CAS: 73918-56-6; Zh8651

上下游产品

4-溴苯乙基溴 1-Bromo-4-(2-Bromoethyl)Benzene 1746-28-7
1-(4-溴苯基)-2-硝基乙烷 1-(4-Bromophenyl)-2-Nitroethane 137521-07-4
4-溴苯乙醛 P-Bromophenylacetaldehyde 27200-79-9
对溴苯乙腈 4-Bromophenylacetonitrile 16532-79-9
对溴苯丙氨酸 P-Bromo-Dl-Phenylalanine 14091-15-7
N-Boc-2-四溴苯乙胺 T-Butyl 2-(4-Bromophenyl)Ethylcarbamate 120157-97-3

1-(4-溴苯基)-2-硝基乙烷置于samarium Diiodide,水,异丙胺体系中,用 四氢呋喃 作为反应溶剂,以60%的收率获得产物4-溴苯乙胺
参考文献:瞬时smi 2 / H2O /胺介导的硝基烷和α,β-不饱和硝基烯烃的还原
标题:瞬时smi 2 / H2O /胺介导的硝基烷和α,β-不饱和硝基烯烃的还原
摘要:已经开发出一种使用smi 2 / H2O /胺有效还原硝基链烷和α,β-不饱和硝基链烯的快速方法.
DOI:10.1016/j.Tetlet.2007.05.105

专利信息

专利号:US-7592392-B2
优先权日:2003-04-04
标 题 :Synthesis of functional polymers for use in organic synthesis and combinatorial chemistry
发明人：LINDSLEY CRAIG W; WISNOSKI DAVID D
权利人:MERCK & CO INC
摘要:The present invention relates to a novel process for the preparation of solid-supported scavenging reagents and solid-supported functional polymers. The invention further relates to novel solid-supported functional polymers and to their use in organic synthesis and combinatorial chemistry.

专利号:WO-0078740-A1
优先权日:1999-06-23
标 题 :Solid-supported initiators and functional polymers for use in organic synthesis and combinatorial chemistry
发明人：HARIKRISHNAN LALGUDI SANKARAN; HODGES JOHN COOKE; LINDSLEY CRAIG WILLIAM
权利人:WARNER LAMBERT CO; HARIKRISHNAN LALGUDI SANKARAN; HODGES JOHN COOKE; LINDSLEY CRAIG WILLIAM
摘要:Solid-supported initiator and functional polymers are described as well as methods for the preparation and use in solution phase, solid-phase organic synthesis, and combinational chemistry including use as initiators of solid-supported free-radical polymerization, as solid-supported scavengers for purification of crude solution phase reaction mixtures, as a stationary phase for solid-phase organic synthesis, and as solid-supported reagents in solution-phase organic synthesis.

专利号:US-2006189764-A1
优先权日:2003-04-04
标 题:Synthesis of functional polymers for use in organic synthesis and combinatorial chemistry

专利号:WO-2009017671-A1
优先权日:2007-07-26
标题 :Synthesis of inhibitors of 11beta-hydroxysteroid dehydrogenase type 1

专利号:US-2005080267-A1
优先权日:2001-09-12
标 题:Synthesis of enantiomerically pure amino-substituted fused bicyclic rings

专利号:EP-1487795-A2
优先权日:2001-09-12
标题 :Synthesis of enantiomerically pure amino-substituted fused bicyclic rings