CAS: 542-50-7; Heptacosan-14-One

该化合物是一个长链脂质开关,其特点是27-碳脊柱和碳基组,位于14碳位置;该化合物是脂肪氯酮家族的一部分,通常存在于各种自然来源,包括某些植物蜡和动物脂肪;在室内温度下,它没有色素可粉色黄色固体,表现出蜡状质;该物质由于水分缺乏性,在水中基本溶解,但在乙醇和乙醇等有机溶剂中溶解. 14-七氯丙酮的熔点和沸点相对较高,这是长链脂肪化合物的典型特征,其应用可能包括在香味,调味剂和作为可能的丙酮在昆虫交流中使用.此外,它可以作为研究各种化学和生物环境中长链质的特性的示范化合物.

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45206-91-5 540-08-9 462-18-0

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CAS号544-63-8 肉豆蔻酸 | CAS号124-10-7 肉豆蔻酸甲酯 | CAS号112-53-8 月桂醇 | CAS号112-72-1 十四醇 | CAS号1308885-39-3 benzyl 2-myrist... | CAS号31161-71-4 肉豆蔻酸苄酯 | CAS号945764-60-3 2-myristoylmyri... | CAS号4086-70-8 豆蔻酸镁 | CAS号60-29-7 乙醚 | CAS号677-22-5 叔丁基氯化镁 | CAS号593-49-7 二十七烷 | CAS号32116-10-2 heptacosan-14-ol

合成工艺路线路线简述

    📜五甲基呋喃溴酸酯置于乙醚,叔丁基氯化镁体系中,化学反应生成 14-二十七酮
    参考文献:Claisen Condensation By T-Butylmagnesium Chloride
    标题:Claisen Condensation By T-Butylmagnesium Chloride
    摘要:
    DOI:10.1021/ja01215A510

    海关参考信息

    专利信息


    专利号:US-9200299-B2
    优先权日:2007-05-22
    标 题:Genetically engineered cell encoding ole amino acid motifs in a carbon source producing aliphatic ketones or olefins
    发明人：FRIEDMAN LISA; DA COSTA BERNARDO
    权利人:FRIEDMAN LISA; DA COSTA BERNARDO; REG LIFE SCIENCES LLC
    摘要:The invention provides isolated nucleic acids and isolated polypeptides involved in the synthesis of hydrocarbons and hydrocarbon intermediates. Homologs of, conservative variants of, and sequences having at least about 35% sequence identity with nucleic acids involved in the synthesis of hydrocarbons and hydrocarbon intermediates are also provided. The invention further provides methods for producing an aliphatic ketone or a hydrocarbon, as well as a method for identifying an enzyme useful for the production of hydrocarbons.

    专利号:CN-110484539-B
    优先权日:2019-08-27
    标题:Gene and gene fragment for regulating and controlling synthesis of sex pheromone of Blattella germanica, corresponding dsRNA (double-stranded ribonucleic acid) and preparation method and application thereof

    专利号:US-2015240295-A1
    优先权日:2012-09-28
    标题 :Reactive, lipophilic nucleoside building blocks for the synthesis of hydrophobic nucleic acids

    专利号:US-2019175633-A1
    优先权日:2017-12-12
    标题:Reactive, lipophilic nucleoside building blocks for the synthesis of hydrophobic nucleic acids
    发明人：ROSEMEYER HELMUT; MALECKI EDITH; KORNEEV SERGEI; WERZ EMMA; GALL KARSTEN
    权利人:IONOVATION GMBH
    摘要:wherein Q represents a group having a substituted tetrahydrofuran ring and Bas represents a group having one or more heterocyclic rings having one or more heterocyclic nitrogen atoms.

    专利号:EP-2900681-A1
    优先权日:2012-09-28
    标题:Reactive, lipophilic nucleoside building blocks for the synthesis of hydrophobic nucleic acids

    专利号:US-3336391-A
    优先权日:1965-03-30
    标 题 :Synthesis of ketones and sulfones
    发明人：LYNESS WARREN I; O'CONNOR DAVID E
    权利人:PROCTER & GAMBLE

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    主要参考文献

    参考标题:Reactive, Lipophilic Nucleoside Building Blocks For The Synthesis Of Hydrophobic Nucleic Acids
    摘要:The Present Invention Relates To A Method For The Isolation And/or Identification Of Known Or Unknown Sequences Of Nucleic Acids (Target Sequences) Optionally Marked With Reporter Groups By Base Specific Hybridation With Complementary Sequences Using Nucleolipids. The Nucleolipids Are Prepared By Lipophilizing Nucleosides Of Formula (Ia) Wherein Q Represents A Group Having A Substituted Tetrahydrofuran Ring And Bas Represents A Group Having One Or More Heterocyclic Rings Having One Or More Heterocyclic Nitrogen Atoms.

    合成参考文献


    参考文献:10.1007/bf02531463
    摘要:Albro PW, Dittmer JC. Bacterial hydrocarbons: occurrence, structure and metabolism. Lipids. 1970 Mar;5(3):320–5. doi: 10.1007/bf02531463.
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