CAS: 4433-13-0; 4,4'-Divinyl-1,1'-Biphenyl

该化合物是一个有机化合物,其特征为联苯结构,其中两个联苯环由一个单一的债券连接,该复合体具有联苯框架各位置附属的两个电子(乙烯)组,这增强了联苯框架在聚合化学和材料科学方面的回弹性和潜在应用,在聚合物化学和材料科学中具有更大的回弹力和潜在应用,在室温和展示特性时通常具有固体性,如良好的热稳定性和进行聚合的能力,使其在合成各种聚合物和共聚物时有用.

结构式图片

相似化合物

2350-89-2 38383-51-6 644-08-6

物理性质

MSDS等安全信息

上下游产品

4,4'-二甲基联苯 (4,4'-Dimethyl-1,1'-Biphenyl) 613-33-2
联苯二氯苄 4,4'-Bis(Chloromethyl)Biphenyl 1667-10-3
4,4'-二乙炔基联苯 4,4'-Diethynylbiphenyl 38215-38-2
4-Vinyl-4'-α-Hydroxyethyl-Biphenyl 209738-38-5
4,4'-苯偶酰氯 4,4'-Biphenyldicarboxylic Acid Dichloride 2351-37-3
1,1'-([1,1'-Biphenyl]-4,4'-Diyl)Diethanol
4,4'-二乙酰联苯 4,4'-Diacetylbiphenyl 787-69-9

合成工艺路线路线简述

  • 合成目标产物 4,4'-Divinylbiphenyl 主要起始原料 4-Vinylphenylboronic Acid
  • (文献来源)合成步骤主要原料 4-Vinylphenylboronic Acid
4,4'-二乙酰联苯置于aluminum Isopropoxide,异丙醇体系中,化学反应生成 4,4'-二乙烯基联苯
参考文献:Preparation Of 4,4'-Divinyl-Biphenyl
标题:Preparation Of 4,4'-Divinyl-Biphenyl

海关参考信息

专利信息


专利号:WO-2005005358-A1
优先权日:2003-07-01
标 题 :Process for the synthesis of bisphenol

专利号:WO-2004054949-A1
优先权日:2002-12-12
标 题 :Process for the synthesis of bisphenol

专利号:RU-2402521-C2
优先权日:2004-02-05
标题 :Synthesis of bisphenol a with low isomerisation

专利号:US-10729623-B2
优先权日:2015-05-08
标 题:Method for producing elliptical, needle-shaped, or rod-shaped polymer particles
发明人：HAYAKAWA KAZUTOSHI; HASHIBA TOSHIFUMI; MATSUZAKA ERINA; YAMADA Goki
权利人:NISSHINBO HOLDINGS INC
摘要:A method for producing elliptical, needle-shaped, or rod-shaped polymer particles satisfying (1)-(3) below includes a step in which a synthesis solution including water, a mixed solvent of a hydrophilic organic solvent and a hydrophobic organic solvent, a polymeric stabilizer, a polymerization initiator, and an unsaturated monomer is heated, and, at least after the heating has started, the pH of the synthesis solution is adjusted to 5-9 inclusive to perform solution polymerization: (1) the average (L AV ) length (L) in a two-dimensional projection diagram obtained by irradiating the particles with light from a direction orthogonal to the longitudinal direction is 0.1-80 μm; (2) the average (D AV ) breadth (D) in the two-dimensional projection diagram obtained by irradiating the particles with light from the direction orthogonal to the longitudinal direction is 0.05-40 μm; and (3) the average (P AV ) aspect ratio (L/D) calculated from the length (L) and the breadth (D) is 1.5-30.

专利号:JP-2006509818-A
优先权日:2002-12-12
标题 :Synthesis method of bisphenol

专利号:CN-114835741-A
优先权日:2022-04-20
标题 :A kind of quaternary carbogem disilyl compound containing three silicon-hydrogen bonds and its synthesis method and application

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主要参考文献

参考标题:Trans-Directing Ability Of The Amide Group: Enabling The Enantiocontrol In The Synthesis Of 1,1-Dicarboxy Cyclopropanes. Reaction Development, Scope, And Synthetic Applications
作者:David Marcoux,Sébastien R. Goudreau,André B. Charette |发布日期:2009.12.4
摘要:Enantioselective Formation Of 1,1-Cyclopropane Diesters Via The Metal-Catalyzed Cyclopropanation Of Olefins. The Strategies Envisioned To Achieve Such A Goal Are Discussed As Well As The Results That Led Us To The Discovery Of The Powerful Trans-Directing Ability Of The Amide Group In Rh(II)-Catalyzed Cyclopropanation Reactions. We Show How This Feature Enables A Solution For The Stereoselective Synthesis

合成参考文献


参考文献:10.1007/978-4-431-54198-1_5
摘要:Hasegawa G. Fabrication of Activated Carbon Monoliths with Well-Defined Macropores Derived from Sulfonated Poly(divinylbenzene) Networks. 2012 Oct 04. In: Springer Theses.
参考文献:10.1055/s-0036-1591602
摘要:Pietraszuk C, Ostrowska S, Rogalski S, Lorkowski J, Walkowiak J. Efficient Homocoupling of Aryl- and Alkenylboronic Acids in the Presence of Low Loadings of [{Pd(μ–OH)Cl(IPr)}2]. Synlett. 2018 Jul 10;29(13):1735–40. doi: 10.1055/s-0036-1591602.
参考文献:10.1007/978-3-030-73488-6_1
摘要:Dujardin C, Hamel M. Introduction—Overview on Plastic and Inorganic Scintillators. 2021. In: Topics in Applied Physics.
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