CAS: 101-42-8; Fenuron

该化合物是被归类为苯尿素除草剂的一种化学化合物,主要用于农业,以控制作物中各种杂草;Fenuron的特点是水溶性较低,影响其在土壤中的流动性和潜在的环境影响;该化合物的特点是尿素功能组,它通过抑制目标植物中的光合作物而助长其除草性活动;Fenuron通常在出现前或出现后应用,取决于具体的杂草种和作物类型;其行动方式涉及扰乱易感染植物的生长过程,最终导致其死亡;虽然在杂草管理方面有效,但Fenuron的使用受到监管监督,因为潜在的环境和健康关切,包括其在土壤中的持久性和对非目标生物的可能影响;适当的处理和应用做法对于尽量减少其使用的风险至关重要.

结构式图片

相似化合物

53693-55-3 7160-01-2 39938-79-9

物理性质

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CAS号103-71-9 异氰酸苯酯 | CAS号124-40-3 二甲胺 | CAS号506-59-2 盐酸二甲胺 | CAS号103-70-8 甲酰苯胺 | CAS号79-44-7 二甲氨基甲酰氯 | CAS号201230-82-2 carbon monoxide | CAS号81106-50-5 N'-(2-Bromophen... | CAS号15249-51-1 N,N-dimethylcar... | CAS号74-89-5 氨基甲烷 | CAS号103-71-9 异氰酸苯酯 | CAS号124-40-3 二甲胺 | CAS号6526-66-5 邻氨基-N,N-二甲基苯甲酰胺 | CAS号2908-80-7 3-(4-hydroxyphe... | CAS号6331-71-1 4-氨基-N,N-二甲基苯甲酰胺 | CAS号83898-17-3 3-(2-hydroxyphe... | CAS号2990-01-4 Urea,N,N-dimeth... | CAS号1783-25-1 Methanimidamide...

合成工艺路线路线简述

    N-苯基甲酰胺置于[双(三氟乙酰氧基)碘]苯体系中,用 1,2-二氯乙烷 用作溶剂,化学反应 2.03H,反应生成非草隆
    参考文献:Synthesis Of Unsymmetrical Phenylurea Derivatives Via Oxidative Cross Coupling Of Aryl Formamides With Amines Under Metal-Free Conditions
    标题:Synthesis Of Unsymmetrical Phenylurea Derivatives Via Oxidative Cross Coupling Of Aryl Formamides With Amines Under Metal-Free Conditions
    摘要:通过使用高价碘试剂作为外部氧化剂,在非常好的收率下,将n-芳基甲酰胺直接转化为相应的苯基脲衍生物,通过形成异氰酸酯中间体实现.
    Doi:10.1039/c4Nj01668H

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-6849650-B2
    优先权日:1998-02-27
    标 题:Heterocyclic compounds, pharmaceutical compositions comprising same, and methods for inhibiting β-amyloid peptide release and/or its synthesis by use of such compounds
    发明人:THORSETT EUGENE D; PORTER WARREN J; NISSEN JEFFREY S; LATIMER LEE H; AUDIA JAMES E; DROSTE JAMES
    权利人:ATHENA NEUROSCIENCES INC; LILLY CO ELI
    摘要:Disclosed are compounds which inhibit β-amyloid peptide release and/or its synthesis, and, accordingly, have utility in treating Alzheimer's disease. Also disclosed are pharmaceutical compositions comprising a compound which inhibits β-amyloid peptide release and/or its synthesis as well as methods for treating Alzheimer's disease both prophylactically and therapeutically with such pharmaceutical compositions.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.
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    主要参考文献

    [参考文献]: A Carpio, Et Al. Evaluation Of Phenylene-Bridged Periodic Mesoporous Organosilica As A Stationary Phase For Solid Phase Extraction. J Chromatogr A. 2014 Nov 28:1370:25-32.
    [参考文献]: B Roig, Et Al. Monitoring Of Methotrexate Chlorination In Water. Water Res. 2014 Jun 15:57:67-75.
    [参考文献]: G Schumann, Et Al. [参考文献]: Z Gesamte Hyg. 1979;25(12):926-8.
    [参考文献]: H H Attaway Rd, Et Al. Degradation Of Selected Phenylurea Herbicides By Anaerobic Pond Sediment. J Environ Sci Health B. 1982;17(6):683-99.
    [参考文献]: J P Aguer, Et Al. Fenuron Sorption On Homoionic Natural And Modified Smectites. J Environ Sci Health B. 2000 May;35(3):279-96.

    合成参考文献


    摘要:Zhang, H.; Liu, C.; Lei, A., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 173.
    摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 40(10)(22), 1975
    摘要:Verschueren, K. Handbook of Environmental Data of Organic Chemicals. 2nd ed. New York, NY: Van Nostrand Reinhold Co., 1983., p. 988
    摘要:SRC; Meylan WM, Howard PH; Environ Toxicol Chem 10: 1283-93 (1991)
    摘要:Yoshino, T.; Matsunaga, S., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 130.
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