CAS: 17598-82-2; L-Tagatose

该化合物是一种自然形成的单沙律和氯代谢物,被归类为富集糖的缩皮,是一种在水中溶解并有甜味的白色晶状粉,大约92%的甜度与苏集糖一样,大约是苏集糖一样的甜度为92%.L-Tagatose的血糖指数较低,适合糖尿病饮食和各种食品中的糖替代物.它的化学配方是C6H12O6,以其前生特性著称,它促进有益的直肠细菌的生长.L-Tagatasose在热和酸性条件下保持稳定,能够用于烹饪和烘烤.此外,它受到某些细菌的发酵,有助于其潜在的健康利益.由于其独特的特性,L-Tagatose在食品工业中越来越受到关注,成为传统糖的更健康的替代物.

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CAS号608-66-2 卫矛醇 | CAS号60660-58-4 L-塔罗糖醇

合成工艺路线路线简述

    📜L-(-)-半乳糖置于d-Arabinose Isomerase From Thermanaeromonas Toyohensis体系中,用 Aq. Buffer 用作溶剂,化学反应 0.17H,反应生成L-塔格糖
    参考文献:来自丰隆产热单胞菌的新型 D-阿拉伯糖异构酶的表征及其在 D-核酮糖和 L-岩藻糖生产中的应用
    标题:来自丰隆产热单胞菌的新型 D-阿拉伯糖异构酶的表征及其在 D-核酮糖和 L-岩藻糖生产中的应用
    摘要:D-核酮糖和 L-岩藻糖是具有潜在价值的稀有糖,可用于农业和医药行业的抗癌和抗病毒药物.这些稀有糖通常通过化学方法生产,通常价格昂贵,复杂且不能满足日益增长的需求.此外,由于生物催化剂的短缺,用于生产 D-核酮糖和 L-岩藻糖的细菌来源的 D-阿拉伯糖和 L-岩藻糖通过 D-阿拉伯糖异构化和 L-岩藻糖的 D-阿拉伯糖和 L-岩藻糖异构化尚未实现工业化,导致产量低,生产成本高.在这项研究中,对来自丰水产热单胞菌的热稳定 D-核酮糖和 L-岩藻糖生产 D-阿拉伯糖异构酶进行了表征.来自 T 的重组 D-阿拉伯糖异构酶.Toyohensis (Thto-Daiase) 使用his-Trap 亲和层析纯化为 66 Kda 的单条带.天然酶以分子量为 310 Kda 的同源四聚体形式存在,观测到 D-阿拉伯糖和 L-岩藻糖的比活性分别为 98.08 和 85.52 U Mg-1.热稳定的重组 Thto-Daiase
    Doi:10.1016/j.Enzmictec.2019.109427

    海关参考信息

    专利信息


    专利号:US-5078796-A
    优先权日:1989-07-19
    标 题:Process for manufacturing tagatose
    发明人:BEADLE JAMES R; SAUNDERS JAMES P; WAJDA JR THOMAS J
    权利人:BIOSPHERICS INC
    摘要:A process is disclosed for the synthesis of D-tagatose by isomerizing a mixture containing D-galactose with a metal hydroxide in the presence of a catalyst at a relatively low temperature to form an intermediate metal hydroxide-D-tagatose complex, and then neutralizing the intermediate with acid to yield D-tagatose. The method is also suitable for the synthesis of L-tagatose from L-galactose, and for the recovery of pure tagatose from crude tagatose syrups. Whey, deproteinized whey, or lactose may be used as the raw material for the D-galactose. The lactose in such cases is hydrolyzed to D-galactose and D-glucose before the isomerization step.

    专利号:US-5002612-A
    优先权日:1989-07-19
    标题 :Process for manufacturing tagatose
    发明人:BEADLE JAMES R; SAUNDERS JAMES P; WAJDA JR THOMAS J
    权利人:BIOSPHERICS INC
    摘要:A process is disclosed for the synthesis of D-tagatose by isomerizing a mixture containing D-galactose with a metal hydroxide in the presence of a catalyst at a relatively low temperature to form an intermediate metal hydroxide-D-tagatose complex, and then neutralizing the intermediate with acid to yield D-tagatose. The method is also suitable for the synthesis of L-tagatose from L-galactose, and for the recovery of pure tagatose from crude tagatose syrups. Whey, deproteinized whey, or lactose may be used as the raw material for the D-galactose. The lactose in such cases is hydrolyzed to D-galactose and D-glucose before the isomerization step.

    专利号:CN-117143935-A
    优先权日:2023-09-09
    标 题:A method for whole-cell synthesis of D-ribose using the isomerase pathway using D-xylose as a substrate

    专利号:EP-3538239-A1
    优先权日:2016-11-11
    标 题 :Synthesis of d-allulose

    专利号:CN-110891937-A
    优先权日:2017-07-11
    标题 :Synthesis of azasugars and their intermediates

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Facile Enzymatic Synthesis Of Ketoses
    作者:Liuqing Wen,Kenneth Huang,Mohui Wei,Jeffrey Meisner,Yunpeng Liu,Kristina Garner,Lanlan Zang,Xuan Wang,Xu Li,Junqiang Fang,Houcheng Zhang,Peng George Wang |发布日期:2015.10.19
    摘要:Studies Of Rare Ketoses Have Been Hampered By A Lack Of Efficient Preparation Methods. A Convenient, Efficient, And Cost‐effective Platform For The Facile Synthesis Of Ketoses Is Described. This Method Enables The Preparation Of Difficult‐to‐access Ketopentoses And Ketohexoses From Common And Inexpensive Starting Materials With High Yield And Purity And Without The Need For A Tedious Isomer Separation

    合成参考文献


    参考文献:10.1007/s10529-010-0224-x
    摘要:Yeom SJ, Kim BN, Park CS, Oh DK. Substrate specificity of ribose-5-phosphate isomerases from Clostridium difficile and Thermotoga maritima. Biotechnol Lett. 2010 Jun;32(6):829–35. doi: 10.1007/s10529-010-0224-x.
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