参考信息

    专利信息


    专利号:US-9999223-B2
    优先权日:2008-05-21
    标 题 :Herbicidal composition comprising glyphosate, glufosinate or their salts
    发明人:SIEVERNICH BERND; MOBERG WILLIAM KARL; SIMON ANJA; WALTER HELMUT; EVANS RICHARD R
    权利人:BASF SE
    摘要:The present invention relates to a herbicidal composition which comprises:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, and b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone]. nn The present invention relates in particular to a herbicidal composition comprising:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone], and c) at least one further herbicide C, which is selected from the herbicide groups C.1 to C.8:n C.1 herbicides of the group of acetolactate synthase inhibitors (ALS inhibitors), C.2 herbicides of the group of protoporphyrinogen oxidase inhibitors (PPO inhibitors), C.3 herbicides of the group of auxines, C.4 herbicides of the group of 4-hydroxyphenyl-pyruvate-dioxygenase inhibitors (HPPD inhibitors), C.5 herbicides of the group of phytoene desaturase inhibitors (PDS inhibitors), C.6 herbicides of the group of photosystem II inhibitors (PSII inhibitors), C.7 herbicides of the group of microtubulin inhibitors, and C.8 herbicides of the group of inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors).

    专利号:CN-118179061-A
    优先权日:2024-03-18
    标题:A system and method for continuous synthesis of 2,4-dichlorophenoxyacetic acid isooctyl ester

    专利号:US-10506809-B2
    优先权日:2015-01-15
    标 题:Herbicidal combination comprising saflufenacil and glufosinate
    发明人:MASSA DARIO; EVANS RICHARD; WITSCHEL MATTHIAS; SEISER TOBIAS; LIEBL REX; FRATESCHI ALEXANDRE
    权利人:BASF SE
    摘要:The present invention relates to a herbicidal combination which comprises:n a) a herbicide A which is 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)-pyrimidinyl]-4-fluoro-N-[[methyl-(1-methylethyl)-amino]sulfonyl]benzamide, b) a herbicide B which is glufosinate or one of its salts, and c) at least one herbicide C different from herbicides A and B which is selected fromn C.1) herbicides of the group of acetolactate synthase inhibitors which are selected from the group of triazolopyrimidine herbicides, sulfonylamino-carbonyl-triazolinone herbicides and pyrimidinyl(thio) benzoate herbicides, C.2) herbicides of the group of protoporphyrinogen oxidase inhibitors, C.3) herbicides of the group of synthetic auxins, C.4) herbicides of the group of microtubule inhibitors, C.5) herbicides of the group of acetyl-CoA carboxylase inhibitors, C.6) herbicides of the group of photosystem II inhibitors, C.7) herbicides of the group of pigment synthesis inhibitors, and C.8) herbicides of the group of VLCFA inhibitors which are selected from the group of oxyacetamide herbicides and chloroacetamide herbicides.

    专利号:CN-120329192-A
    优先权日:2025-03-03
    标题:Continuous synthesis process of isooctyl 2, 4-dichlorophenoxyacetate

    专利号:CN-106242971-A
    优先权日:2016-08-04
    标 题 :A kind of aqueous phase synthesis technology of chloroacetate and its new method for preparing 2,4-D ester

    专利号:CN-106242971-B
    优先权日:2016-08-04
    标题:A kind of aqueous phase synthesis technology of chloroacetate and new method for preparing 2,4-D ester

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Yu H, Cui H, Chen J, Chen P, Ji M, Huang S, Li X. Regulation of 2,4-D Isooctyl Ester on Triticum aestivum and Aegilops tauschii Tillering and Endogenous Phytohormonal Responses. Front Plant Sci. 2021 Apr 28;12:642701. doi: 10.3389/fpls.2021.642701.
    2: Yu H, Huang S, Chen P, Ji M, Cui H, Chen J, Li X. Different leaf-mediated deposition, absorbed and metabolism behaviors of 2,4-D isooctyl ester between Triticum aestivum and Aegilops tauschii Coss. Pestic Biochem Physiol. 2021 Jun;175:104848. doi: 10.1016/j.pestbp.2021.104848. Epub 2021 Apr 2.
    157:70-78. doi: 10.1016/j.plaphy.2020.10.013. Epub 2020 Oct 17. 68(15):4315-4324. doi: 10.1021/acs.jafc.0c00193. Epub 2020 Mar 31. 184(7):4247-51. doi: 10.1007/s10661-011-2259-4. Epub 2011 Aug 4. 55(3):338-43. doi: 10.1016/s0147-6513(02)00131-8. 29(3):237-45. doi: 10.1080/15287399009531387. Erratum in: J Toxicol Environ Health 1991 Jan;32(1):107-8. 50(8):438-46. doi: 10.1080/15298668991374949. 31(3):203-18. doi: 10.1016/0048-9697(83)90077-3. 2(2):65-74. doi: 10.1007/BF01684146.

    合成参考文献


    参考文献:10.1038/ncb3255
    摘要:Lin R, Elf S, Shan C, Kang HB, Ji Q, Zhou L, Hitosugi T, Zhang L, Zhang S, Seo JH, Xie J, Tucker M, Gu TL, Sudderth J, Jiang L, Mitsche M, DeBerardinis RJ, Wu S, Li Y, Mao H, Chen PR, Wang D, Chen GZ, Hurwitz SJ, Lonial S, Arellano ML, Khoury HJ, Khuri FR, Lee BH, Lei Q, Brat DJ, Ye K, Boggon TJ, He C, Kang S, Fan J, Chen J. 6-Phosphogluconate dehydrogenase links oxidative PPP, lipogenesis and tumour growth by inhibiting LKB1-AMPK signalling. Nat Cell Biol. 2015 Nov;17(11):1484–96.
    摘要:Fundamental and Applied Toxicology., 9(423), 1987
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