CAS: 18880-00-7; 1-(Bromomethyl)-4-(Tert-Butyl)Benzene

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CAS号50-00-0 甲醛 | CAS号98-51-1 4-叔丁基甲苯 | CAS号877-65-6 4-叔丁基苄醇 | CAS号1058648-68-2 4-tert-butyl-1-... | CAS号64-19-7 冰醋酸 | CAS号108-88-3 甲苯 | CAS号32857-63-9 4-叔丁基苯乙酸 | CAS号3288-99-1 对叔丁基苯乙腈 | CAS号93-68-5 2'-甲基乙酰乙酰苯胺(AAOT) | CAS号1373267-91-4 (4-tert-butylbe... | CAS号39895-55-1 4-叔丁基苄胺 | CAS号939-97-9 对叔丁基苯甲醛 | CAS号877-65-6 4-叔丁基苄醇 | CAS号4210-32-6 对叔丁基苯甲腈 | CAS号196505-83-6 2,3,4,5-tetraki... | CAS号98-51-1 4-叔丁基甲苯

4-叔丁基甲苯置于n-溴代丁二酰亚胺(Nbs),偶氮二异丁腈体系中,用 三氟甲苯 用作溶剂,化学反应 2.5H,以88%的收率获得4-叔丁基苄溴
参考文献:N-溴代琥珀酰亚胺在(三氟甲基)苯中的苄基溴化反应
标题:N-溴代琥珀酰亚胺在(三氟甲基)苯中的苄基溴化反应
摘要:在(2,2'-偶氮二异丁腈,1,1'-偶氮二(环己烷甲腈)或过氧化苯甲酰作为自由基引发剂的存在下,通过在(三氟甲基)苯中的n-溴琥珀酰亚胺在(三氟甲基)苯中进行光化学活化,进行了各种苄基溴化反应.该系统提供了清洁,快速和高产率的反应,并用毒性较小的三氟甲基苯代替了传统的溶剂,例如四氯甲烷. 苄基溴化-(三氟甲基)苯-自由基-N-溴代琥珀酰亚胺-偶氮二异丁腈
Doi:10.1055/s-0029-1216793

专利信息

专利号:US-6951932-B2
优先权日:2001-10-25
标 题:Synthesis of 2-aralkoxyadenosines and 2-alkoxyadenosines
发明人：MOORMAN ALLAN R
权利人:KING PHARMACEUTICALS RES & DEV
摘要:The invention provides new methods for synthesis of 2-aralkyloxyadenosines and 2-alkoxyadenosines. The invention is particularly useful for synthesis of 2-[2-(4-chlorophenyl)ethoxy]adenosine. Preferred methods of the invention include activating a guanosine compound followed by hydrolysis; alkylating the hydrolyzed compound with subsequent animation to provide a 2-aralkyloxyadenosine or a 2-alkoxyadenosine compound.

专利号:US-7884175-B2
优先权日:2003-04-17
标 题:Method for controlling the molecular weight during poly(arylene vinylene) synthesis, and polymers produced therewith
发明人：SPREITZER HUBERT; BECKER HEINRICH; HUFSKY ELFRIEDE
权利人:MERCK PATENT GMBH
摘要:The present invention relates to a process in which addition of certain bis(methyl)aryl compounds which have a further substituent other than hydrogen and on which at least one of the two methyl groups bears a leaving group, the molecular weight in the synthesis of poly(arylenevinylenes) is controlled reproducibly and can be deduced by the GILCH polymerization or by the sulfinyl precursor route, and to the polymers obtainable by means of the process according to the invention.

专利号:US-7915276-B2
优先权日:2006-02-14
标题 :Berberrubine derivatives having antifungal activities
发明人：KIM SUNG UK; PARK KI DUK; MOON JAE SUN; KANG TAE HOON; KIM YOUNG KOOK
权利人:KOREA RES INST OF BIOSCIENCE
摘要:The present invention relates to a berberrubine derivative having superior antifungal activity, more particularly to a berberrubine derivative having activity against chitin synthase, which participates in the synthesis of chitin and is essential in the growth of fungi, and having a potent antifungal activity against human pathogenic fungi.

专利号:US-6252082-B1
优先权日:1997-01-16
标 题 :Pyridone derivatives, their preparation and their use as synthesis intermediates
发明人：LASSALLE GILBERT; BELLEVERGUE PATRICE; BOURBIER JEAN-CLAUDE; GALTIER DANIEL; MARTIN VALERIE
权利人:SANOFI SYNTHELABO
摘要:The invention concerns compounds of formula (I)in which: R is -NO2 or -NHR3, R3 being hydrogen, -COR4 (R4 selected among (C1-C4) alkyl, aryl and aryl (C1-C4) alkyl, -COOR5 (R5 selected among (C1-C4) alkyl and aryl (C1-C4) alkyl), -CONHR6 or SO2R6 (R6 selected among (C1-C5) alkyl, aryl and aryl(C1-C4) alkyl), -SO2NR7R8 (R7 and R8 independently of each other represent hydrogen or (C1-C4) alkyl or form with the nitrogen atom a morpholine group), aryl (C1-C4) alkyl, R1 is a (C1-C4) alkyl group linear or branched, cyclo (C3-C8) alkyl, aryl optionally substituted, aryl (C1-C4) alkyl optionally substituted, heteroaryl, R2 is a hydrogen atom, a (C1-C4) alkyl or arylmethyl group, X is an oxygen or sulphur atom, a -CH2-, -SO2 or -NR1- group and Y is a hydrogen atom or (C1-C6) alkyl. The invention is applicable to synthesis intermediates.

专利号:US-2003199686-A1
优先权日:2001-10-25
标题:Synthesis of 2-aralkoxyadenosines and 2-alkoxyadenosines

专利号:US-11767302-B2
优先权日:2020-10-01
标题 :Reagents and methods for tetrazine synthesis
发明人：FOX JOSEPH M; LAMBERT WILLIAM; FANG YINZHI; AM ENDE CHRISTOPHER WILLIAM; MAHAPATRA SUBHAM; XIE YIXIN; WANG CHUANQI
权利人:UNIV DELAWARE
摘要:Disclosed herein are mono- and di-substituted tetrazines and methods of their preparation and converting an oxetanyl ester to a thio-substituted tetrazine, which is then converted to a mono-substituted tetrazine, a di-substituted tetrazine, or a vinylether disubstituted tetrazine.