CAS: 634-47-9; 2-Chloro-4-Methylquinoline

相似化合物

23952-31-0 88499-92-7 59666-16-9

上下游产品

CAS号607-66-9 4-甲基喹诺酮 | CAS号676-58-4 甲基氯化镁 | CAS号703-61-7 2,4-二氯喹啉 | CAS号98-88-4 苯甲酰氯 | CAS号114058-74-1 2-氯-4-甲基喹啉-7-胺 | CAS号10026-13-8 五氯化磷 | CAS号50693-78-2 4-甲基-2-(1-哌嗪基)喹啉 | CAS号607-66-9 4-甲基喹诺酮 | CAS号4437-65-4 4-甲基喹啉-2-硫醇 | CAS号491-35-0 4-甲基喹啉 | CAS号2584-47-6 1,4-二甲基喹啉酮 | CAS号7654-51-5 2,2'-联-4-勒皮啶 | CAS号62748-01-0 4-甲基-8-氨基喹啉 | CAS号100949-89-1 4-甲基-2-(4-甲基哌嗪-... | CAS号35213-85-5 5-甲基四唑并[1,5-A]喹啉

2-羟基-4-甲基喹啉置于三氯氧磷体系中,化学反应生成 4-甲基-2-氯-喹啉
参考文献:杂原子定向的光环化:吲哚喹啉生物碱的合成:隐地平,隐花果碱,隐血人扁豆碱及其甲基衍生物
标题:杂原子定向的光环化:吲哚喹啉生物碱的合成:隐地平,隐花果碱,隐血人扁豆碱及其甲基衍生物
摘要:描述了吲哚喹啉生物碱的三步合成.2,3和4-取代的卤代喹啉与苯胺的反应得到各自的苯胺喹啉,其在光环化后得到吲哚喹啉.通过在喹啉氮上的区域选择性甲基化,提供了生物碱隐tackieine,隐sanguinolentine,隐lepinepine和合成异构体isooneocryptolepine.还合成了它们的甲基衍生物,以寻找新的抗疟原虫药物和dna嵌入剂.
DOI:10.1016/j.Tet.2006.04.050

专利信息

专利号:US-9126995-B2
优先权日:2011-11-08
标题:Method for catalytic asymmetric synthesis of optically active isoxazoline compound and optically active isoxazoline compound
发明人：TOYAMA KEN-ICHI; MORIYAMA YUJI; MATOBA KAZUTAKA; YAOSAKA MANABU; IKEDA EITATSU
权利人:NISSAN CHEMICAL IND LTD
摘要:There is provided a method for catalytic asymmetric synthesis of optically active isoxazoline compound and an optically active isoxazoline compound. A method for catalytic asymmetric synthesis of optically active isoxazoline compound of a formula (6) including reacting an α,β-unsaturated carbonyl compound of a formula (1) and a hydroxylamine in a solvent in the presence of a base by adding a chiral phase transfer catalyst. An optically active isoxazoline compound of a formula (13) that can be synthesized by the method.

专利号:US-7960553-B1
优先权日:2006-10-02
标 题 :Reagent for synthesis of para-methoxbenzyl (PMB) ethers and associated methods
发明人：DUDLEY GREGORY B
权利人:UNIV FLORIDA STATE RES FOUND
摘要:A newly synthesized compound designated lepidine ether 2-(4-Methoxybenzyloxy)-4-methylquinoline reacts with methyl triflate in the presence of alcohols to generate a neutral organic salt that transfers the para-methoxybenzyl (PMB) protecting group onto alcohols in high yield and under mild conditions.

专利号:US-2014350261-A1
优先权日:2011-11-08
标 题 :Method for catalytic asymmetric synthesis of optically active isoxazoline compound, and optically active isoxazoline compound

专利号:HU-P0401607-A2
优先权日:2004-08-10
标题 :Synthesis of aminoquinoline derivatives and of their starting materials

专利号:WO-2013069731-A1
优先权日:2011-11-08
标题 :Method for catalytic asymmetric synthesis of optically active isoxazoline compound, and optically active isoxazoline compound

专利号:UA-122918-C2
优先权日:2018-07-26
标题 :ASYMMETRIC 2-AMINO-SUBSTITUTED MONOMETINCYANINE DYES AND THE METHOD OF THEIR SYNTHESIS (ACB)