专利号:US-9580323-B2 优先权日:2013-05-31 标题 :Method of producing graphene and other carbon materials 发明人:MUKASYAN ALEXANDER; MANUKYAN KHACHATUR 权利人:MUKASYAN ALEXANDER; MANUKYAN KHACHATUR; UNIV NOTRE DAME DU LAC 摘要:The invention provides methods for the combustion synthesis (CS) of graphene by a novel exothermic self-sustained reaction between a refractory ceramic compound and a carbon-containing polymer under an inert gas atmosphere. The synthesis of graphene was confirmed by both transmission electron microscopy and Raman spectroscopy. The graphene produced has very low (<1 wt. %) oxygen content. Fluorocarbon gases released due to decomposition of the carbon-containing polymer in the combustion wave can reduce the ceramic to a gas and mesoporous carbon particles and graphene layers. The method does not require an external energy source because it occurs in a self-sustained synergetic manner after ignition. The methods are flexible in terms of tuning the synthesis conditions for desired products, and the method can be scaled to provide kilogram quantities.
专利号:US-6956142-B2 优先权日:2003-12-15 标 题 :Process for eco-friendly synthesis of bromobenzene 发明人:BEDEKAR ASHUTOSH VASANT; GHOSH KUMAR PUSHPITO; ADIMURTHY SUBBARAYYAPPA; RAMACHANDRAIAH GADDE 权利人:CENTRAL SALT AND MARINE CHEMIC 摘要:A new eco-friendly process is described in the present invention for the preparation of bromobenzene through substitution of one of the C—H proton of benzene ring with a highly reactive hypobromous acid generated in situ, said process comprises the steps of activating a water soluble, easy to handle, brominating reagent with a mineral acid at elevated temperature and atmospheric pressure to generate active bromine species which in turn reacts with benzene.
专利号:US-2005137431-A1 优先权日:2003-12-15 标题:Process for eco-friendly synthesis of bromobenzene
专利号:US-2014377160-A1 优先权日:2013-05-31 标题 :Combustion synthesis of graphene and carbonous nanomaterials
专利号:AU-2003288582-A1 优先权日:2003-12-15 标 题:A process for eco-friendly synthesis of bromobenzene
专利号:AU-2003288582-B2 优先权日:2003-12-15 标题:A process for eco-friendly synthesis of bromobenzene
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合成参考文献
参考文献:10.1021/es201850n 摘要:Möller A, Xie Z, Cai M, Zhong G, Huang P, Cai M, Sturm R, He J, Ebinghaus R. Polybrominated diphenyl ethers vs alternate brominated flame retardants and Dechloranes from East Asia to the Arctic. Environ Sci Technol. 2011 Aug 15;45(16):6793–9. doi: 10.1021/es201850n.