📜1,6-己二异氰酸酯置于2-甲基氮丙啶体系中,用 乙酸乙酯 用作溶剂,化学反应 1.0H,反应生成(2,4,6-三氧代三嗪-1,3,5(2H,4H,6H)-三基)三(六亚甲基)异氰酸酯 参考文献:신규한 화합물,이의 제조 방법 및 이를 포함하는 경화제 标题:신규한 화합물,이의 제조 방법 및 이를 포함하는 경화제 摘要:本发明涉及一种新的化合物,其制备方法以及包含它的固化剂,其中包括具有一个或多个异氰酸酯基团和含有咔唑基团的化合物,通过反应分子内的酰胺键和含有咔唑基团的化合物,揭示了包含它们的固化剂.根据本发明的化合物可以提供具有长工作时间和短成熟时间的固化剂.
专利号:US-2019211134-A1 优先权日:2016-08-19 标 题 :Thiourethane polymers, method of synthesis thereof and use in fused filament fabrication printing 发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER 权利人:BOARD OF REGENTS THE UNIV OF TEXAS; ADAPTIVE 3D TECH 摘要:A thermoplastic thiourethane polymer comprising a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. The first type of monomer includes two or more thiol functional groups and the type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anhydrous aprotic solvent-dissolved anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7.
专利号:US-10899072-B2 优先权日:2016-03-15 标题:Thiourethane polymers, method of synthesis thereof and use in additive manufacturing technologies 发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER 权利人:UNIV TEXAS; ADAPTIVE 3D TECH; BOARD OF RESENTS THE UNIV OF TEXAS SYSTEM 摘要:A semi-crystalline thiourethane polymer. The semi-crystalline thiourethane polymer comprises a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. Each of the first type of monomer includes two or more thiol functional groups and each of the second type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7, produced by photo-initiated decomposition of a photolatent base. A method of synthesizing, and polymer jetting and stereolithography methods of manufacturing a polymer part, are also disclosed.
专利号:WO-9723519-A1 优先权日:1995-12-21 标题:Synthesis of aqueous, anionic, amino acrylate polymers 发明人:DAS SURYYA K; KILIC SONER 权利人:PPG INDUSTRIES INC 摘要:Disclosed is a method of making aqueous, anionic amino polymers in water from olefinically unsaturated monomers including amine-containing monomers, but substantially without the inclusion of acid-group containing monomers. The polymerization of the amino polymer is carried out in the presence of a carboxy functional azo initiator dissolved in water by neutralization of acid groups present on the initiator. The polymer is useful in single-package or two-package coating compositions having pH above 7.0 that may be cured with polyisocyanates or polyepoxides.
专利号:US-2007141386-A1 优先权日:2005-12-16 标 题 :Protected air-activated organotin catalysts for polyurethane synthesis 发明人:FELDMAN JERALD; MCLAIN STEPHAN J; BARSOTTI ROBERT J; O'NEIL JAMES W 权利人:FELDMAN JERALD; MCLAIN STEPHAN J; BARSOTTI ROBERT J; O'NEIL JAMES W 摘要:This invention relates to a protected organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.
专利号:US-7919423-B2 优先权日:2005-06-16 标题 :Air activated organotin catalysts for polyurethane synthesis 发明人:FELDMAN JERALD; MCLAIN STEPHAN JAMES 权利人:DU PONT 摘要:This invention relates to an organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.
专利号:US-7683004-B2 优先权日:2004-06-16 标 题 :Air-activated organotin catalysts for polyurethane synthesis 发明人:FELDMAN JERALD; MCLAIN STEPHAN J 权利人:DU PONT 摘要:This invention relates to an organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.
参考标题:Synthesis Of Monodisperse Naphthalene Dendrons For The Application Of Dendrimers 作者:Raveendra Jillella,Jaewoong Kim,Kun Hee Kim,Jin Wook Han,Chang Ho Oh |发布日期:2018.9 摘要:And Urethane Derivatives. The Napthol, 1‐(3‐hydroxy‐6‐(Methoxymethoxy)Naphthalen‐1‐yl)Ethan‐1‐one (H), Was Synthesized By Employing Au‐catalyzed Cyclization Of The Corresponding Propargylic Carboxylates. Polynapthol Dendrons (I, J, K, And L) Were Prepared From Substitution Reactions Of Napthyl Derivative H With Alkyl/aryl Halides Under Basic Conditions. Branched Polyurethane Compounds (Q, R, And S)