异丁醇置于吡啶,三氯氧磷体系中,化学反应生成磷酸三异丁酯 参考文献:Act系元素-磷酸三烷基酯配合物的小角中子散射趋势:分子对第三相形成的洞察力 标题:Act系元素-磷酸三烷基酯配合物的小角中子散射趋势:分子对第三相形成的洞察力 摘要:溶剂萃取中的"第三相"形成现象是由于萃取物种的聚集和反胶束的形成.由于小角中子散射(sans)是探测胶体颗粒的强大工具,因此被认为是研究solvent系化合物在溶剂萃取系统中的聚集行为的重要技术.锕特定磷酸三烷基酯(talp)基于萃取剂,即,三-ñ丁基磷酸酯(tbp),三异丁基磷酸酯(tibp),三-仲-丁基磷酸盐(tsbp)和三-仲-磷酸戊酯(tsap)首次使用sans技术进行了研究,以研究某些act系元素的第三相形成现象.使用sans来深入了解通过氘代十二烷中的1.1 M Talp溶液从1 M Hno 3萃取th(iv)和u(vi)(n-C 12 D 26,98原子%d).为了在中子散射测量过程中提供对比,使用了氘化稀释剂.在上述溶剂体系中形成的反胶束的势能和粘性参数已根据有机金属负载量进行了量化.使用巴克斯特的粘性球模型拟合数据.量化胶束之间的吸引力相互作用的量度(τ-1)以及吸引力势能(u Doi:10.1039/c6Ra20175J
专利号:US-7241399-B2 优先权日:2000-09-08 标题 :Synthesis of nanoparticles 发明人:HAUBOLD STEPHAN; HAASE MARKUS; RIWOTZKI KARSTEN; WELLER HORST; MEYSSAMY HEIKE; IBARRA FERNANDO 权利人:CT ANGEWANDTE NANOTECH CAN 摘要:Methods for the preparation of inorganic nanoparticles capable of fluorescence, wherein the nanoparticles consist of a host material that comprises at least one dopant. The synthesis of the invention in organic solvents allows to gain a considerably higher yield compared to the prior art synthesis in water. All kinds of objects can advantageously be marked and reliably authenticated by using an automated method on the basis of a characteristic emission. Further, the size distribution of the prepared nanoparticles is nartower which renders a subsequent size-selected separation process superfluous.
专利号:EP-1232226-B1 优先权日:2000-09-08 标题:Synthesis of nanoparticles 发明人:HAUBOLD STEPHAN; HAASE MARKUS; RIWOTZKY CARSTEN; WELLER HORST; MEYSAMMY HEIKE; IBARRA FERNANDO 权利人:NANOSOLUTIONS GMBH 摘要:Production of inorganic nanoparticles that can be fluoresced consisting of a host material containing a dopant comprises using an organic solvent for liquid phase synthesis of the particles.
专利号:US-5670465-A 优先权日:1993-01-08 标题 :Preparation of p-fuchsones and synthesis of p-dihydroxylated aromatic compounds therefrom 发明人:COSTANTINI MICHEL; MANAUT DANIEL; MICHELET DANIEL 权利人:RHONE POULENC CHIMIE 摘要:p-Dihydroxylated aromatic compounds are prepared via the oxidation of p-fuchsones, the latter advantageously being synthesized by reacting a phenolic compound having at least one hydrogen atom in the para-position to the hydroxyl function with a non-enolizable ketonic compound, in the presence of a catalytically effective amount of an acid catalyst and, optionally, a cocatalytically effective amount of an ionizable sulfur-containing compound.
专利号:US-2003032192-A1 优先权日:2000-09-08 标题 :Synthesis of nanoparticles
专利号:EP-1707611-A2 优先权日:2000-09-08 标 题 :Synthesis of nanoparticles
专利号:CN-215655166-U 优先权日:2021-09-16 标 题 :Stirring kettle for synthesis of triisobutyl phosphate
参考文献:10.1007/s00216-004-2760-5 摘要:Isetun S, Nilsson U, Colmsjö A. Evaluation of solid-phase microextraction with PDMS for air sampling of gaseous organophosphate flame-retardants and plasticizers. Analytical and Bioanalytical Chemistry. 2004 Aug 07;380(2):319–24. doi: 10.1007/s00216-004-2760-5.