CAS: 87-88-7; 2,5-Dichloro-3,6-Dihydroxycyclohexa-2,5-Diene-1,4-Dione

该化合物是一种有机化合物,属于芳酸类别,其特征是其深红至棕色晶体外观,以其在水和酒精等极溶剂中的溶性而著称,化学结构具有氯化阴性,有助于其酸性和反应性.氯酸经常被用作分析化学的试剂,特别是因其能形成有色复合物而用于确定金属离子.此外,它展示了有助于染料合成和pH指标的特性,并指出了该化合物在有机电子学和材料科学中的潜在应用.然而,应谨慎处理该化合物,因为它可能对接触产生健康风险.

结构式图片

相似化合物

615-94-1 4370-59-6 615-93-0

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号118-75-2 四氯对醌 | CAS号123-31-9 对苯二酚 | CAS号1198-55-6 四氯邻苯二酚 | CAS号2435-53-2 四氯邻苯醌 | CAS号634-85-5 2,3,5-三氯-1,4-苯醌 | CAS号632-21-3 1,1,3,3-四氯丙酮 | CAS号58965-69-8 2,3,5-trichloro... | CAS号57-13-6 尿素 | CAS号87-86-5 五氯苯酚 | CAS号7790-94-5 氯磺酸 | CAS号75-47-8 三碘甲烷 | CAS号106-34-3 醌氢醌 | CAS号124-48-1 二溴一氯甲烷标准溶液 | CAS号144-62-7 草酸 | CAS号1768-31-6 Pentachloropropanone | CAS号76-06-2 氯化苦 | CAS号632-21-3 1,1,3,3-四氯丙酮

合成工艺路线路线简述

  • 2435-53-2 = 87-88-7 [标题:Reaction Conditions
    标题:Chlorinated Benzo-1,2-Quinones: An Example Of Chemical Transformation Of Toxicants During Tests With Aquatic Organisms
    作者:Remberger,M.; Et Al
    参考文献:Ecotoxicology And Environmental Safety 日期:1991 卷标:22(3) 页码:320-36]

    118-75-2 = 87-88-7
    反应条件:1.1 Reagents: Potassium Hydroxide
    标题:3,6-Dichlorobenzene-1,2,4,5-Tetraol
    作者:Aitken,R. Alan; Et Al
    参考文献:Molbank 日期:2022 卷标:2022(3)]

    118-75-2 = 87-88-7
    反应条件:1.1 Reagents: Sodium Bicarbonate,Water Catalysts: 4-Methoxypyridine N-Oxide Solvents: Acetonitrile,Water; Rt
    标题:Catalytic Activity Of Heteroaromatic N-Oxides In The Hydrolysis Of 2,3,5,6-Tetrachloro-P-Benzoquinone
    作者:Ryzhakov,A. V.; Et Al
    参考文献:Russian Journal Of General Chemistry 日期:2006 卷标:76(1) 页码:126-128]

    13115-24-7 + 87-87-6 = 87-88-7 + 877-13-4 + 79-16-3 + 118-75-2
    反应条件:1.1 Solvents: Water; 1 H,Ph 7.4,37 °C
    标题:An Unexpected New Pathway For Nitroxide Radical Production Via More Reactive Nitrogen-Centered Amidyl Radical Intermediate During Detoxification Of The Carcinogenic Halogenated Quinones By N-Alkyl Hydroxamic Acids
    作者:Zhu,Ben-Zhan; Et Al
    参考文献:Free Radical Biology & Medicine 日期:2020 卷标:146 页码:150-159]

    593-77-1 = 87-88-7 + 877-13-4 + 79-16-3 + 118-75-2
    反应条件:1.1 Reagents: Sodium Carbonate Solvents: Methanol; 0 °C; 30 Min,0 °C2.1 Solvents: Water; 1 H,Ph 7.4,37 °C
    标题:An Unexpected New Pathway For Nitroxide Radical Production Via More Reactive Nitrogen-Centered Amidyl Radical Intermediate During Detoxification Of The Carcinogenic Halogenated Quinones By N-Alkyl Hydroxamic Acids
    作者:Zhu,Ben-Zhan; Et Al
    参考文献:Free Radical Biology & Medicine 日期:2020 卷标:146 页码:150-159
📜四氯苯醌置于sodium Hydroxide,乙醇,水体系中,化学反应生成 氯冉酸
参考文献:Graebe,Justus Liebigs Annalen Der Chemie,1891,Vol. 263,P. 30
标题:Graebe,Justus Liebigs Annalen Der Chemie,1891,Vol. 263,P. 30

海关参考信息

专利信息


专利号:US-6329543-B1
优先权日:1999-05-06
标题:Process for synthesis of isobornyl (Meth) acrylate
发明人：KNEBEL JOACHIM; SAAL DORIS
权利人:ROEHM GMBH
摘要:The present invention relates to processes for synthesis of isobornyl (meth)acrylate by reacting camphene with (meth)acrylic acid in the presence of sulfuric acid and at least one compound having inhibiting action. Aqueous sulfuric acid with an acid concentration in the range of 65 to 85 wt % is used. Isobornyl (meth)acrylate can advantageously be distilled from a mixture containing sulfuric acid in the presence of 2,6-di-tert-butyl-alpha-(dialkylamino)-p-cresol.

专利号:US-7504231-B2
优先权日:2001-09-13
标题:Method of alleviating chronic pain via peripheral inhibition of neurotransmitter synthesis
发明人：MILLER KENNETH E
权利人:UNIV OKLAHOMA
摘要:A composition having sustained pain-relieving properties such that the composition may be administered to a subject to alleviate chronic pain. The composition includes an effective amount of at least one inhibitor of neurotransmitter synthesis. A method for alleviating chronic pain in a subject for an extended period of time is also disclosed, in which the compound is administered to a subject suffering from chronic pain at a site of inflammation such that the administration of the compound results in a reduction in at least one of thermal and mechanical pain responses at the site of inflammation for a period of at least two days without any resulting acute pain behavior. The composition may further include an effective amount of at least one compound having analgesic effects such that the composition also alleviates acute pain.

专利号:WO-2004028448-A9
优先权日:2002-09-13
标题:Method of alleviating pain via inhibition of neurotransmitter synthesis
发明人：MILLER KENNETH E
权利人:MILLER KENNETH E
摘要:A composition having sustained pain-relieving properties such that thecomposition may be administered to a subject to alleviate chronic pain. The composition includes an effective amount of at least one inhibitor of neurotransmitter synthesis. A method for alleviating chronic pain in a subject for an extended period of time is also disclosed, in which the compound is administered to a subject suffering from chronic pain at a site of inflammation such that the administration of the compound results in a reduction in at least one of thermal and mechanical pain responses at the site of inflammation for a period of at least two days without any resulting acute pain behavior. The composition may further include an effective amount of at least one compound having analgesic effects such that the composition also alleviates acute pain.

专利号:US-6706209-B1
优先权日:1999-08-27
标题:Stabilized monomer composition
发明人：SCHARF JAKOB; RAU HARTMUT; GOETZEN FRIEDRICH
权利人:ROEHM GMBH
摘要:A stabilized monomer composition containing at least one ethylenically unsaturated monomer and a combination of N,N-diethylhydroxylamine an N-nitroso-N-phenylhydroxylamine or its salt in a weight ratio of from 1:1 to 10:1 permits the synthesis of 2-hydroxyalkyl (meth)acrylates in particularly high yields and remains stable during prolonged storage.

专利号:US-2004126368-A1
优先权日:2001-09-13
标 题 :Method of alleviating chronic pain via peripheral inhibition of neurotransmitter synthesis

专利号:WO-2004028448-A2
优先权日:2002-09-13
标题 :Method of alleviating pain via inhibition of neurotransmitter synthesis

其他信息查阅

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

实用工具

⚠️全国化工行业净网倡议书
📋制造商识别码
📖 海关编码查询
📝MSDS生成器

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Ibrahim A Darwish, Et Al. Spectrophotometric Analysis Of Selective Serotonin Reuptake Inhibitors Based On Formation Of Charge-Transfer Complexes With Tetracyanoquinodimethane And Chloranilic Acid. J Aoac Int. 2006 Mar-Apr;89(2):326-33.
[参考文献]: Idrees F Al-Momani, Et Al. Indirect Flow-Injection Spectrophotometric Determination Of Meloxicam, Tenoxicam And Piroxicam In Pharmaceutical Formulations. Anal Sci. 2006 Dec;22(12):1611-4.
[参考文献]: K Sharma, Et Al. Spectrophotometric, Fourier Transform Infrared Spectroscopic And Theoretical Studies Of The Charge-Transfer Complexes Between Methyldopa [参考文献]: M Walash, Et Al. Spectrophotometric Determination Of Nizatidine And Ranitidine Through Charge Transfer Complex Formation. Arch Pharm Res. 2004 Jul;27(7):720-6.
[参考文献]: Moamen S Refat, Et Al. Intermolecular Hydrogen Bond Complexes By In Situ Charge Transfer Complexation Of O-Tolidine With Picric And Chloranilic Acids. Spectrochim Acta A Mol Biomol Spectrosc. 2011 Aug;79(3):672-9.

合成参考文献


摘要:National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review., 5(9), 1953
摘要:Schafer, E. W., Jr., W. A. Bowles Jr., and J. Hurlbut. 1983. The acute oral toxicity and repellency and hazard potential of 998 chemicals to one or more species of wild and domestic birds. Archives of Environmental Contamination and Toxicology 12:355-382.
摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 1985. Acute oral toxicity and repellency of 933 chemicals to house and deer mice. Archives of Environmental Contamination and Toxicology 14:111-129.
摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 2004. Toxicity, Repellency of Phytotoxicity of 979 Chemicals to Birds, Mammals and Plants. Research Report No. 04-01. National Wildlife Research Center, Fort Collins, Colorado. 118 pp.
摘要:A. Beauchamp and R. L. Benoit, Can. J. Chem. 42, 2161 (1964).
📝 需求与反馈
尽可能描述清楚需求与问题信息
×

通知