CAS: 359803-53-5; 2-(Dimethylamino)-2-Biphenylyl-Palladium(Ii) Chloride Dinorbornylphosphine

该化合物是一种复杂的有机金属化合物,其特点是,一个与磷离子和双苯衍生物相协调的中心;该化合物的特点是,其独特的双环磷离心剂具有独特的双环特性,有助于其消化和电子特性,使之适合各种催化用途,特别是在交叉反应中.二甲基氨基化合物的存在可增强复合体的溶性和再活动.氯离心和二苯基表明,它可以参与离心和交换反应,这是化学的一个常见特征.

英文名称2-(Dimethylamino)-2-Biphenylyl-Palladium(Ii) Chloride Dinorbornylphosphine
中文名称氯-[2’-(二甲氨基)-2-联苯基]-(二去甲冰片基膦)-钯
IUPAC名称bis(2-bicyclo[2.2.1]heptanyl)phosphane;chloropalladium(1+);N,N-dimethyl-2-phenylaniline
其它别名Sk-Cc01-A; 2'-(Dimethylamino)-2-Biphenylyl-Palladium(Ii) Chloride Dinorbornylphosphine Complex; Chloro(Di-2-Norbornylphosphino)(2'-Dimethylamino-1,1'-Biphenyl-2-yl)Palladium; Chloro(Di-2-Norbornylphosphino)(2'-Dimethylamino-1,1'-Biphenyl-2-yl)Palladium(Ii); Chloro-[2'-(Dimethylamino)-2-Biphenylyl]-(Dinorbornylphosphine)-Palladium; 2'-(Dimethylamino)-2-Biphenylyl-Pd(Ii)-Cl Dinorbornylphosph.; Chloro(Di-2-Norbornylphosphino)(2'-Dimethylamino-1,1'-Biphenyl-2-yl)Palladium(Ii),min.; Sk-Cc01-A, Chloro-[2μ-(Dimethylamino)-2-Biphenylyl]-(Dinorbornylphosphine)-Palladium
CAS编号359803-53-5
MFCD编号:MFCD03427335
EINECS号:811-496-0
分子式:C28H36ClNPPd分子量:560.45
产品CID: 1368790
产品分类有机原料 → 有机金属类化合物 → 有机钯

相似结构搜索
InChIKey: DSRKYISBIPSOIL-UHFFFAOYNA-M
InChI=1S/C14H14N.C14H22P.ClH.Pd/c1-15(2)14-11-7-6-10-13(14)12-8-4-3-5-9-12;1-3-11-5-9(1)7-13(11)15-14-8-10-2-4-12(14)6-10;;/h3-8,10-11H,1-2H3;9-14H,1-8H2;1H;/q2*-1;;+3/p-
计算化学: 氢键受体数3.0氢键供体数*可旋转键数4.0

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H319-H315-H335
防范说明P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
UN编号NONH for all modes of transport
WGK Germany3

上下游产品

CAS号148432-44-4 二-2-降冰片基膦

合成工艺路线路线简述

合成目标产物 2'-(Dimethylamino)-2-Biphenylyl-Palladium(Ii) Chloride Dinorbornylphosphine Complex 主要起始原料 Di-2-Norbornylphosphine And Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
(文献来源)合成步骤主要原料 Di-2-Norbornylphosphine 和 Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-

专利信息

专利号:US-8288497-B2
优先权日:2008-02-27
标题 :Synthesis of poly-(P-aryleneethynylene)s in neat water under aerobic conditions
发明人：KANG YOUN K; DERIA PRAVAS; THERIEN MICHAEL J
权利人:KANG YOUN K; DERIA PRAVAS; THERIEN MICHAEL J; UNIV PENNSYLVANIA
摘要:Provided are ethyne synthons comprising boron and related methods. Also provided are related water-soluble arylethynylene polymers capable of being synthesized in neat water under aerobic conditions.

专利号:US-2011257356-A1
优先权日:2008-02-27
标题:Synthesis of Poly-(P-Aryleneethynylene)s in Neat Water Under Aerobic Conditions

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实用工具

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献

参考文献:10.1007/978-3-642-32099-6_2
摘要:Gøgsig TM, Gøgsig TM. Palladium 1,2-Migration in the Heck Reaction. 2012. In: New Discoveries on the β-Hydride Elimination. : Springer Berlin Heidelberg; 2012.