专利号:US-7485741-B2 优先权日:2002-12-02 标 题:Method of producing nitrile compounds from ethylenically-unsaturated compounds 发明人:BOURGEOIS DAMIEN; GALLAND JEAN-CHRISTOPHE; DIDILLON BLAISE; MARION PHILIPPE 权利人:RHODIA POLYAMIDE INTERMEDIATES 摘要:The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.
专利号:US-12209104-B1 优先权日:2018-07-11 标 题:Metal complexes and methods of making the same 发明人:KIPLINGER JAQUELINE; BEATTIE ROSS; PAGANO JUSTIN; ERICKSON KARLA 权利人:TRIAD NAT SECURITY LLC 摘要:Disclosed herein are embodiments of metal complexes and methods of making the same. The disclosed method embodiments provide a one-step approach to making metal complexes, such as complexes comprising lanthanide metals, rare earth metals, transition metals, main group metals, and/or actinide metals that can be used various applications, such as in separations technology, catalysis (e.g., catalysts for pharmaceutical synthesis and/or catalysts for biomass conversion), nuclear chemistry, LED phosphors, scintillator materials, magnetic materials, and nuclear fuels.
[参考文献]: Tom Vander Hoogerstraete, Et Al. Homogeneous Liquid-Liquid Extraction Of Rare Earths With The Betaine-Betainium Bis(Trifluoromethylsulfonyl)Imide Ionic Liquid System. Int J Mol Sci. 2013 Oct 28;14(11):21353-77.
合成参考文献
参考文献:10.1007/s10973-025-14461-9 摘要:Salamon-Baran B, Kapała J, Rycerz L. The dissolution enthalpy at 298.15 K of intermediate compounds in LnBr3-MBr systems: CALPHAD reassessment of thermodynamics of LnBr3-MBr systems (Ln = Ce, Pr, M = K-Cs). J Therm Anal Calorim. 2025 Jul 08;150(24):19989–20000. doi: 10.1007/s10973-025-14461-9.