CAS: 5172-02-1; 1-Chloro-4-(Phenylethynyl)Benzene
该化合物是具有芳香结构特征的有机化合物,其特征是用苯乙烯基组(由与一个苯乙烯组(碳碳-碳三联)相连的苯环组成)替换在准位置的氯苯基,该组通常没有色素,可以用于黄色的黄色固体,并因其在有机合成和材料科学中的潜在应用而闻名,特别是在液体晶体和其他电子材料的开发中,其化学特性包括有机溶剂中的中等溶性,以及在标准条件下的稳定性.氯原子的存在增强了其再活性,使其在各种化学反应中成为有用的中间体,包括核分裂替代物.此外,苯乙烯组有助于其独特的电子特性,可在功能材料的设计中加以利用.在处理该化合物时应采取安全防范措施,因为如果吸入或浸入,可能会对健康造成危害.
- 英文名称1-Chloro-4-(Phenylethynyl)Benzene
- 中文名称1-氯-4-(苯乙炔基)苯
- IUPAC名称1-chloro-4-(phenylethynyl)benzene
- 其它别名Acetylene,(p-chlorophenyl)phenyl- (6CI,7CI,8CI); Benzene, 1-chloro-4-(phenylethynyl)-(9CI); (4-Chlorophenyl)phenylacetylene; (4-Chlorophenylethynyl)benzene; (p-Chlorophenyl)phenylacetylene; 1-(4-Chlorophenyl)-2-phenylacetylene; 1-Chloro-4-(phenylethynyl)benzene; 4-(Phenylethynyl)chlorobenzene; p-Chlorodiphenylacetylene
- CAS编号5172-02-1
- MFCD编号:MFCD00957930
- EINECS号:624-096-4
- 分子式:C14H9Cl分子量:212.68
- 产品CID: 2293806
- 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物
相似化合物
1820-42-4 51624-34-1 5216-31-9物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
CAS号637-87-6 对氯碘苯 | CAS号2170-06-1 1-苯基-2-(三甲基硅)乙炔 | CAS号637-44-5 苯丙炔酸 | CAS号536-74-3 苯乙炔 | CAS号873-73-4 1-氯-4-乙炔基苯 | CAS号591-50-4 碘苯 | CAS号1679-18-1 4-氯苯硼酸 | CAS号932-87-6 (溴炔)苯 | CAS号77295-59-1 1-chloro-4-(2,2... | CAS号98-80-6 苯硼酸 | CAS号1657-50-7 (E)-1-(4-Chloro... | CAS号14310-22-6 1-chloro-4-(2-p... | CAS号22711-23-5 对氯联苯酰 | CAS号134-85-0 4-氯二苯甲酮合成工艺路线路线简述
📜P-Chlorobenzenediazonium Tetrafluoroborate置于碘代三甲硅烷,C11H20N3(1+)*c2F6No4S2(1-),Palladium Diacetate体系中,化学反应 5.0H,反应生成 1-氯-4-(苯基乙炔基)苯
参考文献:在没有配体或添加剂的咪唑类ils中,通过顺序的碘脱氮/脱羧sonogashira反应,可轻松访问内部炔烃的不同文库
标题:在没有配体或添加剂的咪唑类ils中,通过顺序的碘脱氮/脱羧sonogashira反应,可轻松访问内部炔烃的不同文库
摘要:一种简便的一锅法,包括顺序的碘脱氮/ Sonogashira反应,用于制备各种内部炔烃库.该方法使用咪唑鎓ils作为碱和溶剂,不需要配体或添加剂.
DOI:10.1002/ejoc.201900093
海关参考信息
- 2901292000-乙炔
2902300000-甲苯
2903919090-氯苯
2903991000-对氯甲苯 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-11033889-B2
优先权日:2018-10-23
标 题:Palladium acyclic diaminocarbene complexes as precatalysts for Hiyama coupling and the tandem one-pot fluoride free Hiyama coupling/cyclization for the synthesis of biologically relevant
发明人：SINGH CHANDAN; GHOSH PRASENJIT
权利人:INDIAN INST TECHNOLOGY BOMBAY
摘要:The present invention provides Acyclic diaminocarbene complex of formula (I):Wherein,M is palladium;X is monoanionic ligand selected from Cl, Br or I;Where R1 is different from R2;R1 is selected from the group consisting of alkyl or aryl, each of which have 4 to 20 carbon atoms, and may optionally contain one or more heteroatoms;R2 is selected from the group consisting of alkyl, or aryl each of which have 4 to 20 carbon atoms, and may optionally contain one or more heteroatoms. The said palladium diamino carbine complex of the present invention are particularly useful as catalyst from Hiyama cross-coupling reaction.
专利号:US-2020122132-A1
优先权日:2018-10-23
标 题 :Palladium acyclic diaminocarbene complexes as precatalysts for hiyama coupling and the tandem one-pot fluoride free hiyama coupling/cyclization for the synthesis of biologically relevant
专利号:CN-109518211-B
优先权日:2019-01-08
标题:Electrochemical synthesis method of aromatic acyl-coupled compound
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Hopkinson, M. N.; Gouverneur, V., Science of Synthesis Knowledge Updates, (2011) 2, 109.
摘要:Mérour, J.-Y.; Joseph, B., Science of Synthesis Knowledge Updates, (2016) 3, 40.
摘要:Guram, A. S.; Milne, J. E.; Tedrow, J. S.; Walker, S. D., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 139.
摘要:Bonrath, W.; Medlock, J. A.; Müller, M.-A., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 1, 212.
摘要:de Frémont, P., Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis, (2016) 1, 406.
📝 需求与反馈
尽可能描述清楚需求与问题信息
