CAS: 93717-55-6; 3-Benzylbenzonitrile

该化合物是一种有机化合物,其特征是其联苯结构,由两只联苯环组成,由一个单一的联结连接;在2位和4位的联苯环中,一个联苯组(-CH3)的存在有助于其独特的化学特性;该化合物一般在室温下是固体,在有机溶剂中可能表现出中等溶解性;众所周知,它有可能在有机电子中应用,特别是在开发有机半导体和用于光电子装置的材料方面.该环组增强了其电吸附特性,这可能影响其与其他化学种的再活动性和相互作用.此外,2-Cyano-4'-甲基联苯可能会发生各种化学反应,包括核乐替代和电药用芳香替代,使其在有机合成中具有多功能性.在处理和储存时,应参考安全数据,作为化学物质的处理和储存.

英文名称3-Benzylbenzonitrile
中文名称2-氰基-4’-甲基联苯
IUPAC名称3-benzylbenzonitrile
其它别名[2-(P-Tolyl)Benzonitrile]; 2-(4-Tolyl)-Benzonitrile; 2-(4-Methylphenyl)Benzonitrile; 4'-Methyl[1,1'-Biphenyl]-2-Carbonitrile; 4'-Methyl-2-Biphenylcarbonitrile; 3-Benzylbenzonitrile; Benzonitrile, 3-(Phenylmethyl)-
CAS编号93717-55-6
MFCD编号:MFCD20489239
分子式:C14H11N分子量:193.25
产品CID: 1977220
产品分类有机原料 → 烃类化合物及其衍生物 → 芳香烃

相似结构搜索
InChIKey: GOFIMQVJGKCLGF-UHFFFAOYSA-N
InChI=1S/C14H11N/c15-11-14-8-4-7-13(10-14)9-12-5-2-1-3-6-12/h1-8,10H,9H2
计算化学: 氢键受体数1.0氢键供体数*可旋转键数2.0

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H302-H315-H319-H335
防范说明P261-P305+P351+P338
危险品标志Xn
安全声明36/37/39-26-22
危险类别码36/37/38-20/21/22

上下游产品

合成工艺路线路线简述

6952-59-6 + 329976-73-0 = 93717-55-6
反应条件:1.1 Reagents: Diisopropylethylamine Catalysts: Nickel,(2,2′-Bipyridine-Kn1,Kn1′)Dichloro-,(Sp-4-2)- (Functionalized With Carbon Nitride) Solvents: Tetrahydrofuran; 36 H,Rt
标题:Heterogeneous Metallaphotocatalytic C(Sp2)-C(Sp3) Cross-Coupling Reactions With Integrated Bipyridyl-Ni(Ii)-Carbon Nitride
作者:Dan,Xiao; Yang,Qian; Xing,Liuzhuang; Tang,Yurong; Wang,Wentao; Et Al
参考文献:Organic Letters 日期:2023 卷标:25(22) 页码:4124-4129]

640-60-8 = 93717-55-6
反应条件:1.1 Catalysts: Dichlorobis(Triphenylphosphine)Palladium,2′-[bis(1-Methylethyl)Phosphino]-6-Methoxy-N,N-Dimethyl[1,1′-Biphenyl]-2-Amine Solvents: 2-Methyltetrahydrofuran; 15 Min,Rt; Rt -> 80 °C; 6 H,80 °C1.2 Reagents: Water
标题:Synthesis Of Diarylmethanes Via Pd-Catalyzed Coupling Of Aryltosylates With Benzyltitanium Reagents
作者:Zhang,He
参考文献:Russian Journal Of General Chemistry 日期:2022 卷标:92(7) 页码:1340-1347]

98-80-6 + 28188-41-2 = 93717-55-6
反应条件:1.1 Reagents: Sodium Carbonate,Tri-O-Tolylphosphine Catalysts: Dichlorobis(Triphenylphosphine)Palladium Solvents: Acetonitrile,Water; 2 H,Reflux; Reflux -> Rt
标题:Preparation Of 4,5-Dihydro-1,2,4-Triazin-6-Ones And 1,2,4-Trianzin-6-Ones For Use As Fungicides
参考文献:World Intellectual Property Organization]

27798-39-6 = 93717-55-6
反应条件:1.1 Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Dimethylformamide; 2 D,95 °C
标题:Preparation Of Hydrazide,Amide,Phthalimide And Phthalhydrazide Analogs As Inhibitors Of Retroviral Integrase
参考文献:World Intellectual Property Organization]

6952-59-6 = 93717-55-6
反应条件:1.1 Reagents: Trifluoroacetic Acid,Allyl Chloride,Zinc Catalysts: Cobalt Dibromide Solvents: Acetonitrile; 3 Min,Rt1.2 Rt
标题:Synthesis Of Functionalized Diarylmethanes Via A Cobalt-Catalyzed Cross-Coupling Of Arylzinc Species With Benzyl Chlorides
作者:Amatore,Muriel; Gosmini,Corinne
参考文献:Chemical Communications (Cambridge 日期:2008 卷标:(40) 页码:5019-5021]

98-80-6 + 10406-24-3 = 93717-55-6
反应条件:1.1 Reagents: Isoamyl Nitrite,Sodium Carbonate Solvents: Chloroform; 24 H,60 °C
标题:Deaminative Coupling Of Benzylamines And Arylboronic Acids
作者:Sirvinskaite,Giedre; Reisenbauer,Julia C.; Morandi,Bill
参考文献:Chemical Science 日期:2023 卷标:14(7) 页码:1709-1714]

69113-59-3 + 1644578-02-8 = 93717-55-6
反应条件:1.1 Catalysts: Dichlorobis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran; 1 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Rt
标题:Alternative Approach Toward The Generation Of Benzylic Zinc Reagent: Direct Oxidative Addition Of Active Zinc Into The Carbon-Oxygen Bond Of Benzyl Mesylates
作者:Jung,Hye-Soo; Kim,Seung-Hoi
参考文献:Synlett 日期:2015 卷标:26(5) 页码:666-670]

150255-96-2 = 93717-55-6
反应条件:1.1 Reagents: Potassium Carbonate,Oxygen Catalysts: 2242836-60-6 Solvents: Ethanol,Water; 5 H,60 °C
标题:Picolinamide Modified β-Cyclodextrin/pd (Ii) Complex: Asupramolecular Catalyst For Suzuki-Miyaura Coupling Of Aryl,Benzyl And Allyl Halides With Arylboronic Acids In Water
作者:Luo,Kaixiu; Zhang,Lu; Yang,Rui; Jin,Yi; Lin,Jun
参考文献:Carbohydrate Polymers 日期:2018 卷标:200 页码:200-210]

= 93717-55-6 [标题:Reaction Conditions
标题:The Effect Of Meta- Or Para-Cyano Substitution On The Reactivity Of The Radical Cations Of Arylalkenes And Alkanes. Radical Ions In Photochemistry. Part 34
作者:Arnold,Donald R.; Du,Xinyao; Chen,Jing
参考文献:Canadian Journal Of Chemistry 日期:1995 卷标:73(3) 页码:307-18

📜3-(1-Phenylethenyl)Benzonitrile置于对苯二腈体系中,用甲醇,乙腈作为反应溶剂,化学反应生成 2-氰基-4'-甲基联苯
参考文献:Arnold,Donald R.; Du,Xinyao; Chen,Jing,Canadian Journal Of Chemistry,1995,Vol. 73,# 3,P. 307-318
标题:Arnold,Donald R.; Du,Xinyao; Chen,Jing,Canadian Journal Of Chemistry,1995,Vol. 73,# 3,P. 307-318