合成目标产物 Trans-Stilbene 主要起始原料 Benzyl Bromide And Benzaldehyde
(文献来源)合成步骤主要原料 Benzyl Bromide 和 Benzaldehyde
📜苯甲醛吖嗪 反应生成反式-1,2-二苯乙烯 参考文献:The Thermal Decomposition Of Azines: A Note On The Thermal Decomposition Of Benzaldazine Under 1000 Atmospheres Pressure Of Nitrogen,Hydrogen And Ammonia 标题:The Thermal Decomposition Of Azines: A Note On The Thermal Decomposition Of Benzaldazine Under 1000 Atmospheres Pressure Of Nitrogen,Hydrogen And Ammonia 摘要: Doi:10.1021/ja01348A020
专利信息
专利号:US-6794534-B2 优先权日:2000-06-23 标题:Synthesis of functionalized and unfunctionalized olefins via cross and ring-closing metathesis 发明人:GRUBBS ROBERT H; CHATTERJEE ARNAB K; MORGAN JOHN P; SCHOLL MATTHIAS; CHOI TAE-LIM 权利人:CALIFORNIA INST OF TECHN 摘要:The invention is directed to the cross-metathesis and ring-closing metathesis reactions between geminal disubstituted olefins and terminal olefins, wherein the reaction employs a Ruthenium or Osmium metal carbene complex. Specifically, the invention relates to the synthesis of α-functionalized or unfunctionalized olefins via intermolecular cross-metathesis and intramolecular ring-closing metathesis using a ruthenium alkylidene complex. The catalysts preferably used in the invention are of the general formula n wherein: n M is ruthenium or osmium; n X and X 1 are each independently an anionic ligand; n L is a neutral electron donor ligand; and, n R, R 1 R 6 , R 7 , R 8 , and R 9 are each independently hydrogen or a substituent selected from the group consisting of C 1 -C 20 alkyl, C 2 -C 20 alkenyl, C 2 -C 20 alkynyl, aryl, C 1 -C 20 carboxylate, C 1 -C 20 alkoxy, C 2 -C 20 alkenyloxy, C 2 -C 20 alkynyloxy, aryloxy, C 2 -C 20 alkoxycarbonyl, C 1 -C 20 alkylthio, C 1 -C 20 alkylsulfonyl and C 1 -C 20 alkylsulfinyl.
专利号:US-2014194584-A1 优先权日:2013-01-07 标题 :Process for the synthesis of w-Unsaturated nitrile-acid/ester in which two types of cross metathesis are alternated consecutively swing process 发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC 权利人:ARKEMA FRANCE 摘要:The invention relates to a process for the synthesis of a monounsaturated nitrile-ester (acid) by cross metathesis starting from an unsaturated compound I comprising at least one trivalent nitrile, acid or ester functional group, characterized in that it comprises a stage in which two types of cross metathesis are alternated consecutively:n a first type of cross metathesis cm1 with an acrylic compound II chosen from acrylonitrile, acrylic acid or an acrylic ester, one of the compounds I or II comprising a nitrile functional group and the other of these compounds II or I comprising an acid or ester functional group, and a second type of cross metathesis cm2 with a light C 2 to C 4 alkene compound III, preferably with ethylene. nn The invention also relates to a process for the synthesis of an α,ω-amino ester (acid) obtained by a process comprising a stage in which the two types of cross metathesis defined above are alternated consecutively, followed by a hydrogenation stage.
专利号:US-2003162992-A1 优先权日:2001-12-14 标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides 发明人:WATANABE KYOICHI A; DU JINFA 摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.
专利号:US-9382189-B2 优先权日:2013-02-08 标题:Synthesis of a branched unsaturated compound by means of cross metathesis 发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC 权利人:ARKEMA FRANCE 摘要:The invention relates to a method for the synthesis of a branched unsaturated fatty compound, said method comprising the metathesis, in the presence of a metathesis catalyst, of a linear unsaturated fatty compound and a branched olefin. The branched unsaturated fatty compound is used in particular for the production of at least one of the following products: dielectric fluids, specialty surfactants, emulsifiers, frictions agents, antistatic additives, antifogging additives, mould release agents, pigment dispersants, high-performance lubricants, waxes and wax emulsifiers, polymer conversion additives, PVC stabilizing agents, inks, resins, paints, varnishes, solvents, lipsticks, creams for the skin, deodorants, particularly stick deodorants, hair dyes, shampoos and other liquid soaps, shaving foam, laundry detergents, cleaning agents, fabric softeners, and mixtures of same.
专利号:WO-2012120543-A1 优先权日:2011-03-09 标 题 :A single step process for synthesis of yellow dye -11 of consistent colour tone 发明人:KULKARNI AMOL ARVIND; JOSHI RAMESH ANNA; JOSHI ROHINI RAMESH 权利人:COUNCIL SCIENT IND RES; KULKARNI AMOL ARVIND; JOSHI RAMESH ANNA; JOSHI ROHINI RAMESH 摘要:Yellow due 11 is a useful dye with several application in the industry. The available literature in the synthesis of this dye results in non uniform colour tone. This issue in prior art is addressed by disclosing a batch as well continuous single condensation step process for synthesizing the yellow dye 11 with on-line uv monitoring system to ensure colour tone uniformity.
专利号:WO-2024105686-A1 优先权日:2022-11-14 标 题 :A process for the synthesis of stilbene and intermediates thereof 发明人:KANUMURU RAHUL RAJU; KOCHUMALAYIL SHAJI GEORGE; SURANENI RAVIKUMAR; VANA MURALI MOHANARAO 权利人:FERTIS INDIA PVT LTD 摘要:The present invention discloses a process for the preparation of Stilbene such as Pterostilbene and Resveratrol. More particularly, the present invention discloses synthesis of Stilbene employing a novel intermediate, 5-(4-(1-ethoxyethoxy) styryl)-benzene 1,3 diol and 1-(4-(1-ethoxyethoxy) styryl)-3,5-dimethoxy- benzene.
参考文献:10.1007/s00216-010-3516-z 摘要:Knecht MR, Pacardo DB. Employing high-resolution materials characterization to understand the effects of Pd nanoparticle structure on their activity as catalysts for olefin hydrogenation. Analytical and Bioanalytical Chemistry. 2010 Feb 16;397(3):1137–55. doi: 10.1007/s00216-010-3516-z. 参考文献:10.1007/s00394-011-0227-y 摘要:Duchnowicz P, Broncel M, Podsędek A, Koter-Michalak M. Hypolipidemic and antioxidant effects of hydroxycinnamic acids, quercetin, and cyanidin 3-glucoside in hypercholesterolemic erythrocytes (in vitro study). European Journal of Nutrition. 2011 Jul 14;51(4):435–43. doi: 10.1007/s00394-011-0227-y. 参考文献:10.1007/s00425-011-1474-0 摘要:Hall D, Kim KH, De Luca V. Molecular cloning and biochemical characterization of three Concord grape (Vitis labrusca) flavonol 7-O-glucosyltransferases. Planta. 2011 Dec;234(6):1201–14. doi: 10.1007/s00425-011-1474-0.