CAS: 37993-76-3; 3-Phenylisoquinoline
该化合物是一种以其等离子体结构为特征的杂交有机化合物,该化合物由一个有引信的苯和环系统组成,在等离子体的三处附着一个联苯组,该化合物通常具有一个板状结构,有助于其欧元叠叠合相互作用的潜力,从而影响其溶解性和再活动.该化合物一般被视为黄对褐的固体,在有机溶剂中具有中等溶解性.该苯组的存在可增强其电子特性,使其在各个领域,包括有机合成和药用化学领域,引起兴趣. 3-苯基辛基尼松还可能展示生物活动,从而导致调查其作为药剂的潜力.其化学行为可能受到诸如苯基体环子组和整个电子环境等因素的影响,使其成为对有机和药用化学领域进行进一步研究的感兴趣对象.
相似化合物
630422-14-9 223553-42-2 884500-88-3物理性质
MSDS等安全信息
- GHS象形图
- GHS符号GHS06 & GHS05;
注释: Skull and crossbones & Corrosion - 危险类别急性毒性 类别3(经皮)
急性毒性 类别4(经口)
皮肤腐蚀/刺激 类别2
严重眼损伤 类别1 - 警示词Danger(危险)
- 危险描述H311 |皮肤接触会中毒.
H302 |吞咽有害.
H315 |造成皮肤刺激.
H318 |造成严重眼损伤. - 防范说明P264-P270-P280-P302+P352-P330-P361+P364-P362+P364-P405-P501
- 危险等级8
- UN编号3261.0
- 危险品标志T
- 包装等级Ⅲ
- 安全声明26-36/37/39-45
- 危险类别码22-24-38-41
- WGK Germany3
欧盟法规
C&L通报上下游产品
CAS号536-74-3 苯乙炔 | CAS号6630-33-7 2-溴苯甲醛 | CAS号241813-23-0 N-tert-butyl-2-... | CAS号59046-72-9 2-苯基乙炔基苯甲醛 | CAS号5680-80-8 L-丝氨酸甲酯盐酸盐 | CAS号1159003-31-2 (E)-2-(2-phenyl... | CAS号1159003-32-3 (E)-2-(2-phenyl... | CAS号1226977-16-7 N-[2-(phenyleth...合成工艺路线路线简述
- 合成目标产物 3-Phenylisoquinoline 主要起始原料 2-Phenylethynyl-Benzaldehyde
- (文献来源)合成步骤主要原料 2-Phenylethynyl-Benzaldehyde
📜邻溴苄胺置于1,1'-Bis(Di-Tertbutylphosphino)Ferrocene,Palladium Diacetate,三正丁基氟化锡,三乙胺,Cesium Fluoride,2,3-二氯-5,6-二氰基-1,4-苯醌体系中,用 四氢呋喃,二氯甲烷,甲苯 作为反应溶剂,化学反应 14.0H,反应生成 3-苯基异喹啉
参考文献:钯催化的甲硅烷基醚的α-芳基化在异喹啉和菲啶的合成中
标题:钯催化的甲硅烷基醚的α-芳基化在异喹啉和菲啶的合成中
摘要:通过开发两步,一锅法,构成了区域选择性的钯催化的甲硅烷基醚的kuwajima-Urabeα-芳基化和酸介导的脱保护,环化和芳构化,已经获得了各种各样的异喹啉和菲啶.甲硅烷基醚的结构多样性导致了三类不同的异喹啉和菲啶,可以从中衍生出相关的天然产物.还证明了通过快速组装天然产物三鸟苷可实现该方法的合成效用.
DOI:10.1021/acs.Orglett.7B03776
海关参考信息
- 2902200000-苯
2933310010-吡啶
2939800000-其他生物碱 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-7399857-B2
优先权日:2005-03-31
标题 :Synthesis of organometallic cyclometallated transition metal complexes
发明人：LUSSIER BARBARA B; DEATON JOSEPH C
权利人:EASTMAN KODAK CO
摘要:A process for forming a tris-cyclometallated complex comprises the step of reacting;n a) an M(I) complex, wherein M represents Rh or Ir, and said complex comprises at least two ligands and contains at least two alkenyl groups pi-bonded to M, with b) a heterocyclic compound capable of forming a organometallic cyclometallated complex.
专利号:US-2006224007-A1
优先权日:2005-03-31
标题 :Synthesis of organometallic cyclometallated transition metal complexes
发明人：LUSSIER BARBARA B; DEATON JOSEPH C
权利人:EASTMAN KODAK CO
摘要:A process for forming a tris-cyclometallated complex comprises the step of reacting; a) an M(I) complex, wherein M represents Rh or Ir, and said complex comprises at least two ligands and contains at least two alkenyl groups pi-bonded to M, with b) a heterocyclic compound capable of forming a organometallic cyclometallated complex.
专利号:US-7005522-B2
优先权日:2004-06-29
标 题 :Synthesis of organometallic cyclometallated transition metal complexes
发明人：DEATON JOSEPH C
权利人:EASTMAN KODAK CO
摘要:A process for forming a tris-cyclometallated iridium or rhodium complex comprises reacting in the presence of a solvent:n a) a bis-cyclometallated complex comprising an Ir (III) or Rh (III) metal, two bidentate ligands, two monodentate ligands and a counterion, and b) a heterocyclic compound capable of forming an organometallic cyclometallated complex.
专利号:US-7015344-B2
优先权日:2004-06-29
标题 :Synthesis of organometallic cyclometallated group viiib metal complexes
发明人：DEATON JOSEPH C
权利人:EASTMAN KODAK CO
摘要:A process for forming an organometallic cyclometallated Group viiib metal complex comprises reacting a Group viiib metal compound with a heterocyclic compound capable of forming an organometallic cyclometallated complex in the presence of a solvent comprising an aromatic oxygen containing compound.
专利号:US-2006223997-A1
优先权日:2005-03-31
标题 :Synthesis of organometallic cyclometallated transition metal complexes
专利号:US-2005288507-A1
优先权日:2004-06-29
标题:Synthesis of organometallic cyclometallated transition metal complexes
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Indole As Neutral Leaving Group In Silver Nitrate Induced Cyclization Reactions OfN-{2-[alkynyl(Hetero)Aryl]Methylene}Indolin-1-Amines For The Synthesis Of Annulated Pyridine Derivatives作者:Nugzar Ghavtadze,Roland Fröhlich,Ernst-Ulrich Würthwein |发布日期:2010.3
摘要:Nitrate In Chloroform At 60 °C, Electrophilic Cyclization Reactions To Afford Annulated Pyridine Derivatives 4. Mechanistically, The Silver(I)-Assisted 6-Endo-Dig Ring-Closure Process Of Compounds 3 Leads To The Formation Of An Intermediate Pyridinium Cation, Which Releases - Besides The Products 4 ― Indole As Unusual But Efficient Neutral Leaving Group After N-N Bond Cleavage. It Is Shown That Among The
合成参考文献
摘要:Pilgrim, B. S.; Tucker, M. J., Science of Synthesis Knowledge Updates, (2019) 1, 249.
摘要:Pilgrim, B. S.; Tucker, M. J., Science of Synthesis Knowledge Updates, (2019) 1, 217.
摘要:Pilgrim, B. S.; Tucker, M. J., Science of Synthesis Knowledge Updates, (2019) 1, 190.
摘要:Arndtsen, B. A.; Tjutrins, J., Science of Synthesis: Multicomponent Reactions, (2013) 2, 497.
📝 需求与反馈
尽可能描述清楚需求与问题信息
