CAS: 156791-82-1; Hosenkoside A

该化合物是一个复杂的胶质板,其特点是糖和碳氢化合物的多种成分,其特点是B-D-Gluclarosy modie,这是一种六人组成的循环甘蔗糖,表明其在碳水化合物化学中的作用.该化合物展示了一种循环结构,对于其独特的三维安排具有重要意义,有助于其潜在的生物活动.多种手艺中心的存在表明,它可能在生物系统中出现立体互动,影响其再活性和溶性.此外,该结构中的氢氧化物和甲基氧化合物可能增强其水的繁殖性,影响其在极地溶剂中的溶性.该化合物可能因其在药物开发中的潜在应用,特别是针对特定生物路径或作为生物活性剂,因此可能对医药发展产生兴趣.

英文名称Hosenkoside A
中文名称凤仙萜四醇苷A
IUPAC名称(2S,3R,4S,5S,6R)-2-(((2R,3R,4S,5S,6R)-4,5-dihydroxy-2-(((1R,2S,4aR,4bR,6aR,6'S,7R,8S,10aR,10bR,12aS)-1-hydroxy-6'-((S)-1-hydroxypropan-2-yl)-4a,4b,7,10a-tetramethyl-7-((((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)methyl)octadecahydro-1H,2'H,4'H-spiro[chrysene-2,3'-pyran]-8-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
其它别名β-D-Glucopyranoside,(1R,2S,4Ar,4Br,6'S,6Ar,7R,8S,10Ar,10Br,12As)-7-[(β-D-Glucopyranosyloxy)Methyl]Octadecahydro-1-Hydroxy-6'-[(1S)-2-Hydroxy-1-Methylethyl]-4A,4B,7,10A-Tetramethylspiro[chrysene-2(1H),3'(4'H)-[2H]P
CAS编号156791-82-1
MFCD编号:MFCD32000712
分子式:C48H82O20分子量:979.16
产品CID: 783408
产品分类有机原料 → 脂质和类脂质分子 → 异戊烯醇脂质

相似结构搜索
产品信息参考;;;;
InChIKey: JUKFJOYCFLIWIA-MDQYKXRHSA-N
InChI=1S/C48H82O20/c1-22(16-49)24-8-13-48(21-62-24)15-14-46(4)23(40(48)61)6-7-29-44(2)11-10-30(45(3,28(44)9-12-47(29,46)5)20-63-41-37(59)34(56)31(53)25(17-50)64-41)67-43-
计算化学: 氢键受体数20.0氢键供体数13.0可旋转键数12.0

MSDS等安全信息

警示词Warning
危险描述H302-H315-H319-
防范说明P264-P270-P280-P301+P312+P330-P302+P352-P305+P351+P338-P332+P313-P337+P313-P362+P364-
安全声明24/25
WGK Germany3

合成工艺路线路线简述

📜Hosenkoside K置于sodium Dihydrogenphosphate体系中,用乙醇用作溶剂,化学反应 48.0H,以10 Mg的收率获得prasapogenin Iv
参考文献:Hosenkosides F,G,H,I,J,And K,Novel Baccharane Glycosides From The Seeds Of Impatiens Balsamina.
标题:Hosenkosides F,G,H,I,J,And K,Novel Baccharane Glycosides From The Seeds Of Impatiens Balsamina.
摘要:From The Seeds Of Impatiens Balsamina We Have Isolated Six Novel Baccharane Glycosides,Hosenkosides F-K. The Structures Of All Isolates Were Determined By The Use Of Two Dimensional (2D) NMR Techniques (1H-1H Correlation Spectroscopy (Cosy),Heteronuclear Multiple Quantum Coherence (Hmqc),Heteronuclear Multiple-Bond Correlation (Hmbc),Rotating Frame Overhauser Enhancement Spectroscopy (Roesy),Total Correlation Spectroscopy (Tocsy)) And Chemical Derivatization. Hosenkosides F,H And I Are Hosenkol B 3-O-Sambubiosido-26-O-Glucoside,3-O-Sambubioside And 3,26-O-Diglucoside,Respectively. Hosenkoside G Is Hosenkol C 3-O-Sambubiosido-28-O-Glucoside. Hosenkosides J And K Are Hosenkol A 3-O-Sophoroside And 3-O-Sophorosido-26-O-Glucosyl-28-O-Glucoside,Respectively.
Doi:10.1248/cpb.42.1422