CAS: 24940-57-6; N,N-Dimethyl-L-Histidine

相似化合物

1217840-61-3 534-30-5 1217608-75-7

上下游产品

formaldehyd L-histidine L-histidine monohydr°Chlorideα-N,N,N-trimethylhistidine

📜聚合甲醛,L-组氨酸盐酸盐置于palladium On Activated Charcoal,氢气体系中,用 水 用作溶剂,化学反应 0.83H,反应生成N,N-二甲基-L-组氨酸
参考文献:Pelianthinarubins A和b,来自蘑菇mycena Pelianthina子实体的红色吡咯啉喹啉生物碱
标题:Pelianthinarubins A和b,来自蘑菇mycena Pelianthina子实体的红色吡咯啉喹啉生物碱
摘要:Pelianthinarubin A(1)和pelianthinarubin B(2),两个以前未知的吡咯并喹啉生物碱,已从mycena Pelianthina的子实体中分离出来.这些生物碱的结构已从其hr-(+)-Esims和2D NMR数据推导出来.通过分析noe相关性和耦合常数,并通过比较1和2的cd光谱以及通过用合适的已知化合物降解1而得到的海西宁分配pelianthinarubins A(1)和b(2)的绝对构型.绝对配置.Pelianthinarubins A(1)和b(2),其中含有一个s-海西林部分,与海洋生物和其他mycena物种(如mycenarubins,Haematopodins和sanguinones)的吡咯并喹啉生物碱有很大的不同.
Doi:10.1021/acs.Jnatprod.5B00942

专利信息

专利号:US-8835477-B2
优先权日:2009-10-06
标题 :Method for the synthesis of 2-thiohistidine and the like
发明人：ERDELMEIER IRÈNE; DAUNAY SYLVAIN
权利人:ERDELMEIER IRÈNE; DAUNAY SYLVAIN; TETRAHEDRON
摘要:Methods for the synthesis of 2-thiohistidine or a derivative thereof of the formula (I), or of a physiologically acceptable salt, a tautomer, a stereoisomer or a mixture of stereoisomers in any proportions thereof, from a compound of the formula (II) or a physiologically acceptable salt, a tautomer, a stereoisomer or a mixture of stereoisomers in any proportions thereof, by cleavage reaction in the presence of a thiol at a temperature higher than or equal to 60° C. The invention also relates to compounds of the formula (II) and a method for the synthesis thereof.

专利号:US-2012330029-A1
优先权日:2009-10-06
标题 :Method for the synthesis of 2-thiohistidine and the like

专利号:WO-2011042478-A1
优先权日:2009-10-06
标 题 :Method for the synthesis of 2-thiohistidine and the like

专利号:CN-116855467-A
优先权日:2022-05-03
标 题 :A chemical-enzyme coupling method for the synthesis of ergothioneine

专利号:CN-117083377-A
优先权日:2022-05-03
标题 :A chemical-enzyme coupling method for the synthesis of ergothioneine

专利号:CN-107108520-B
优先权日:2014-09-22
标 题 :Process for the synthesis of ergothioneine and related compounds