CAS: 87-82-1; Hexabromobenzene

该化合物是一种溴化芳香化合物,主要用作各种工业应用中的阻燃剂,其高溴含量(按重量计约为86%)通过阻断天然气阶段的自由激进链反应,有助于有效抑制燃烧;该化合物具有热稳定性和低挥发性,适合高温工艺;通常用于聚合物,纺织品和电子部件,以提高防火性;六溴苯还被用作其他溴化化合物合成的中间体;由于其持久性和潜在的环境关切,处理和处置必须遵守严格的监管准则.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号106-37-6 对二溴苯 | CAS号71-43-2 苯 | CAS号584-48-5 1-溴-2,4-二硝基苯 | CAS号93-89-0 苯甲酸乙酯 | CAS号119-61-9 二苯甲酮 | CAS号65-85-0 苯甲酸 | CAS号101-81-5 二苯甲烷 | CAS号22230-42-8 2,3,4,5,6-penta... | CAS号78903-36-3 pentabromobenza... | CAS号98-95-3 硝基苯 | CAS号100516-61-8 1,2,3,4,5,6-hex... | CAS号992-04-1 六苯基苯 | CAS号87-85-4 六甲基苯 | CAS号7789-66-4 四溴化硅 | CAS号13465-75-3 dibromo(dichlor... | CAS号13465-74-2 Bromotrichlorosilane | CAS号13465-76-4 tribromo(chloro... | CAS号118-75-2 四氯对醌 | CAS号636-28-2 1,2,4,5-四溴苯 | CAS号608-71-9 五溴苯酚

合成工艺路线路线简述

    📜二苯甲酮置于aluminum Tri-Bromide,溴体系中,化学反应 3.0H,以10%的收率获得产物六溴苯
    参考文献:Golounin,A. V.; Shukhta,T. K.; Kirienko,E. K.,Russian Journal Of Applied Chemistry,1994,Vol. 67,# 8.2,P. 1167-1169
    标题:Golounin,A. V.; Shukhta,T. K.; Kirienko,E. K.,Russian Journal Of Applied Chemistry,1994,Vol. 67,# 8.2,P. 1167-1169

    专利信息


    专利号:US-9580323-B2
    优先权日:2013-05-31
    标题 :Method of producing graphene and other carbon materials
    发明人:MUKASYAN ALEXANDER; MANUKYAN KHACHATUR
    权利人:MUKASYAN ALEXANDER; MANUKYAN KHACHATUR; UNIV NOTRE DAME DU LAC
    摘要:The invention provides methods for the combustion synthesis (CS) of graphene by a novel exothermic self-sustained reaction between a refractory ceramic compound and a carbon-containing polymer under an inert gas atmosphere. The synthesis of graphene was confirmed by both transmission electron microscopy and Raman spectroscopy. The graphene produced has very low (<1 wt. %) oxygen content. Fluorocarbon gases released due to decomposition of the carbon-containing polymer in the combustion wave can reduce the ceramic to a gas and mesoporous carbon particles and graphene layers. The method does not require an external energy source because it occurs in a self-sustained synergetic manner after ignition. The methods are flexible in terms of tuning the synthesis conditions for desired products, and the method can be scaled to provide kilogram quantities.

    专利号:US-6956142-B2
    优先权日:2003-12-15
    标 题 :Process for eco-friendly synthesis of bromobenzene
    发明人:BEDEKAR ASHUTOSH VASANT; GHOSH KUMAR PUSHPITO; ADIMURTHY SUBBARAYYAPPA; RAMACHANDRAIAH GADDE
    权利人:CENTRAL SALT AND MARINE CHEMIC
    摘要:A new eco-friendly process is described in the present invention for the preparation of bromobenzene through substitution of one of the C—H proton of benzene ring with a highly reactive hypobromous acid generated in situ, said process comprises the steps of activating a water soluble, easy to handle, brominating reagent with a mineral acid at elevated temperature and atmospheric pressure to generate active bromine species which in turn reacts with benzene.

    专利号:US-2005137431-A1
    优先权日:2003-12-15
    标题:Process for eco-friendly synthesis of bromobenzene

    专利号:US-2014377160-A1
    优先权日:2013-05-31
    标题 :Combustion synthesis of graphene and carbonous nanomaterials

    专利号:AU-2003288582-A1
    优先权日:2003-12-15
    标 题:A process for eco-friendly synthesis of bromobenzene

    专利号:AU-2003288582-B2
    优先权日:2003-12-15
    标题:A process for eco-friendly synthesis of bromobenzene

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Anders Larsson, Et Al. Identification Of The Brominated Flame Retardant 1,2-Dibromo-4-(1,2-Dibromoethyl)Cyclohexane As An Androgen Agonist. J Med Chem. 2006 Dec 14;49(25):7366-72.
    [参考文献]: G Koss, Et Al. Metabolic Fate Of Hexabromobenzene In Rats. Toxicol Lett. 1982 Nov;14(1-2):69-77.
    [参考文献]: Hans Peter H Arp, Et Al. Presence And Partitioning Properties Of The Flame Retardants Pentabromotoluene, Pentabromoethylbenzene And Hexabromobenzene Near Suspected Source Zones In Norway. J Environ Monit. 2011 Mar;13(3):505-13.
    [参考文献]: I Watanabe, Et Al. Hexabromobenzene And Its Debrominated Compounds In River And Estuary Sediments In Japan. Bull Environ Contam Toxicol. 1986 May;36(5):778-84.
    [参考文献]: K D Courtney, Et Al. Teratogenic Evaluation And Fetal Deposition Of Hexabromobenzene (Hbb) And Hexafluorobenzene (Hfb) In Cd-1 Mice. J Environ Sci Health B. 1984 Feb;19(1):83-94.

    合成参考文献


    参考文献:10.1021/es201850n
    摘要:Möller A, Xie Z, Cai M, Zhong G, Huang P, Cai M, Sturm R, He J, Ebinghaus R. Polybrominated diphenyl ethers vs alternate brominated flame retardants and Dechloranes from East Asia to the Arctic. Environ Sci Technol. 2011 Aug 15;45(16):6793–9. doi: 10.1021/es201850n.
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