CAS: 135158-54-2; Acibenzolar-S-Methyl

该化合物是一个系统性杀真菌剂和植物生长调节器,主要用于农业,以提高植物对各种病原体的抗药性;它作为系统获取抗药性(SAR)的诱发者,刺激植物的自然防御机制;该化合物的特点是对人类和非目标生物的毒性相对较低,在综合虫害管理中成为有利的选择;Acibenzolar-S-甲基通常作为一种叶喷雾剂使用,对包括下温和粉末温剂在内的一系列真菌疾病有效;其行动方式涉及激活具体的植物防御基因,导致产生病原蛋白;此外,它因其环境稳定性和土壤中的持久性较低而闻名,有助于其安全性.

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欧盟法规

统一分类与标签REACH注册ECHA物质工作场所安全标识要求ECHA物质欧盟农药活性物质C&L通报REACH预注册废弃物危险特性清单

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CAS号35272-27-6 阿拉酸式苯 | CAS号53553-14-3 2-氯-3-硝基苯甲酸甲酯 | CAS号3209-22-1 2,3-二氯硝基苯 | CAS号2497-91-8 2-氯-3,5-二硝基苯甲酸 | CAS号3970-35-2 2-氯-3-硝基苯甲酸 | CAS号179104-32-6 3-氯-2-(异丙基硫代)苯胺 | CAS号124371-57-9 2-benzylthio-3-... | CAS号124371-61-5 methyl 2-(pheny...

合成工艺路线路线简述

  • 合成目标产物 Acibenzolar-S-Methyl 主要起始原料 Acibenzolar Acid
  • (文献来源)合成步骤主要原料 Acibenzolar Acid
📜2-氯-3,5-二硝基苯甲酸置于镍 Sodium Hydroxide,氯化亚砜,水,氢气,氢气,Potassium Carbonate,Sodium Nitrite体系中,用 四氢呋喃,N,N-二甲基甲酰胺 用作溶剂,化学反应生成阿拉酸式苯-S-甲基
参考文献:The Chemistry Of Benzothiadiazole Plant Activators
标题:The Chemistry Of Benzothiadiazole Plant Activators
摘要:
Doi:10.1002/(Sici)1096-9063(199708)50:4<275::Aid-Ps593>3.0.Co;2-7

海关参考信息

专利信息


专利号:US-9068192-B2
优先权日:2009-01-28
标 题:Compositions and methods for conversion of aldehydes to alkanes
发明人:ZENG WEIQING; HE SHENG YANG
权利人:ZENG WEIQING; HE SHENG YANG; UNIV MICHIGAN STATE
摘要:The invention provides the discovery that SCD2 (Susceptible to Coronatine-Deficient Pst DC3118-2) protein converts aldehydes to alkanes, thereby changing the composition and/or amount of synthesized waxes. The invention additionally provides homologs, orthologs and paralogs of SCD2 protein, and nucleotide sequences encoding these proteins. Also provided are expression vectors, transgenic cells, transgenic plants, transgenic seeds, methods for altering alkane production in cells, methods for identifying the function of a nucleotide sequence in the synthesis of plant surface wax, and methods for identifying plant tissue that has an altered surface wax composition. The invention's compositions and methods are useful for altering the amount and/or composition of wax produced by cells, including plants and seeds, that have been transformed with the invention's sequences.

专利号:WO-2025056767-A1
优先权日:2023-09-15
标题 :Process for the preparation of enantiomerically enriched aliphatic amines
发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
权利人:SYNGENTA CROP PROTECTION AG
摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

专利号:US-2016073631-A1
优先权日:2013-03-04
标 题 :Process for the preparation of dihydropyrrole derivatives
发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).

专利号:US-9968097-B2
优先权日:2012-05-30
标题:Composition comprising a biological control agent and a fungicide selected from inhibitors of the lipid membrane synthesis, the melanine biosynthesis, the nucleic acid synthesis or the signal transduction
发明人:WACHENDORFF-NEUMANN ULRIKE; ANDERSCH WOLFRAM; STENZEL KLAUS; SPRINGER BERND
权利人:BAYER CROPSCIENCE AG
摘要:The present invention relates to a composition comprising at least one biological control agent. Furthermore, the present invention relates to the use of this composition as well as a method for reducing overall damage of plants and plant parts.

专利号:US-5696091-A
优先权日:1993-09-29
标 题 :Use of growth factor and antimetabolite combination to prevent or retard secondary cataract formation
发明人:YORK BILLIE M; NIXON JON C; SAMS KAREN C
权利人:ALCON LAB INC
摘要:The intraocular use of combinations of lens epithelial cell growth stimulators (e.g., TGF-β) and antimetabolites (e.g., mitomycin C) is described. The combination is applied to the capsular bag to prevent or retard the formation of secondary cataracts following cataract surgery. The lens epithelial cell stimulators activate DNA synthesis in dormant lens epithelial cells, and thereby make those cells susceptible to the anti-metabolites. This enables the antimetabolites to suppress the proliferation of lens epithelial cells to a much greater extent, relative to the proliferation observed when the metabolites alone are utilized. The increased suppression of the growth of lens epithelial cells results in a significant improvement in the ability to prevent or retard the formation of opacities on the lens capsule (i.e., secondary cataracts).

专利号:WO-2019218027-A1
优先权日:2018-05-18
标题:Core-shell particles
发明人:MEANEY SHANE; TABOR RICHARD; FOLLINK BART
权利人:UNIV MONASH
摘要:The application relates to a core-shell particle having a) a cross-linked polyelectrolyte core, and b) a silica-based shell having covalently bound thereto one or more groups of formula –R–F, wherein R is an organic group and F is a functional moiety. The application also relates to a method of synthesis of a core-shell particle, the method comprising the steps of: a) providing a cross-linked polyelectrolyte core template, b) coating the core template with a silica-based shell, and c) introducing one or more groups of formula –R–F covalently bound to the silica-based shell, wherein R is an organic group and F is a functional moiety.

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📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献


1: Sleiman M, de Sainte Claire P, Richard C. Heterogeneous Photochemistry of Agrochemicals at the Leaf Surface: A Case Study of Plant Activator Acibenzolar-S-methyl. J Agric Food Chem. 2017 Sep 6;65(35):7653-7660. doi: 10.1021/acs.jafc.7b02622. Epub 2017 Aug 21. doi: 10.3389/fpls.2017.01224. eCollection 2017.
3: Lavergne F, Richard C, Saudreau M, Venisse JS, Fumanal B, Goupil P. Effect of acibenzolar-S-methyl phototransformation on its elicitation activity in tobacco cells. Plant Physiol Biochem. 2017 Sep;118:370-376. doi: 10.1016/j.plaphy.2017.07.008. Epub 2017 Jul 8. eCollection 2016.
5: Schouteden N, Lemmens E, Stuer N, Curtis R, Panis B, De Waele D. Direct nematicidal effects of methyl jasmonate and acibenzolar-S-methyl against Meloidogyne incognita. Nat Prod Res. 2017 May;31(10):1219-1222. doi: 10.1080/14786419.2016.1230111. Epub 2016 Sep 23. doi: 10.1002/ps.4303. Epub 2016 May 26. doi: 10.1080/03601234.2014.911556. doi: 10.1094/PHYTO-08-12-0188-R. doi: 10.1002/ps.2277. Epub 2011 Aug 30. doi: 10.1080/03601234.2011.583881. doi: 10.1002/ps.1969. doi: 10.1016/j.febslet.2010.06.046. Epub 2010 Jul 14. doi: 10.1186/1756-0500-3-43.

合成参考文献


参考文献:10.1002/ps.2243
摘要:Mautino GC, Bosco L, Tavella L. Integrated management of Thrips tabaci (Thysanoptera: Thripidae) on onion in north‐western Italy: basic approaches for supervised control. Pest Management Science. 2011 Jul 18;68(2):185–93. doi: 10.1002/ps.2243.
参考文献:10.1007/s00299-011-1119-6
摘要:Burlini N, Iriti M, Daghetti A, Faoro F, Ruggiero A, Bernasconi S. Benzothiadiazole (BTH) activates sterol pathway and affects vitamin D3 metabolism in Solanum malacoxylon cell cultures. Plant Cell Rep. 2011 Nov;30(11):2131–41. doi: 10.1007/s00299-011-1119-6.
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