CAS: 624-73-7; 1,2-Diiodoethane

上下游产品

CAS号54509-73-8 ethene | CAS号936-51-6 2-苯基-1,3-二四氢呋喃 | CAS号107-21-1 乙二醇 | CAS号7381-30-8 1,2-双(三甲基硅氧基)乙烷 | CAS号110-71-4 乙二醇二甲醚 | CAS号64-19-7 冰醋酸 | CAS号3970-21-6 2-甲氧基乙氧基甲基氯 | CAS号123-91-1 1,4-二氧六环 | CAS号107-06-2 1,2-二氯乙烷 | CAS号333-20-0 硫氰酸钾 | CAS号100-71-0 2-乙基吡啶 | CAS号536-75-4 4-乙基吡啶 | CAS号593-66-8 碘乙烯 | CAS号107-01-7 2-丁烯 | CAS号590-19-2 1,2-丁二烯 | CAS号624-72-6 1,2-二氟乙烷 | CAS号2366-52-1 氟化丁基 | CAS号624-70-4 1-氯-2-碘乙烷 | CAS号107-06-2 1,2-二氯乙烷 | CAS号7790-87-6 三碘化铈

1,2-二氯乙烷置于calcium Iodide体系中,化学反应生成 1,2-二碘乙烷
参考文献:Spindler,Justus Liebigs Annalen Der Chemie,1885,Vol. 231,P. 272
标题:Spindler,Justus Liebigs Annalen Der Chemie,1885,Vol. 231,P. 272

专利信息

专利号:US-10011580-B2
优先权日:2016-04-21
标题:Diastereoselective synthesis of (±)-epianastrephin, (±)-anastrephin and analogs thereof
发明人：WALSE SPENCER S; KUZMICH DANIEL
权利人:US AGRICULTURE
摘要:A process for the synthesis of trans-fused γ-lactones having Formula (IV) from substituted cyclic ketones having Formula (I). A diastereoselective synthesis of (±)-epianastrephin (1) (wherein: R 1 is ethenyl, R 2 and R 3 is methyl, and n is 1), (±)-anastrephin (2) (wherein: R 2 is ethenyl, R 1 and R 3 is methyl and n is 1), and analogs thereof (wherein: R 1 is H, C 1-5 alkyl, C 2-6 alkenyl or C 2-6 alkynyl, R 2 is H, C 1-5 alkyl, C 2-6 alkenyl or C 2-6 alkynyl, R 1 and R 2 together with the carbon atom they are attached form a C 3-6 cycloalkyl ring, R 3 is C 1-5 alkyl and n is 0-2):

专利号:WO-2012003598-A1
优先权日:2010-07-06
标 题 :Intermediates for the synthesis of 1,2-bis(4,7-dimethyl-1,4,7-triazacyclonon-1-yl)-ethane and preparation method thereof
发明人：HAGE RONALD; KOEK JEAN HYPOLITES; RUSSELL STEPHEN WILLIAM; WANG XIAOHONG; WOLF LODEWIJK VAN DER; ZHANG JIANRONG; ZHAO WEI
权利人:UNILEVER PLC; UNILEVER NV; UNILEVER HINDUSTAN; HAGE RONALD; KOEK JEAN HYPOLITES; RUSSELL STEPHEN WILLIAM; WANG XIAOHONG; WOLF LODEWIJK VAN DER; ZHANG JIANRONG; ZHAO WEI
摘要:The present invention provides intermediates for the synthesis of 1,2-bis(4,7-dimethyl-1,4,7-triazacyclonon-1-yl)-ethane and preparation method thereof. The intermediates are protonated salts of 1,4-ditosylate-1,4,7-triazacyclononane or 1,4-dibenzenesulphonate-1,4,7-triazacyclononane. The preparation method of 1,4-diarylsulfonate-1,4,7-triazacyclononane (compound A) comprises reacting 1,4,7-triarylsulfonate-1,4,7-triazacyclononane (compound B) in an acidic medium comprising sulphuric acid, wherein the molar ratio of B to sulphuric acid is in the range from 1 : 0.5 to 1 : 10, or reacting 1,4,7-triarylsulfonate-1,4,7-triazacyclononane (compound B) in an acidic medium and working up the acidic medium when the conversion of B to A is at least 50 mol % yielding compound A.

专利号:US-8907082-B2
优先权日:2010-07-06
标 题 :1,2-bis-(4,7-dimethyl-1,4,7-triazacyclonon-1-yl)-ethane and intermediate for the synthesis of same
发明人：HAGE RONALD; KOEK JEAN HYPOLITES; RUSSELL STEPHEN WILLIAM; VAN DER WOLF LODEWIJK; ZHANG JIANRONG; ZHAO WEI; WANG XIAOHONG
权利人:HAGE RONALD; KOEK JEAN HYPOLITES; RUSSELL STEPHEN WILLIAM; VAN DER WOLF LODEWIJK; ZHANG JIANRONG; ZHAO WEI; WANG XIAOHONG; CATEXEL LTD
摘要:The present invention provides improved processes for the synthesis of 1,4-ditosyl-1,4,7-triazacyclonone, comprising deprotecting a compound of formula (C): n nwherein P is tosylate or arylsulfonate, with an acidic medium to form 1,2-bis(1,4,7-triazacyclonon-1-yl)-ethane; and subsequently adding formaldehyde and formic acid to the acidic medium to form 1,2-bis-(4,7-dimethyl-1,4,7-triazacyclonon-1-yl)-ethane (Me 4 -DTNE). The syntheses of intermediates are also disclosed.

专利号:US-7078572-B2
优先权日:2002-09-20
标题:Process for the synthesis of intermediates useful for the synthesis of tubulin inhibitors
发明人：KENDALL JOHN THOMAS
权利人:WYETH CORP
摘要:The invention is a process for the preparation of compounds of the Formula I: n nwhere R 1 , R 2 , R 3 , R 4 and R 5 are defined in the specification, which are intermediates useful for the preparation of tubulin inhibitors which are useful in the treatment of cancer.

专利号:US-2007042987-A1
优先权日:2004-07-30
标题:Stereoselective synthesis of beta-nucleosides
发明人：LIN KO-CHUNG; LI WENSEN; LIN CHUNHUI; YUNGSHUN WEIN; KUO-HIS KAO
权利人:LIN KO-CHUNG; LI WENSEN; LIN CHUNHUI; YUNGSHUN WEIN; KUO-HIS KAO
摘要:This invention relates to a process of stereoselectively synthesizing an alcohol of the following formula: n n nwherein R 1 , R 2 , R 3 , R 4 , and R 5 are defined in the specification. The process includes reacting (R) 4-formyl-2,2-dimethyldioxolane with α-bromoacetate in the presence of Zn and a Zn activating agent.

专利号:US-7485716-B2
优先权日:2005-05-02
标题:Stereoselective synthesis of β-nucleosides
发明人：LIN KO-CHUNG; LI WENSEN
权利人:PHARMAESSENTIA CORP
摘要:This invention relates to a process for stereoselectively preparing a nucleoside of the following formula: n nwherein R 3 , R 4 , and B are defined herein. The process includes reacting a furanose compound with a nucleobase in the presence of a halide salt. Also disclosed is another process for stereoselectively synthesizing an intermediate that can be used to make the starting compound in the first-mentioned process.