CAS: 123-02-4; Tridecylbenzene

相似化合物

123-01-3 2189-60-8 4445-07-2

上下游产品

CAS号770-09-2 苄基三甲基硅烷 | CAS号143-15-7 溴代十二烷 | CAS号140-29-4 苯乙腈 | CAS号546-67-8 四乙酸铅 | CAS号544-63-8 肉豆蔻酸 | CAS号71-43-2 苯 | CAS号2050-77-3 1-碘癸烷 | CAS号1462-75-5 3-PHENYL PROPAN... | CAS号766-04-1 BENZYLLITHIUM | CAS号6711-19-9 methanidylbenzene

📜2-Phenyltetradecanenitrile置于bis(Acetylacetonate)Nickel(II),1,1,3,3-四甲基二硅氧烷,三甲基铝,三环己基膦体系中,用 甲苯 用作溶剂,化学反应 24.0H,以74%的收率获得十三烷基苯
参考文献:Nickel-Catalyzed Decyanation Of Inert Carbon-cyano Bonds
标题:Nickel-Catalyzed Decyanation Of Inert Carbon-cyano Bonds
摘要:镍催化的芳基和脂肪族氰化物的脱氰化反应已发展起来,以氢硅烷作为氢源.这种方法易于操作,可扩展,并且无需在手套箱中进行.该方法已被应用于氰基导向的功能化反应以及苄基氰的α-取代反应中.
Doi:10.1039/c2Cc36883H

专利信息

专利号:US-7652164-B2
优先权日:2005-09-13
标题:Process for the direct synthesis of trialkoxysilane
发明人：LEWIS KENRICK M; MEREIGH ABELLARD T; O'YOUNG CHI-LIN; CAMERON RUDOLPH A
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:The Direct Synthesis of trialkoxysilane is carried out by conducting the Direct Synthesis reaction of silicon and alcohol, optionally in solvent, in the presence of a catalytically effective amount of Direct Synthesis catalyst and an effective catalyst-promoting amount of Direct Synthesis catalyst promoter, said promoter being an organic or inorganic compound possessing at least one phosphorus-oxygen bond.

专利号:US-7429672-B2
优先权日:2006-06-09
标题 :Process for the direct synthesis of trialkoxysilane
发明人：LEWIS KENRICK M; CAMERON RUDOLPH A; RITSCHER LEGAL REPRESENTATIVE KAREN
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:This invention discloses a process to improve reaction stability in the Direct Synthesis of trialkoxysilanes. The process is particularly effective in the Direct Synthesis of triethoxysilane and its higher alkyl cognates providing improved triethoxysilane yields.

专利号:US-2003162992-A1
优先权日:2001-12-14
标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
发明人：WATANABE KYOICHI A; DU JINFA
摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

专利号:US-RE39650-E
优先权日:1996-10-10
标 题:Surface-active additives in the direct synthesis of trialkoxysilanes
发明人：MENDICINO FRANK D; LEWIS KENRICK M; MAGRI SEBASTIANO; YU HUA; CHILDRESS THOMAS E
权利人:GEN ELECTRIC
摘要:Disclosed is a process in which surface-active additives are used in the slurry phase Direct Synthesis of trialkoxysilanes to shorten the period between the start of the reaction and the attainment of steady-state rates and selectivities, to improve product yields and to control or prevent foam formation. Compositions comprising silicone antifoam compounds and fluorosilicone polymers are the preferred surface-active additives of the instant process.

专利号:US-7495120-B2
优先权日:2001-01-31
标题 :Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes
发明人：LEWIS KENRICK M; ENG REGINA NELSON; CROMER SABRINA R; MEREIGH ABELLARD T; O'YOUNG CHI-LIN
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:The present invention provides a process for using nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and mixtures thereof, as sources of catalytic copper in the Direct Synthesis of trialkoxysilanes of the formula HSi(OR) 3 wherein R is an alkyl group containing from 1 to 6 carbon atoms inclusive. The nanosized copper, nanosized copper oxides, nanosized copper chlorides, other nanosized copper salts, and their mixtures of this invention have average particle sizes that are in the range from about 0.1 to about 600 nanometers, preferably from about 0.1 to about 500 nanometers, and most preferably from about 0.1 to about 100 nanometers. Nanosized sources of catalytic copper afford high dispersion of catalytic sites on silicon and contribute to high reaction rates, high selectivity and high silicon conversion. The nanosized copper catalyst precursors of the invention permit the use of substantially reduced levels of copper compared to conventional practice.

专利号:US-5728858-A
优先权日:1996-10-10
标题:Activation of copper-silicon slurries for the direct synthesis of trialkoxysilanes
发明人：LEWIS KENRICK M; YU HUA
权利人:OSI SPECIALTIES INC
摘要:Disclosed is an improved process for the slurry phase Direct Synthesis of trialkoxysilanes which comprises the activation of copper catalyst and silicon with a reducing agent such as hydrogen gas, carbon monoxide or monosilane. Such activation affords high, stable reaction rates and selectivities and high silicon overall conversion especially in alkylated benzene solvents.