CAS: 13818-75-2; Gadolinium(Iii) Bromide

该化合物是一种无机化合物,由,稀土元素和溴组成,一般是白色或非白色晶状固体.GdBr3以其血压特征而著称,这意味着它可以吸收空气中的湿度,从而影响其稳定性和处理能力.该化合物在水和极地溶剂中溶解,使其在各种化学应用中有用.由于有,它具有未受污染的氟化铀,因此具有有趣的磁性,有助于其在磁共振成像和其他技术应用中的潜在用途.此外,GdBr3可用于合成其他基化合物和材料.必须谨慎地处理该物质,因为加丁基亚化铀化合物如果被浸入或吸入,可能会对健康造成危害,而且应在实验室或工业环境中使用适当的安全措施.

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上下游产品

hydrogen bromide bromine disulfur dichloride aluminium bromide6H5C3N2(CH3)2ONHC°CH3)2Br3Gd(C6H5C3N2(CH3)2ONHC°CH3)2Br3 gadolinium(III) bromide hexahydrate Gd(III)(dibenzylsulphoxide)5(bromide)3 17H17N2)GdBr2(C4H8O)2}{(C17H17N2)GdBr2(C4H8O)2}

合成工艺路线路线简述

    📜Gadolinium(III) Oxide置于氢溴酸体系中,用 水 用作溶剂,化学反应生成溴化钆(III)
    参考文献:硝酸盐和硫氰酸盐对g离子水溶液发光的猝灭
    标题:硝酸盐和硫氰酸盐对g离子水溶液发光的猝灭
    摘要:发现硝酸sex和硫氰酸根强烈淬灭了g金属离子最低六边形的发射.研究了离子强度,温度,粘度和强络合剂(如edta)的影响.淬灭是通过电子交换能量转移机制发生的.
    Doi:10.1039/f19898502605

    专利信息


    专利号:US-9777022-B2
    优先权日:2012-10-02
    标题 :Process for the preparation of macrocyclic polyazacarboxylate ligands and chelates
    发明人:MOORE DENNIS A; RAJAGOPALAN RAGHAVAN
    权利人:MALLINCKRODT LLC; GUERBET SA
    摘要:The present disclosure relates generally to a process for the synthesis of 1,4,7,10-tetraazacyclododecane ligands, chelates, and derivatives thereof. In particular, the present disclosure is directed to a process for the synthesis of 1,4,7,10-tetraaza-1,4,7,10-tetrakis(carboxymethyl)cyclododecane (DOTA) ligands, corresponding DOTA-metal chelates, and various derivatives thereof.

    专利号:US-7485741-B2
    优先权日:2002-12-02
    标 题:Method of producing nitrile compounds from ethylenically-unsaturated compounds
    发明人:BOURGEOIS DAMIEN; GALLAND JEAN-CHRISTOPHE; DIDILLON BLAISE; MARION PHILIPPE
    权利人:RHODIA POLYAMIDE INTERMEDIATES
    摘要:The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.

    专利号:US-12209104-B1
    优先权日:2018-07-11
    标 题:Metal complexes and methods of making the same
    发明人:KIPLINGER JAQUELINE; BEATTIE ROSS; PAGANO JUSTIN; ERICKSON KARLA
    权利人:TRIAD NAT SECURITY LLC
    摘要:Disclosed herein are embodiments of metal complexes and methods of making the same. The disclosed method embodiments provide a one-step approach to making metal complexes, such as complexes comprising lanthanide metals, rare earth metals, transition metals, main group metals, and/or actinide metals that can be used various applications, such as in separations technology, catalysis (e.g., catalysts for pharmaceutical synthesis and/or catalysts for biomass conversion), nuclear chemistry, LED phosphors, scintillator materials, magnetic materials, and nuclear fuels.

    专利号:US-2023212024-A1
    优先权日:2020-04-14
    标 题:New lithium rare-earth halides
    发明人:BRAIDA MARC-DAVID
    权利人:SOLVAY
    摘要:The present invention concerns new lithium rare earth halides that may be used as solid electrolytes or in electrochemical devices. The invention also refers to wet and dry processes for the synthesis of such lithium rare earth halides and lithium rare earth halides susceptible to be obtained by these processes.

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    合成参考文献


    参考文献:10.1134/s0020168517070147
    摘要:Ryumin MA, Sazonov EG, Guskov VN, Gagarin PG, Khoroshilov AV, Guskov AV, Gavrichev KS, Baldaev LK, Mazilin IV, Golushina LN. Thermodynamic properties of GdTaO4. Inorganic Materials. 2017 Jun 22;53(7):728–33. doi: 10.1134/s0020168517070147.
    参考文献:10.1007/10529543_3
    摘要:Graner G, Hirota E, Iijima T, Kuchitsu K, Ramsay DA, Vogt J, Vogt N. 2 Inorganic Molecules. Part 1. . In: Landolt-Börnstein - Group II Molecules and Radicals.
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