📜三己基十四烷化膦溴化物 反应生成 三己基(四癸基)膦 双(三氟甲基磺酰)氨 参考文献:Liquid Metal Complex Having Oxygen-Absorbing Ability 标题:Liquid Metal Complex Having Oxygen-Absorbing Ability 摘要:提供一种具有吸氧能力的液态金属配合物,包含钴-乙酰辛基配合物或其衍生物,以及离子液体,其中离子液体中的离子配体具有胺结构,其对应的阴离子配对,其中钴-乙酰辛基配合物或其衍生物由通式(1)表示,并且液态金属配合物具有离子配体的胺结构与钴-乙酰辛基配合物或其衍生物的钴原子轴向配位的结构.
专利号:US-2010191010-A1 优先权日:2007-07-02 标题 :Process for the synthesis of carbamates using co2 发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY 权利人:HUNTSMAN INT LLC 摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.
专利号:US-9267213-B1 优先权日:2005-03-25 标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array 发明人:MAURER KARL; COOPER JOHN J 权利人:CUSTOMARRAY INC 摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.
专利号:US-9512080-B2 优先权日:2012-07-10 标 题:Synthesis of acridinium compounds by N-alkylation of acridans 发明人:NATRAJAN ANAND; WEN DAVID 权利人:SIEMENS HEALTHCARE DIAGNOSTICS INC 摘要:A method is provided for N-alkylation of acridine compounds by reduction of acridines to corresponding acridans to improve the reactivity of the acridine nitrogen, and subsequent N-alkylation of the acridans in ionic liquid solvents to provide the corresponding acridinium compounds in high yield. This inventive process improves chemical conversion, and does not require the use of highly toxic alkylating agents, such as 1,3-propane sultone.
专利号:US-8445715-B2 优先权日:2007-07-02 标 题 :Method of synthesizing fenofibrate 发明人:LUCAS BEATRICE 权利人:LUCAS BEATRICE; SYNKEM 摘要:A novel process for the synthesis of fenofibrate, includes reacting a metal salt of fenofibric acid with an isopropyl halide, in a solvent system composed of a mixture of dimethyl sulfoxide and a C 2 -C 4 alkyl acetate. The process can be used on an industrial scale and makes it possible to obtain a fenofibrate of a quality in accordance with the Pharmacopoeia without the need for purification by recrystallization.
专利号:US-10407676-B2 优先权日:2014-12-09 标题 :High efficiency, small volume nucleic acid synthesis 发明人:POEHMERER THOMAS; KUHN PHILLIP; NOTKA FRANK; ZEIDLER ANDREAS; HEIL KORBINIAN; TREFZER AXEL; FONNUM GEIR; KATZEN FEDERICO; ANDERSSON KRISTIAN 权利人:LIFE TECHNOLOGIES CORP; THERMO FISHER SCIENT GENEART GMBH; LIFE TECH AS 摘要:The disclosure generally relates to compositions and methods for the production of nucleic acid molecules. In some aspects, the invention allows for the microscale generation of nucleic acid molecules, optionally followed by assembly of these nucleic acid molecules into larger molecules. In some aspects, the invention allows for efficient production of nucleic acid molecules (e.g., large nucleic acid molecules such as genomes).
专利号:US-2015197491-A1 优先权日:2012-07-10 标 题:Synthesis of acridinium compounds by n-alkylation of acridans