CAS: 27178-34-3; Tert-Butylphenol

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      专利号:US-5840814-A
      优先权日:1996-08-07
      标题 :Multi-arm star polymers having a well-defined core and methods for the synthesis thereof
      发明人:MAJOROS ISTVAN J; MARSALKO TIMEA M; KENNEDY JOSEPH P
      权利人:UNIV AKRON
      摘要:The synthesis of star polymers having well-defined arms emanating from well-defined and readily controllable calix n!arene (n=4 to 16) cores are described. The synthesis is particularly suitable for polyisobutylene and/or polysiloxane star polymers. The synthesis has been achieved using carbocationic and/or anionic ring-opening polymerization techniques to form polymer arms of desired molecular weights, then separately preparing the calixarene derivative core, and finally, linking the arms to the core by transesterification or hydrosilation.

      专利号:US-2006051291-A1
      优先权日:2004-09-07
      标题 :Synthesis of radiolabeled sugar metal complexes
      发明人:ADAM MICHAEL J; FISHER CARA L; BAYLY SIMON R; ORVIG CHRISTOPHER; LIM NATHANIEL C; STORR TIMOTHY J; EWART CHARLES B
      权利人:ADAM MICHAEL J; FISHER CARA L; BAYLY SIMON R; ORVIG CHRISTOPHER; LIM NATHANIEL C; STORR TIMOTHY J; EWART CHARLES B
      摘要:The invention provides a method for manufacturing or preparing neutral, low molecular weight 99m Tc-labeled and 186 Re-labeled carbohydrate complexes with an improved radiochemical yield from a simple functionalized sugar, such as glucosamine. In particular the synthesis relies on single ligand transfer (SLT) or double ligand transfer (DLT) reactions for converting a ferrocene compound into a rhenium or technetium tricarbonyl complex. The ferrocene compound may be linked to a sugar through various functional groups including, for example, thio, amino and alcohol functionalities to provide a wide range of radiolabeled sugar complexes that include both water soluble and relatively water insoluble compounds.

      专利号:US-12319712-B2
      优先权日:2018-05-09
      标 题:Methods of synthesizing a polynucleotide array using photoactivated agents
      发明人:RAJASEKARAN JOHN J; JAYARAMAN VASANTH; VENUGOPAL ANIRUDH; BEI KANG; WANG TIANHAO; KRISHNA KARTHIK; KRISHNAMURTHY HARI KRISHNAN
      权利人:VIBRANT HOLDINGS LLC
      摘要:Described herein are methods for the synthesis of DNA polynucleotides and polynucleotides, as well as methods for their deprotection and methods for the use of said compounds and compositions comprising said compounds. In particular, such compounds and compositions comprising them are used in methods for light-directed synthesis of DNA microarrays.

      专利号:US-2009099061-A1
      优先权日:2006-01-27
      标 题:Synthesis of carotenoid analogs or derivatives with improved antioxidant characteristics
      发明人:FOSS BENTE J; NADOLSKI GEOFFRY T; LOCKWOOD SAMUEL F
      权利人:FOSS BENTE J; NADOLSKI GEOFFRY T; LOCKWOOD SAMUEL F
      摘要:A method is described for synthesizing and administering carotenoid compounds with improved antioxidant characteristics. In some embodiments, extension or improvement of conjugation may be employed in structural modification of carotenoids. In other embodiments, reduction of ring/chain steric hindrance may improve the lambda max, and hence, the overall antioxidant capability, of particular compounds. In other embodiments, introduction and/or increase in synthetic handles for conjugation may improve the stoichiometric ratios of conjugating moieties to the polyene backbone. The methods may be used to improve natural and/or synthetic compounds for medicinal application in the treatment of disease.

      专利号:US-5670465-A
      优先权日:1993-01-08
      标题 :Preparation of p-fuchsones and synthesis of p-dihydroxylated aromatic compounds therefrom
      发明人:COSTANTINI MICHEL; MANAUT DANIEL; MICHELET DANIEL
      权利人:RHONE POULENC CHIMIE
      摘要:p-Dihydroxylated aromatic compounds are prepared via the oxidation of p-fuchsones, the latter advantageously being synthesized by reacting a phenolic compound having at least one hydrogen atom in the para-position to the hydroxyl function with a non-enolizable ketonic compound, in the presence of a catalytically effective amount of an acid catalyst and, optionally, a cocatalytically effective amount of an ionizable sulfur-containing compound.

      专利号:US-9505880-B2
      优先权日:2013-06-04
      标题 :Synthesis of polyfunctional polyol acrylates
      发明人:MCCARTHY KEVIN ROBERT; NIU WEIJUN; SCHISSEL DAVID NEAL; WALLACE ARTHUR LAWRENCE
      权利人:CORNING INC
      摘要:A method of synthesizing urethane-free polyfunctional acrylate compounds. The method includes reaction of a polyol with acrylic acid in the presence of an inhibitor. A catalyst may also be present. The catalyst may be an acid and the inhibitor may be a substituted phenol compound. Excess acid may be removed by adding a salt and excess water may be removed by adding a drying agent. The reaction converts alcohol groups of the polyol to acrylate groups to provide a radiation-curable polyfunctional acrylate compound. The reaction is applicable to polyols generally and provides a scalable high yield process for forming urethane-free polyfunctional acrylates over a wide range of molecular weights. Coatings made from the acrylate products exhibit modulus and tensile strength characteristics favorable for primary fiber coatings.

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      合成参考文献


      摘要:Larsen, M. H.; Cacciarini, M.; Brøndsted Nielsen, M., Science of Synthesis Knowledge Updates, (2015) 2, 243.
      摘要:Beier, P., Science of Synthesis Knowledge Updates, (2014) 2, 287.
      摘要:González-Bello, C., Science of Synthesis Knowledge Updates, (2018) 1, 250.
      摘要:González-Bello, C., Science of Synthesis Knowledge Updates, (2018) 1, 211.
      摘要:Furuta, T.; Kawabata, T., Science of Synthesis: Asymmetric Organocatalysis, (2012) 1, 519.
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