CAS: 591-93-5; 1,4-Pentadiene

该化合物是一种与分子式C5H6相交的共聚的二极联苯,其特征是线性链中第一和第二个碳原子存在两个双环,这种化合物在室温下是一种无色液体,具有独特的气味,以其反应作用而著称,特别是在聚合反应中,使其成为有机合成和生产各种聚合物的宝贵中间体. 1,4-五氯苯在诸如乙醚和酒精等有机溶剂中具有溶解性,但水溶解性有限.其结构允许几何异异构体,尽管最常见的形态是变形.该化合物易燃,应谨慎处理,因为它在吸入或皮肤接触时会构成健康风险.此外,它还可以发生各种化学反应,包括增加电药和聚合作用,这对合成材料的开发非常重要.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

1 ,5-pentanediol N,N-dimethylpent-4-enylamine 1,5-diiodopentane 1,2,4,5-tetrabromo-pentane 1,4-pentadiene diepoxide penta-1,3-diene trans-2-pentenal hexa-3,5-dienoic acid

合成工艺路线路线简述

    📜1-戊烯-4-炔置于氢气体系中,用 甲苯 作为反应溶剂,139.84 °C,9.0 Mpa 条件下,反应生成 1,4-戊二烯
    参考文献:负载型ceo2催化剂连续流三相炔烃加氢的立体和化学选择性
    标题:负载型ceo2催化剂连续流三相炔烃加氢的立体和化学选择性
    摘要:Tio 2,Al 2 O 3和zro 2负载的ceo 2通过用硝酸铈铵酸化溶液湿法浸渍载体来制备具有不同ce负载量的催化剂.煅烧后的催化剂通过本体和表面敏感技术进行了表征,其中包括微量热法,并在连续流动条件下,在可变温度(293-413 K)和压力(1-90 Bar)下,对炔烃进行了三相氢化.系统地评估了许多炔化合物,这些化合物含有末端或内部的三键,共轭的不饱和键和其他功能.结果表明,二氧化铈催化剂具有完全的立体选择性和化学选择性,胜过了著名的lindlar催化剂,
    DOI:10.1002/cctc.201402124

    海关参考信息

    专利信息


    专利号:US-7973171-B2
    优先权日:2005-06-13
    标题:Process for synthesis of dialkoxyorganoboranes
    发明人:BURKHARDT ELIZABETH; ATKINS WILLIAM
    权利人:BURKHARDT ELIZABETH; ATKINS WILLIAM
    摘要:The invention relates to a process for the synthesis of dialkoxyorganoboranes, in particular to a process for the synthesis of dialkoxyorganoboranes by an ester exchange reaction. Moreover, the invention relates to a process for the synthesis of organo-oxazaborolidine catalysts (organo-CBS) and of trialkylboroxins. Furthermore, the invention relates to methods of using dialkoxyorganoboranes for the preparation of organo-CBS catalysts and in Suzuki-type coupling reactions.

    专利号:US-2008086013-A1
    优先权日:2006-06-15
    标 题:Carbometallation of alkynes and improved synthesis of uniquinones
    发明人:LIPSHUTZ BRUCE H
    权利人:UNIV CALIFORNIA
    摘要:Methods for the carbometallation of alkynes are presented. Those are useful for the synthesis of CoQ 10 and other ubiquinones as well as for the synthesis of ubiquinol analogs.

    专利号:WO-2023102600-A1
    优先权日:2021-12-06
    标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
    发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
    权利人:NEWSOUTH INNOVATIONS PTY LTD
    摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.

    专利号:US-5087703-A
    优先权日:1988-01-28
    标题 :Process for synthesis of FK-506 intermediates
    发明人:VOLANTE RALPH P; ASKIN DAVID; SHINKAI ICHIRO; RYAN KENNETH M
    权利人:MERCK & CO INC
    摘要:A process is described for the synthesis of diastereomeric 2-methyl-4-hydroxy-5-protected-hydroxy-hept-6-en-prolinolamides, which are useful as intermediates in the synthesis of the C10-C18 chain of the macrolide structure for the immunosuppressant FK-506. These compounds are also useful as intermediates for preparing lactone ultraviolet radiation absorbers.

    专利号:US-6512081-B1
    优先权日:1997-07-21
    标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
    发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME
    权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG
    摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

    专利号:US-2007260076-A1
    优先权日:2003-12-05
    标 题:Practical, Cost-Effective Synthesis of Ubiquinones
    发明人:LIPSHUTZ BRUCE H; BERL VOLKER; SHEIN KARIN; WETTERICH FRANK
    权利人:LIPSHUTZ BRUCE H; BERL VOLKER; SHEIN KARIN; WETTERICH FRANK
    摘要:The present invention provides a convergent method for the synthesis of ubiquinones and ubiquinone analogues. Also provided are precursors of ubiquinones and their analogues that are useful in the methods of the invention. The invention further provides an improved method for the carboalumination of alkyne substrates.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.6026/97320630006315
    摘要:Roy S, Maheshwari N, Chauhan R, Sen NK, Sharma A. Structure prediction and functional characterization of secondary metabolite proteins of Ocimum. Bioinformation. 2011 Jul 06;6(8):315–9. doi: 10.6026/97320630006315.
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