CAS: 1923-70-2; Tetrabutylammonium (Perchlorate)

相似化合物

65201-77-6 16385-59-4 37451-68-6

上下游产品

CAS号1643-19-2 四丁基溴化铵 | CAS号311-28-4 四丁基碘化铵 | CAS号2052-49-5 四丁基氢氧化铵 | CAS号14999-75-8 N,N-diethyletha... | CAS号1112-67-0 四丁基氯化铵(TBAC) | CAS号914-45-4 1-Butanaminium,... | CAS号311-28-4 四丁基碘化铵 | CAS号14999-75-8 N,N-diethyletha... | CAS号1643-19-2 四丁基溴化铵 | CAS号1112-67-0 四丁基氯化铵(TBAC) | CAS号914-45-4 1-Butanaminium,... | CAS号10049-04-4 二氧化氯 | CAS号10442-39-4 氰化四丁基胺 | CAS号1626-24-0 三苯基氯化锗 | CAS号2181-40-0 六苯基二锗杂噁烷 | CAS号106-98-9 正丁烯

四丁基溴化铵置于高氯酸体系中,化学反应生成四丁基高氯酸铵
参考文献:在可见光下靶向姜黄素和(吖啶基)双吡啶并吩嗪的光细胞毒性氧化钒(iv)复合物的线粒体
标题:在可见光下靶向姜黄素和(吖啶基)双吡啶并吩嗪的光细胞毒性氧化钒(iv)复合物的线粒体
摘要:氧化钒 (Iv) 络合物,Vo(Acac)(L)Cl] (1),Vo(Cur)(L)Cl] (2) 和 Vo(Scur)(L)Cl] (3) {acac = 乙酰丙酮化物,制备并表征了 Cur = 姜黄素单阴离子,Scur = 二葡萄糖基姜黄素单阴离子,L = 11-(9-吖啶基)Dipyrido3,2-A:2',3'-C]吩嗪 (Acdppz)}.该复合物在 Dmf 中是非电解的,在 Dmf 水溶液中为 1:1 电解.单电子顺磁配合物在 Dmf 水溶液中显示出接近 725 Nm 的 Dd 带,在 Dmso 水溶液中显示出接近 520 Nm 的绿色发射.配合物在 Dmf 水溶液中表现出接近-0.85 V 的不可逆 V-Iv/v-Iii 氧化还原响应与 Sce.该复合物对小牛胸腺 Dna (Kb: 3.1X10(5)-9.6X10(5) M-1) 显示出非常好的结合强度,并在 705
Doi:10.1002/zaac.201300569

专利信息

专利号:US-3887441-A
优先权日:1971-12-29
标 题 :Electro-chemical synthesis of organonickel compounds
发明人：HUGHES WILLIAM B; FAHEY DARRYL R
权利人:PHILLIPS PETROLEUM CO
摘要:A process for the synthesis of organonickel derivatives by electrochemical reduction of a nickel(II) complex followed by addition of a haloorganic compound which yields a different nickel(II) complex. The complexes have utility as catalysts for olefin dimerization.

专利号:US-4824532-A
优先权日:1987-01-09
标题:Process for the electrochemical synthesis of carboxylic acids
发明人：MOINGEON MARIE-ODILE; CHAUSSARD JACQUES; TROUPEL MICHEL; SABOUREAU CHRISTOPHE
权利人:AEROSPATIALE
摘要:The invention relates to a process for the electrosynthesis of carboxylic acids of general formula R-COOH in which R is an organic radical by the electrochemical reduction, in the presence of carbon dioxide, of organic compounds corresponding to the general formula R-Y in which R is the above-mentioned organic radical and Y is a hetero atom-containing radical, the hetero atom of the radical Y, chosen from the group consisting of oxygen, nitrogen, sulphur andphosphorus, being directly linked to a carbon atom of the radical R by a single covalent linkage. When the hetero atom is nitrogen or phosphorus, the radical Y is an ammonium or phosphonium radical respectively. The anode, which is consumed during the electrosynthesis, is made of a metal chosen from the group consisting of reducing metals and their alloys, preferably made of magnesium, aluminium or zinc. This process without catalyst is very simple to perform and enables a cell with a single compartment to be employed. The carboxylic acids are commonly employed in the chemical industry, especially as intermediates for the synthesis of pharmaceutical products or of products used in plant protection.

专利号:US-10597342-B2
优先权日:2017-03-29
标 题 :Method for the synthesis of 9,10-bis(chloromethyl)anthracene
发明人：ORTEGA HIGUERUELO FRANCISCO JOSÉ; LANGA DE LA PUENTE FERNANDO
权利人:UNIV CASTILLA LA MANCHA
摘要:The invention relates to a method for the synthesis of 9,10-bis(chloromethyl) anthracene, comprising the mixing of the reagents, anthracene and 1,3,5-trioxane, a phase transfer catalyst selected from the group comprising quarternary ammonium salt and crown ether with hydrochloric acid and acetic acid.

专利号:US-10597340-B2
优先权日:2013-05-10
标 题:Synthesis of fluorinated radiopharmaceuticals via electrochemical fluorination
发明人：SADEGHI SAMAN; HE QINGGANG; LEBEDEV ARTEM
权利人:UNIV CALIFORNIA
摘要:Provided herein are methods and compositions for the electrochemical selective radiofluorination of aromatic molecules. The resulting fluorine-18 labeled compounds are ideal radionuclides for use in Positron Emission Tomography (PET); they are also difficult to radiolabel efficiently and with high specific activity using existing approaches. For example, radiopharmaceuticals such as [F18]L-DOPA, which is indispensable in PET brain disease imaging, may be made electrochemically with high radiochemical yield and high specific activity using 18F-. The invention process described herein opens new possibilities and provides wider access to PET tracers such as 18F-L-Dopa, since 18F- is much more widely available than the 18F 2 , currently used for synthesis of electron rich substrates.

专利号:US-8729310-B2
优先权日:2009-09-22
标题:Halogenated diarylamine compound and synthesis method thereof
发明人：OSAKA HARUE; INOUE HIROTO
权利人:OSAKA HARUE; INOUE HIROTO; SEMICONDUCTOR ENERGY LAB
摘要:An object is to provide a new halogenated diarylamine compound serving as a source material for synthesis of a variety of diarylamine compounds and triarylamine compounds and a synthesis method of the new halogenated diarylamine compound. A halogenated diarylamine compound represented by the following general formula (G1) and a synthesis method thereof are provided. Note that a variety of diarylamine compounds and triarylamine compounds can be synthesized using the halogenated diarylamine compound represented by the following general formula (G1).

专利号:US-9267213-B1
优先权日:2005-03-25
标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array
发明人：MAURER KARL; COOPER JOHN J
权利人:CUSTOMARRAY INC
摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.