Tebuconazole置于sodium Hydroxide体系中,用 N-甲基吡咯烷酮,二氯甲烷,水 用作溶剂,以93.8%的收率获得戊唑醇 参考文献:Process For The Preparation Of .Beta.-Hydroxyethyl-(1,2,4-Triazole) 标题:Process For The Preparation Of .Beta.-Hydroxyethyl-(1,2,4-Triazole) 摘要:已知的β-羟乙基-(1,2,4-三唑)衍生物的化学式为##str1##其中r1代表烷基,卤代烷基,烯基,炔基,可选取代的环烷基,可选取代的环烯基,可选取代的芳基,可选取代的芳基烷基,可选取代的芳基烯基或可选取代的杂环基;R2代表氢,烷基,卤代烷基,烯基,炔基,可选取代的环烷基,可选取代的环烯基,可选取代的芳基,可选取代的芳基烷基,可选取代的芳基烯基或可选取代的杂环基.这些衍生物是通过一种新的方法制备的,该方法包括在无极性,双极溶剂的存在下,在碱的存在下搅拌化合物β-羟乙基-(1,3,4-三唑)的衍生物##str2##其中r1和r2具有上述含义.
专利号:US-2024076303-A1 优先权日:2022-09-07 标 题:Green Synthesis of Salicylaldehydate-Metal-Organic Frameworks and Applications Thereof 发明人:SHETTY DINESH; MOHAMMED ABDUL KHAYUM 权利人:UNIV KHALIFA SCIENCE & TECHNOLOGY 摘要:Embodiments of the present disclosure generally describe two-dimensional/three-dimensional conjugated salicylaldehydate metal organic framework (2D/3D-c-SA MOF) compositions, method for green synthesis of the two-dimensional/three-dimensional conjugated salicylaldehydate metal organic framework (2D/3D-c-SA MOF) compositions, applications of the said compositions in supercapacitors, lithium-ion batteries, electrocatalytic conversion reactions, photocatalytic reduction of CO 2 and other uses.
专利号:US-2025296849-A1 优先权日:2021-04-16 标 题:Method of making silver-iron titanate nanoparticles and uses thereof 发明人:SENEVIRATNE KASUN LAKNATH; MUNAWEERA IMALKA; PEIRIS SRIYANI EDUSSURIYA; PEIRIS COLIN NISANTHA; KOTTEGODA NILWALA 权利人:SRI LANKA INSTITUTE OF INFORMATION TECH 摘要:High quality silver-iron titanate nanoparticles are synthesized using an ilmenite source. The silver-iron titanate nanoparticles were characterized using various analytical techniques. As compared to prior art methods, the disclosed methods provide for the simple, cost-effective synthesis of relatively high-quality silver-iron titanate nanoparticles. The silver-iron titanate nanoparticles can be used in a variety of important agricultural, industrial, and hygienic uses, including in the important area of plant tissue culture explant sterilization.
专利号:US-2023399234-A1 优先权日:2022-06-14 标题 :Synthesis of nano-sized zeolites 发明人:RIMER JEFFREY D; PARMAR DEEPENDRA; MALLETTE ADAM 权利人:UNIV HOUSTON SYSTEM 摘要:Nano-sized zeolites may be prepared using germanium oxide (GeO 2 ) as a component of the overall synthesis composition. This is accomplished by the addition of GeO 2 as an inexpensive reagent for the synthesis gel. Most of the Ge is retained in the synthesis mixture and the small amount incorporated in the zeolite solid (Si/Ge>100) does not have an appreciable impact on zeolite acidity or other physicochemical properties. The methods disclosed herein circumvent challenges to prepare nano-sized zeolites having dimensions less than 100 nm.
专利号:EP-3967330-A1 优先权日:2020-09-10 标 题:Methods for the synthesis of bioactivated metal nanocluster and their medical application 发明人:MARCHI VALÉRIE; CHIECHIO REGINA MARIA; EVEN-HERNANDEZ PASCALE 权利人:UNIV RENNES; CENTRE NAT RECH SCIENT; INSTITUT NAT DES SCIENCES APPLIQUEES DE RENNES; ECOLE NAT SUPERIEURE DE CHIMIE DE RENNES 摘要:The present invention relates to a bioactivated metal nanocluster comprising a mixture of ligands linked to a fluorescent metallic nanocluster, their synthesis methods, and their medical applications.
专利号:WO-2025056767-A1 优先权日:2023-09-15 标题 :Process for the preparation of enantiomerically enriched aliphatic amines 发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS 权利人:SYNGENTA CROP PROTECTION AG 摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.
专利号:US-2016073631-A1 优先权日:2013-03-04 标 题 :Process for the preparation of dihydropyrrole derivatives 发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS 权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD 摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).
1: Ren J, Jin X, Zhang Q, Zheng Y, Lin D, Yu Y. Fungicides induced triazole-resistance in Aspergillus fumigatus associated with mutations of TR46/Y121F/T289A and its appearance in agricultural fields. J Hazard Mater. 2016 Dec 10;326:54-60. doi: 10.1016/j.jhazmat.2016.12.013. [Epub ahead of print] doi: 10.1371/journal.pone.0167485. 4: Roszko MŁ, Kamińska M, Szymczyk K, Jędrzejczak R. Levels of Selected Persistent Organic Pollutants (PCB, PBDE) and Pesticides in Honey Bee Pollen Sampled in Poland. PLoS One. 2016 Dec 1;11(12):e0167487. doi: 10.1371/journal.pone.0167487. 5: Kim JO, Shin JH, Gumilang A, Chung K, Choi KY, Kim KS. Effectiveness of Different Classes of Fungicides on Botrytis cinerea Causing Gray Mold on Fruit and Vegetables. Plant Pathol J. 2016 Dec;32(6):570-574.
合成参考文献
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