CAS: 1705-85-7; 6-Methylchrysene

该化合物是一种多环芳烃,其特点是由多个芳香环组成的引信环状结构,其产物为铬,其甲基组附于铬框架的第六处,该化合物一般没有色素,可粉黄固态,以其疏水性闻名,使其在水中不易溶解,但可溶于有机溶剂中. 6-甲基丙烯对环境化学很感兴趣,因为它存在于化石燃料和燃烧产品中,并且已经研究过该化合物的潜在致癌性.该化合物经常在环境污染和人类健康的背景下进行分析,特别是其作为接触全氟辛烷的标记的作用.该化合物的分子结构有助于其在环境中的稳定性和持久性,引起对生物蓄积性和长期生态影响的担忧.在处理该物质时应采取安全措施,因为它可能对接触全氟化学品构成健康风险.

结构式图片

相似化合物

218-01-9 3351-28-8 3351-30-2

物理性质

MSDS等安全信息

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号81465-03-4 12-methyl-1,2,4... | CAS号7496-05-1 6(5H)-Chrysenon... | CAS号2311-91-3 perphthalic acid | CAS号861094-27-1 2-(2-isopropeny... | CAS号100064-41-3 5,11-dimethyl-7... | CAS号113012-61-6 4b,12-dimethyl-... | CAS号110051-41-7 1-(2-Phenyl-pro... | CAS号7647-01-0 盐酸 | CAS号60-29-7 乙醚

合成工艺路线路线简述

    (E)-1-甲基-4-苯乙烯基萘置于碘体系中,化学反应生成6-甲基屈
    参考文献:二苯乙烯类化合物中的光脱氢环化反应-Iii:空间因素的影响
    标题:二苯乙烯类化合物中的光脱氢环化反应-Iii:空间因素的影响
    摘要:仅当在环化步骤中有关原子的自由价数之和在激发态下超过值1时,才会发生1,2-苯乙烯化合物的光脱氢环化. σf*最大;如果用于各种环化的δ∑f *小于0.1,则有时形成第二乘积.
    Doi:10.1016/s0040-4020(01)93139-4

    海关参考信息

    专利信息


    专利号:US-2003162992-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
    发明人：WATANABE KYOICHI A; DU JINFA
    摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

    专利号:US-8729310-B2
    优先权日:2009-09-22
    标题:Halogenated diarylamine compound and synthesis method thereof
    发明人：OSAKA HARUE; INOUE HIROTO
    权利人:OSAKA HARUE; INOUE HIROTO; SEMICONDUCTOR ENERGY LAB
    摘要:An object is to provide a new halogenated diarylamine compound serving as a source material for synthesis of a variety of diarylamine compounds and triarylamine compounds and a synthesis method of the new halogenated diarylamine compound. A halogenated diarylamine compound represented by the following general formula (G1) and a synthesis method thereof are provided. Note that a variety of diarylamine compounds and triarylamine compounds can be synthesized using the halogenated diarylamine compound represented by the following general formula (G1).

    专利号:US-5821387-A
    优先权日:1997-12-22
    标题 :Polyarenes from aryl ketones with application to synthesis of crisnatol mesylate
    发明人：ARCHIBALD THOMAS G; BARNARD JAMES C; HUANG DER-SHING
    权利人:AEROJET GENERAL CO
    摘要:Alkyl-substituted polyarenes of the formula ##STR1## in which R is alkyl and Ar res is an aryl residue, are prepared from aryl ketones by reaction of the latter with 1-cyclohexenyloxytrimethylsilane in the presence of a Friedel-Crafts catalyst. When R is methyl and Ar res is a naphthyl residue, the reaction serves as a step in a reaction scheme leading to crisnatol mesylate, a pharmaceutical useful in the treatment of brain cancer.

    专利号:CA-2470202-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides

    专利号:WO-03051298-A2
    优先权日:2001-12-14
    标 题:Preparation of intermediates useful in the synthesis of antiviral nucleosides

    专利号:EP-1461041-A4
    优先权日:2001-12-14
    标 题:PREPARATION OF INTERMEDIATES SUITABLE FOR THE SYNTHESIS OF ANTIVIRAL NUCLEOSIDES

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    主要参考文献

    [参考文献]: M Machala, Et Al. Effects Of Methylated Chrysenes On Ahr-Dependent And -Independent Toxic Events In Rat Liver Epithelial Cells. Toxicology. 2008 May 21;247(2-3):93-101.
    [参考文献]: S Amin, Et Al. High Stereoselectivity In Mouse Skin Metabolic Activation Of Methylchrysenes To Tumorigenic Dihydrodiols. Cancer Res. 1987 Jul 15;47(14):3613-7.
    [参考文献]: S R Myers, Et Al. Metabolism Of Chrysene, 5-Methylchrysene, 6-Methylchrysene And 5,6-Dimethylchrysene In Rat Liver Cytosol, In Vitro, And In Rat Subcutaneous Tissue, In Vivo. Chem Biol Interact. 1991;77(2):203-21.
    [参考文献]: S S Hecht, Et Al. Enhancing Effect Of A Bay Region Methyl Group On Tumorigenicity In Newborn Mice And Mouse Skin Of Enantiomeric Bay Region Diol Epoxides Formed Stereoselectively From Methylchrysenes In Mouse Epidermis. Cancer Res. 1987 Oct 15;47(20):5310-5.
    [参考文献]: W Koehl, Et Al. Metabolism Of 5-Methylchrysene And 6-Methylchrysene By Human Hepatic And Pulmonary Cytochrome P450 Enzymes. Cancer Res. 1996 Jan 15;56(2):316-24.

    合成参考文献


    参考文献:10.1016/j.tox.2008.02.008
    摘要:Machala M, Svihálková-Sindlerová L, Pencíková K, Krcmár P, Topinka J, Milcová A, Nováková Z, Kozubík A, Vondrácek J. Effects of methylated chrysenes on AhR-dependent and -independent toxic events in rat liver epithelial cells. Toxicology. 2008 May 21;247(2-3):93–101. doi: 10.1016/j.tox.2008.02.008.
    参考文献:10.1007/s00216-017-0224-y
    摘要:Große Brinkhaus S, Thiäner JB, Achten C. Ultra-high sensitive PAH analysis of certified reference materials and environmental samples by GC-APLI-MS. Analytical and Bioanalytical Chemistry. 2017 Feb 15;409(11):2801–12. doi: 10.1007/s00216-017-0224-y.
    摘要:S73 | METXBIODB | Metabolite Reaction Database from BioTransformer | DOI:10.5281/zenodo.4056560
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