CAS: 931-57-7; 1-Methoxycyclohex-1-ene

该化合物是分子式C7H12O的循环酶,其特点是以环己环的1个位置替代一个甲氧基组,该化合物主要用作有机合成的中间体,特别是通过电益添加或循环添加等反应来制造更复杂的分子.其结构在双联体上具有回动性,而甲基环氧组则在随后的转化中提供稳定性和影响再选择性.该化合物通常是一种清晰,易挥发的液体,具有中度极度,适合用于各种溶剂.其合成效用和定义明确的再活性特征在制药和精细化学应用中具有价值.

结构式图片

相似化合物

16807-60-6 1122-84-5 61382-77-2

物理性质

MSDS等安全信息

欧盟法规

C&L通报

上下游产品

quinoline cycloxexanone dimethyl ketal benzoyl chloride 1-methoxy-1,3-cyclohexadiene 2-methoxycyclohexane N-(2-Methoxy-cyclohex-2-enylmethyl)-N,N'-dimethyl-ethane-1,2-diamine N,N'-Dibutyl-N-(2-methoxy-cyclohex-1-enylmethyl)-ethane-1,2-diamine N,N'-Dibutyl-N-(2-methoxy-cyclohex-2-enylmethyl)-ethane-1,2-diamine

合成工艺路线路线简述

  • 合成目标产物 1-Methoxycyclohexene 主要起始原料 Trimethoxymethane
  • 1728-18-3 = 931-57-7
    反应条件:1.1 Reagents: Pyridinium P-Toluenesulfonate; 18 H,150 °C; 150 °C -> 180 °C
    标题:High Resolution Positive Chemical Amplification Resist Materials
    参考文献:Japan]

    933-40-4 = 931-57-7 [标题:Reaction Conditions
    标题:Organic Transformations Via Metal Silane Reagents: Syntheses Of Vinyl Ethers From Dimethyl Ketals And Pentacarbonyl(Trimethylsilyl)Manganese
    作者:Marsi,Marianne; Gladysz,J. A.
    参考文献:Tetrahedron Letters 日期:1982 卷标:23(6) 页码:631-4]

    = 931-57-7
    反应条件:1.1 Reagents: P-Toluenesulfonic Acid
    标题:Determination Of Modulus And Phase Of The Complex Amplitude Transmission Of Arbitrary Electron Microscopic Objects Using Off-Axis Image Plane Holography
    作者:Wahl,H.
    参考文献:Optik (Jena 日期:1974 卷标:39(5) 页码:585-8]

    933-40-4 = 931-57-7 [标题:Reaction Conditions
    标题:Synthesis Of Vinyl And Dienyl Ethers
    作者:Nazarov,I. N.; Makin,S. M.; Kruptsov,B. K.; Mironov,V. A.
    参考文献:Zhurnal Obshchei Khimii 日期:1959 卷标:29 页码:111-17]

    = 931-57-7
    反应条件:1.1 Reagents: Sodium Tert-Butoxide Solvents: Dimethyl Sulfoxide
    标题:Formation Of Enol Ethers By Alkylation Of Ketones
    作者:Heiszwolf,G. J.; Kloosterziel,H.
    参考文献:Chemical Communications (London) 日期:1966 卷标:(2)]

    681-84-5 = 931-57-7
    反应条件:1.1 Reagents: Phosphoric Acid; 12 H,Reflux
    标题:Alkoxysilanes. Xvi. Reaction Of Tetraalkoxysilanes With Ketones
    作者:Voronkov,M. G.; Rabkina,S. M.
    参考文献:Zhurnal Obshchei Khimii 日期:1961 卷标:31 页码:1259-65]

    17497-53-9 = 931-57-7 [标题:Reaction Conditions
    标题:Photochemistry Of Alkyl Halides. 10. Vinyl Halides And Vinylidene Dihalides
    作者:Kropp,Paul J.; Mcneely,Steven A.; Davis,Robert Drummond
    参考文献:Journal Of The American Chemical Society 日期:1983 卷标:105(23) 页码:6907-15]

    933-40-4 = 931-57-7
    反应条件:1.1 Reagents: Magnesium Pyrophosphate
    标题:Reaction Of Organic Azides With Unsaturated Compounds. X. Esters Of N-(Arylsulfonyl) Carboximidic Acids
    作者:Semenov,V. P.; Ogloblin,K. A.
    参考文献:Zhurnal Organicheskoi Khimii 日期:1988 卷标:24(11) 页码:2389-97]

    = 931-57-7 [标题:Reaction Conditions
    标题:C-O Coupling Of Malonyl Peroxides With Enol Ethers Via [5+2] Cycloaddition: Non-Rubottom Oxidation
    作者:Vil',Vera A.; Gorlov,Evgenii S.; Bityukov,Oleg V.; Barsegyan,Yana A.; Romanova,Yulia E.; Et Al
    参考文献:Advanced Synthesis & Catalysis 日期:2019 卷标:361(13) 页码:3173-3181]

    61580-73-2 = 931-57-7
    反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethylformamide
    标题:The Peterson Olefination Reaction
    作者:Ager,David J.
    参考文献:Organic Reactions (Hoboken 日期:1990 卷标:38]

    933-40-4 = 931-57-7
    反应条件:1.1 Reagents: Diisopropylethylamine,Trimethylsilyl Triflate Solvents: Dichloromethane1.2 Reagents: Sodium Hydroxide Solvents: Water
    标题:General Method For The Synthesis Of Enol Ethers (Vinyl Ethers) From Acetals
    作者:Gassman,Paul G.; Burns,Stephen J.
    参考文献:Journal Of Organic Chemistry 日期:1988 卷标:53(23) 页码:5574-6]

    = 931-57-7 [标题:Reaction Conditions
    标题:Radical Reactions Of N-Haloamides With Olefins. Part Xi. The Photochemical Addition Of N-Haloamides To Olefins: The Influence Of Various Factors On The Competition Between 1,2-Addition And Hydrogen Abstraction
    作者:Lessard,Jean; Mondon,Martine; Touchard,Daniel
    参考文献:Canadian Journal Of Chemistry 日期:1981 卷标:59(2) 页码:431-50]

    = 931-57-7
    反应条件:1.1 Catalysts: P-Toluenesulfonic Acid Solvents: Trimethyl Orthoformate
    标题:An Efficient Synthesis Of Functionalized Tricyclo[6.3.1.01.6]Dodec-4-Enes By A Stereoselective Intramolecular Diels-Alder Reaction
    作者:Shishido,Kozo; Hiroya,Kou; Ueno,Yutaka; Fukumoto,Keiichiro; Kametani,Tetsuji; Et Al
    参考文献:Journal Of The Chemical Society 日期:1986 卷标:(5) 页码:829-36]

    = 931-57-7
    反应条件:1.1 Catalysts: P-Toluenesulfonic Acid; Rt; 1 H,Rt
    标题:Polyacetal Or Polyketal And Ether Polymers,Their Conjugates,And Therapeutic Use
    参考文献:World Intellectual Property Organization]

    933-40-4 = 931-57-7
    反应条件:1.1 13.3 Kpa,240 °C
    标题:Synthesis Of 1-Methoxycyclohexene
    作者:Zhang,Shijie; Dai,Liyan; Wang,Xiaozhong; Chen,Yingqi
    参考文献:Zhongguo Yiyao Gongye Zazhi 日期:2006 卷标:37(6) 页码:379-380]

    5927-93-5 = 931-57-7
    反应条件:1.1 Reagents: 2-Propanamine,N-(1-Methylethyl)-,Sodium Salt (1:1) Solvents: Tetrahydrofuran; -78 °C
    标题:Sodium Diisopropylamide-Mediated Dehydrohalogenations: Influence Of Primary- And Secondary-Shell Solvation
    作者:Ma,Yun; Algera,Russell F.; Woltornist,Ryan A.; Collum,David B.
    参考文献:Journal Of Organic Chemistry 日期:2019 卷标:84(17) 页码:10860-10869]

    = 931-57-7 [标题:Reaction Conditions
    标题:Mechanism Of Hydrogenolysis. Part 1. Catalytic Hydrogenation Of Vinyl And Aryl Trifluoromethanesulfonates
    作者:Garcia Martinez,Antonio; Martinez Alvarez,Roberto; Arranz Aguirre,Juan; Subramanian,Lakshminarayanapuram R.
    参考文献:Journal Of The Chemical Society 日期:1986 卷标:(9) 页码:1595-8]

    = 931-57-7
    反应条件:1.1 Reagents: Iodine Catalysts: Dibromobis(Triphenylphosphine)Palladium Solvents: Methanol1.2 Reagents: Oxygen
    标题:Mild Alkane Functionalization Leading To Ethers: Oxidative Alkoxylation Of Cyclohexane With The Dibromobis(Phosphine)Palladium(Ii)-Sodium Alkoxide System
    作者:Vedernikov,Andrei N.; Sayakhov,Marat D.; Solomonov,Boris N.
    参考文献:Mendeleev Communications 日期:1997 卷标:(5) 页码:205-206]

    = 931-57-7
    反应条件:1.1 Reagents: P-Toluenesulfonic Acid Solvents: Methanol
    标题:Asymmetric Synthesis Of Cyclic Hydroxy Ketones Derived From Enol Ethers Via Sharpless Asymmetric Dihydroxylation. A Study In The Correlation Of The Enol Ether Chain Length And Enantioselectivity
    作者:Marcune,Benjamin F.; Karady,Sandor; Reider,Paul J.; Miller,Ross A.; Biba,Mirlinda; Et Al
    参考文献:Journal Of Organic Chemistry 日期:2003 卷标:68(21) 页码:8088-8091]

    = 931-57-7
    反应条件:1.1 Reagents: P-Toluenesulfonic Acid; 2 H,Rt
    标题:Acid-Sensitive Amphiphilic Block Copolymer And Its Self-Organization Micelle And Application
    参考文献:China
1-环己烯-1-基(三甲基)硅烷置于过氧乙酸,硫酸,Sodium Acetate,Sodium Hydride体系中,用 二氯甲烷,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 0.83H,反应生成 1-甲氧基环己烯
参考文献:αβ-环氧硅烷的一些环氧化物开环反应
标题:αβ-环氧硅烷的一些环氧化物开环反应
摘要:1,2-环氧-1-三甲基甲硅烷基环己烷(3)的环氧开环给出了一系列2-取代的2-三甲基甲硅烷基环己醇(4; X = H,Oh,Ome,och 2 Ch Ch 2,Br,I,Scn),其中亲核试剂的攻击发生在碳原子对硅的α处.产物(4)已被转化为许多官能化的硅烷,包括甲硅烷基-环二硫化物(9).尚未进行广泛研究的其他环氧化物是结构偏倚的环氧硅烷(10)和(11),八元环环氧硅烷(17)和(21)以及两种立体异构体2,3-环氧-3-三甲基甲硅烷基戊烷(26)和(29).用h +处理后获得环氧开环加合物除化合物(17)以外,所有情况下均为-Meoh,其中双环醇(18)通过环过环反应形成.
DOI:10.1039/p19810001934

海关参考信息

专利信息


专利号:US-4045422-A
优先权日:1974-04-15
标题 :Synthesis of α-nitrosoketal dimers
发明人：ROGIC MILORAD M; SWERDLOFF MICHAEL D; DEMMIN TIMOTHY R
权利人:ALLIED CHEM
摘要:Ketals of α-oximinoketones and methods for the preparation of these compounds including intermediates are described. The compounds disclosed include both α-oximinoketals and cyclic ketals of α-oximinoketones. Also disclosed is a class of α-nitrosoketal dimers produced during the synthesis of the corresponding α-oximinoketals and the method for their preparation.

专利号:US-4033949-A
优先权日:1976-04-14
标 题:Analogs of thromboxane B2 and processes for their synthesis
发明人：KELLY ROBERT C; NELSON NORMAN A
权利人:UPJOHN CO
摘要:The present specification provides novel intermediates and novel processes for the synthesis of various side chain and skeletal analogs of Thromboxane B 2 (11β-homo-11a-oxa-PGF 2 .sub.α). These analogs are particularly and especially useful as reproductive cycle control agents.

专利号:US-4792637-A
优先权日:1986-07-30
标题:Process for the preparation of vinyl ethers
发明人：MESSINA GIUSEPPE; MORETTI MARIO D; SANNA SALVATORE R; SOMA GIOVANNI; CABRAS PIER G
权利人:ENICHEM ANIC SPA
摘要:A process for the synthesis of vinyl ethers of formula ##STR1## wherein R 1 and R 2 , each independently, represent hydrogen or a primary, secondary or tertiary alkyl group, n R 3 is a hydrogen, a primary alkyl, phenyl, or substituted phenyl group, or n R 2 and R 3 , taken together, represent a polymethylene chain containing from 3 to 10 carbon atoms wherein one or more hydrogens can be replaced by methyl or ethyl groups, and n R is a primary, secondary or tertiary alkyl group, which comprises reacting a suitably selected dioxolane derivative of formula II ##STR2## wherein R 1 , R 2 , and R 3 are as defined above, and n R 4 , R 5 , R 6 , and R 7 , each independently, represent hydrogen or an alkyl group, with a boric acid ester of formula III n n B(OR).sub.3 III n n wherein n R is as defined above, in the vapor phase, at a temperature comprised between 100° and 400° C., and in the presence of an acidic heterogeneous catalyst.

专利号:US-4847429-A
优先权日:1987-08-03
标 题:Synthesis of phenylhydroquinones
发明人：LENTZ CARL M; GUSTAFSON BRUCE L; VAN SICKLE DALE E; BOWERS JR JOSEPH S
权利人:EASTMAN KODAK CO
摘要:Process is disclosed for the preparation of phenylhydroquinones by the alkylation of hydroquinone (or derivatives thereof) with the cyclohexyl moieties, cyclohexanol or cyclohexene (or derivatives thereof), followed by dehydrogenation of the intermediate cyclohexylhydroquinone.

专利号:US-4206112-A
优先权日:1974-04-15
标题:α-Nitrosoketal dimers and production of α-oximinoketals therefrom
发明人：DEMMIN TIMOTHY R; ROGIC MILORAD M; SWERDLOFF MICHAEL D
权利人:ALLIED CHEM
摘要:This invention describes novel ketals of α-oximinoketones, methods for the preparation of these compounds and includes novel intermediates formed during the production thereof. The novel class of compounds disclosed herein includes both α-oximinoketals, as well as the cyclic ketals of α-oximinoketones. This invention also discloses a novel class of α-nitrosoketal dimers produced during the synthesis of the corresponding α-oximinoketals, and it also discloses novel methods in the production thereof.

专利号:US-4594432-A
优先权日:1983-01-28
标题 :Process for the synthesis of 1α,23(S),25-trihydroxycholecalciferol and 1α,23(R),25-trihydroxycholecalciferol
发明人：BAGGIOLINI ENRICO G; USKOKOVIC MILAN R; WOVKULICH PETER M
权利人:HOFFMANN LA ROCHE
摘要:The invention is directed to a process and intermediates for the preparation of 1α,23(S),25-trihydroxycholecalciferol and 1α,23(R),25-trihydroxycholecalciferol. The end-products, 1α,23(S),25-trihydroxycholecalciferol and 1α,23(R),25-trihydroxycholecalciferol, are useful for the treatment of disease states which are characterized by insufficient amounts of 1,25 dihydroxycholecalciferol.

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合成参考文献


摘要:Beier, P., Science of Synthesis Knowledge Updates, (2014) 2, 339.
摘要:Bartels, F.; Zimmer, R.; Christmann, M., Science of Synthesis Knowledge Updates, (2017) 3, 260.
摘要:Vil’, V. A.; Bityukov, O. V.; Terent’ev, A. O., Science of Synthesis Knowledge Updates, (2019) 3, 420.
摘要:Vil’, V. A.; Bityukov, O. V.; Terent’ev, A. O., Science of Synthesis Knowledge Updates, (2019) 3, 389.
摘要:Barsegyan, Y. A.; Vil’, V. A.; Tomkinson, N. C. O.; Terent’ev, A. O., Science of Synthesis Knowledge Updates, (2022) 1, 251.
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