CAS: 121356-12-5; (2R,3S,4R,5R,6S)-5-Acetamido-2-(Acetoxymethyl)-6-(Naphthalen-1-Yloxy)Tetrahydro-2H-Pyran-3,4-Diyl Diacetate

该化合物是用于大气生物学和碳水化合物化学研究的一种专门的甘蓝衍生物,其主要结构特征包括:环球乙酰丙烯酮和全氟辛烷磺胺,使其对酶和化学聚合物研究具有价值;乙酰保护组增强有机溶剂的稳定性和溶性,促进合成应用;该化合物是合成更复杂的甘蓝球门的中间体,包括寡头藻和甘蓝蛋白.其定义明确的立体化学学确保了在同源反应中的可复制性,而环球组则允许在分析分析分析中进行基于紫外线的检测.研究人员利用该化合物来检测玻璃晶素机制或作为生物活性分子发育的前体.

英文名称(2R,3S,4R,5R,6S)-5-Acetamido-2-(Acetoxymethyl)-6-(Naphthalen-1-Yloxy)Tetrahydro-2H-Pyran-3,4-Diyl Diacetate
中文名称(2R,3S,4R,5R,6S)-5-乙酰氨基-2-(乙酰氧基甲基)-6-(萘-1-基氧基)四氢-2H-吡喃-3,4-二乙酸二酯
IUPAC名称(2R,3S,4R,5R,6S)-5-acetamido-2-(acetoxymethyl)-6-(naphthalen-1-yloxy)tetrahydro-2H-pyran-3,4-diyl diacetate
其它别名1-萘基 2-乙酰氨基-3,4,6-O-三乙酰基-2-脱氧-Beta-D-吡喃葡萄糖苷; (1'-Naphthyl) 2-Acetamido-3,4,6-Tri-O-Acetyl-2-Deoxy-Beta-D-Glucopyranoside
CAS编号121356-12-5
MFCD编号:MFCD08703862
分子式:C24H27NO9分子量:473.48
产品CID: 291112
产品分类有机原料→分子砌块→手性化合物→手性砌块

相似结构搜索
InChIKey: TWFPJHVIRXYIGJ-MRKXFKPJSA-N
InChI=1S/C24H27NO9/c1-13(26)25-21-23(32-16(4)29)22(31-15(3)28)20(12-30-14(2)27)34-24(21)33-19-11-7-9-17-8-5-6-10-18(17)19/h5-11,20-24H,12H2,1-4H3,(H,25,26)/t20-,21-,22-,2
计算化学: 氢键受体数9.0氢键供体数1.0可旋转键数7.0

相似化合物

10329-98-3 19939-82-3 41335-32-4

MSDS等安全信息

上下游产品

2-acetamido-3,4,6-tri-O-acetyl-D-glucopyranosyl acetate α-naphthol Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester 1,3,4,6-tetra-O-acetyl-2-amino-2-deoxy-α-D-glucopyranose hydr°Chloride 1-naphthyl 2-acetamido-2-deoxy-β-D-glucopyranoside

合成工艺路线路线简述

📜β-D-葡萄糖胺五乙酸酯置于盐酸,Sodium Hydroxide,乙酸酐,丙酮体系中,化学反应生成1-萘基 2-乙酰氨基-3,4,6-O-三乙酰基-2-脱氧-Beta-D-吡喃葡萄糖苷
参考文献:958. The Preparation And Properties Of Acetochloroglucosamine And Its Use In The Synthesis Of 2-Acetamido-2-Deoxy-β-D-Glucosides (N-Acetyl-β-D-Glucosaminides)
标题:958. The Preparation And Properties Of Acetochloroglucosamine And Its Use In The Synthesis Of 2-Acetamido-2-Deoxy-β-D-Glucosides (N-Acetyl-β-D-Glucosaminides)
摘要:
Doi:10.1039/jr9570004754