2942-15-6 = 88-44-8 反应条件:1.1 Reagents: Chloramine-T,Sodium Hydroxide Catalysts: Chloro[2-[[(1H-Pyrrol-2-Yl-Kn)Methylene]Amino-Kn]Phenolato(2-)-Ko]Bis(Triphenylp... Solvents: Acetonitrile,Water; 40 - 80 °C 标题:Chloramine-T 作者:Goehring,R. Richard; Et Al 参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2013 卷标:1 页码:1-8]
= 88-44-8 反应条件:1.1 0.5 Min,Heated 标题:Preparation,Crystal Structure And Microwave Studies On Ring-Substituted Arylammonium Hydrogen Sulfate Salts 作者:Kapoor,I. P. S.; Et Al 参考文献:Indian Journal Of Chemistry 日期:2007 卷标:(8) 页码:1283-1288]
104613-64-1 = 88-44-8 反应条件:1.1 Reagents: Chlorosulfonic Acid; 1 H,0 °C; 2 H,80 °C 标题:Synthesis And Reactivity Of Neutral Palladium(Ii) Alkyl Complexes That Contain Phosphinimine-Arenesulfonate Ligands 作者:Burns,Christopher T.; Et Al 参考文献:Organometallics 日期:2015 卷标:34(10) 页码:1844-1854]
83350-95-2 = 88-44-8 反应条件:1.1 Reagents: Water Solvents: Water 标题:Sulfonation Of Aromatic Isocyanates. Sulfonated P-Tolylisocyanate - X-Ray Structural Analysis 作者:Balle,Gerhard; Et Al 参考文献:Angewandte Chemie 日期:1982 卷标:94(11) 页码:872-3]
= 88-44-8 反应条件:1.1 Reagents: Sodium Sulfite Solvents: Water2.1 - 标题:The Piria Reaction. Iii. Mechanism Studies 作者:Lauer,Walter M.; Et Al 参考文献:Journal Of The American Chemical Society 日期:1936 卷标:58 页码:225-8]
2942-15-6 = 88-44-8 反应条件:1.1 Reagents: Sodium Hydroxide,Benzenesulfonamide,N-Bromo-,Sodium Salt (1:1) Catalysts: Chloro[2-[[(1H-Pyrrol-2-Yl-Kn)Methylene]Amino-Kn]Phenolato(2-)-Ko]Bis(Triphenylp... Solvents: Acetonitrile,Water; 4 H,313 K 标题:Development Of An Efficient Ruthenium Catalyzed Synthetic Process And Mechanism For The Facile Conversion Of Benzothiazoles To Orthanilic Acids 作者:Jagadeesh,R. V.; Et Al 参考文献:Journal Of Molecular Catalysis A: Chemical 日期:2010 卷标:328(1-2) 页码:99-107]
622-58-2 = 88-44-8 反应条件:1.1 Reagents: Sulfur Trioxide2.1 Reagents: Water Solvents: Water 标题:Sulfonation Of Aromatic Isocyanates. Sulfonated P-Tolylisocyanate - X-Ray Structural Analysis 作者:Balle,Gerhard; Et Al 参考文献:Angewandte Chemie 日期:1982 卷标:94(11) 页码:872-3]
= 88-44-8 反应条件:1.1 Reagents: Iron,Hydrochloric Acid Solvents: Water2.1 Reagents: Sulfuric Acid Solvents: 1,2-Dichlorobenzene 标题:Synthesis Technology Of 4B Acid 作者:Cui,Yumin; Et Al 参考文献:Huaxue Fanying Gongcheng Yu Gongyi 日期:2001 卷标:17(2) 页码:189-191]
2810945-93-6 = 88-44-8 + 600-77-1 反应条件:1.1 Reagents: Trifluoroacetic Acid Catalysts: Ferrous Sulfate Solvents: Dichloromethane; 18 H,40 °C 标题:An Aminative Rearrangement Of O-(Arenesulfonyl)Hydroxylamines: Facile Access To Ortho-Sulfonyl Anilines 作者:Morrill,Charlotte; Et Al 参考文献:Angewandte Chemie 日期:2022 卷标:61(33)]
= 88-44-8 [标题:Reaction Conditions 标题:The Piria Reaction. Iii. Mechanism Studies 作者:Lauer,Walter M.; Et Al 参考文献:Journal Of The American Chemical Society 日期:1936 卷标:58 页码:225-8]
1899-93-0 + 36016-38-3 = 88-44-8 + 600-77-1 反应条件:1.1 Reagents: Triethylamine Solvents: Diethyl Ether; 0 °C; 2 - 16 H,Rt2.1 Reagents: Trifluoroacetic Acid Catalysts: Ferrous Sulfate Solvents: Dichloromethane; 18 H,40 °C 标题:An Aminative Rearrangement Of O-(Arenesulfonyl)Hydroxylamines: Facile Access To Ortho-Sulfonyl Anilines 作者:Morrill,Charlotte; Et Al 参考文献:Angewandte Chemie 日期:2022 卷标:61(33)]
= 88-44-8 反应条件:1.1 Reagents: Sodium Carbonate Solvents: Water2.1 - 标题:The Piria Reaction. Iii. Mechanism Studies 作者:Lauer,Walter M.; Et Al 参考文献:Journal Of The American Chemical Society 日期:1936 卷标:58 页码:225-8]
= 88-44-8 反应条件:1.1 Reagents: Sodium Bisulfite Solvents: Water2.1 - 标题:The Piria Reaction. Iii. Mechanism Studies 作者:Lauer,Walter M.; Et Al 参考文献:Journal Of The American Chemical Society 日期:1936 卷标:58 页码:225-8
4-甲基乙酰苯胺置于硫酸体系中,化学反应生成 4-氨基甲苯-3-磺酸 参考文献:Scott; Cohen,Journal Of The Chemical Society,1923,Vol. 123,P. 3187 标题:Scott; Cohen,Journal Of The Chemical Society,1923,Vol. 123,P. 3187
专利号:US-5189206-A 优先权日:1989-03-16 标题 :Process for the preparation of aminobenzenesulfonic acids 发明人:HERZIG PAUL 权利人:CIBA GEIGY CORP 摘要:There is disclosed a process for the preparation of compounds of formula ##STR1## wherein the symbols are as defined in claim 1, which process comprises dissolving a compound of formula ##STR2## in sulfuric acid, adding this solution to oleum and reacting the mixture in the temperature range from 10° to 80° C. until a sulfo group has been completely introduced, and, in an optional further step, subjecting the reaction mixture to further reaction in the temperature range from 100° to 200° C. to introduce a second sulfo group. n The compounds of formula (1) obtainable by this process are useful intermediates for the synthesis of dyes and are particularly suitable diazo components for the synthesis of azo dyes.
专利号:US-5366546-A 优先权日:1991-11-23 标 题 :Production of pigment compositions 发明人:MCCRAE JAMES M; KEIRS ANNE M; NIMMO JOHN A 权利人:CIBA GEIGY CORP 摘要:A process for the production of a pigment composition, comprising combining a) a dispersion of one or more non-polar components of a surface coating vehicle, or a non-polar additive for the pigment composition in an aqueous solution of a salt of a polar pigment additive, with b) an aqueous slurry of a pigment or a precursor thereof, before, during or after the synthesis of the pigment; and then isolating the pigment composition so obtained.
专利号:US-2017121258-A1 优先权日:2014-04-10 标题 :Synthesis of r-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols 发明人:SANBORN ALEXANDRA; BINDER THOMAS P 权利人:ARCHER DANIELS MIDLAND CO 摘要:Disclosed herein are methods for synthesizing 1,2,5,6-hexanetetrol (HTO), 1,6 hexanediol (HDO) and other reduced polyols from C5 and C6 sugar alcohols or R glycosides. The methods include contacting the sugar alcohol or R-glycoside with a copper catalyst, most desirably a Raney copper catalyst with hydrogen for a time, temperature and pressure sufficient to form reduced polyols having 2 to 3 fewer hydoxy groups than the starting material. When the starting compound is a C6 sugar alcohol such as sorbitol or R-glycoside of a C6 sugar such as methyl glucoside, the predominant product is HTO. The same catalyst can be used to further reduce the HTO to HDO.
专利号:US-10519124-B2 优先权日:2014-04-10 标题 :Synthesis of R-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols 发明人:STENSRUD KENNETH; Ma chi-cheng; MARTIN KEVIN 权利人:ARCHER DANIELS MIDLAND CO 摘要:Disclosed herein are methods for synthesizing 1,2,5,6-hexanetetrol (HTO), 1,6 hexanediol (HDO) and other reduced polyols from C5 and C6 sugar alcohols or R glycosides. The methods include contacting the sugar alcohol or R-glycoside with a copper catalyst, most desirably a Raney copper catalyst with hydrogen for a time, temperature and pressure sufficient to form reduced polyols having 2 to 3 fewer hydoxy groups than the starting material. When the starting compound is a C6 sugar alcohol such as sorbitol or R-glycoside of a C6 sugar such as methyl glucoside, the predominant product is HTO. The same catalyst can be used to further reduce the HTO to HDO.
专利号:US-5190585-A 优先权日:1988-10-06 标 题 :Production of pigment compositions 发明人:MCCRAE JAMES M; FORSYTHE NEIL C W 权利人:CIBA GEIGY CORP 摘要:The present invention provides processes for the production of a pigment composition comprising: Ia) contacting a pigment, before or during its synthesis, with a water-immiscible carrier medium, and then completing the pigment synthesis to produce a pigment composition comprising the pigment and the water-immiscible carrier medium, and Ib) contacting the resulting aqueous fully-synthesized pigment composition with an aliphatic organic acid and optionally a water-immiscible carrier medium; adjusting the pH value of the mixture so obtained to below 7.0; and then adjusting to the pH value of the mixture to a value above 7.0 thereby transferring the organic acid into the aqueous phase; and isolating a pigment composition comprising the pigment and the water-immiscible carrier medium, or II) contacting an aqueous fully-synthesized pigment slurry with an aliphatic organic acid and a water-immiscible carrier medium according to above step Ib).
专利号:US-4719053-A 优先权日:1980-08-01 标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates 发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD 权利人:HOECHST AG 摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.
参考标题:Synthesis Of R-Glucosides, Sugar Alcohols, Reduced Sugar Alcohols, And Furan Derivatives Of Reduced Sugar Alcohols 摘要:Disclosed Herein Are Methods For Synthesizing 1,2,5,6-Hexanetetrol (Hto), 1,6 Hexanediol (Hdo) And Other Reduced Polyols From C5 And C6 Sugar Alcohols Or R Glycosides. The Methods Include Contacting The Sugar Alcohol Or R-Glycoside With A Copper Catalyst, Most Desirably A Raney Copper Catalyst With Hydrogen For A Time, Temperature And Pressure Sufficient To Form Reduced Polyols Having 2 To 3 Fewer Hydoxy Groups Than The Starting Material. When The Starting Compound Is A C6 Sugar Alcohol Such As Sorbitol Or R-Glycoside Of A C6 Sugar Such As Methyl Glucoside, The Predominant Product Is Hto. The Same Catalyst Can Be Used To Further Reduce The Hto To Hdo.