CAS: 50446-44-1; 5'-(4-Carboxyphenyl)-[1,1':3',1''-Terphenyl]-4,4''-Dicarboxylic Acid

该化合物是有机化合物,具有复杂的芳香结构,具有多种碳酸功能组,有助于其酸性,并有可能形成氢结核.苯环的存在增强了其稳定性,有助于其在材料科学中的潜在应用,特别是在聚合物和液体晶体的开发中.化合物的溶解性可因溶剂而异,受可参与离子相互作用的碳酸组的影响.此外,其结构特征可产生有趣的光学特性,使其成为用于光学应用的候选性.该化合物的合成通常涉及多步有机反应,其特性可以使用NMR光谱学,质谱测量和红外线光谱分析等技术来证实其结构和纯度.总的来说,该化合物的溶解性可以因其独特的化学特性而引起学术研究和工业应用的兴趣.

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382137-78-2 118688-53-2 201666-59-3

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CAS号124-38-9 二氧化碳 | CAS号7511-49-1 1,3,5-三(4-溴苯基)苯 | CAS号15797-52-1 1,3,5-三(4-羟苯基)苯 | CAS号109613-00-5 4-乙酰苯基三氟甲烷磺酸酯 | CAS号99-93-4 对羟基苯乙酮 | CAS号3609-53-8 对乙酰基苯甲酸乙酯 | CAS号104-15-4 对甲苯磺酸 | CAS号50446-43-0 1,3,5-三(4-甲基苯基)苯

合成工艺路线路线简述

    📜4,4-二甲基-5-(对甲苯)-1,1:3,1-Ter苯基置于硝酸体系中,化学反应生成 1,3,5-三(4-羧基苯基)苯
    参考文献:überein Neues Kohlenstoffradikal Mit Quartett-Zustand
    标题:überein Neues Kohlenstoffradikal Mit Quartett-Zustand
    摘要:在氮气下,通过将相应的三氯化物与银粉在苯或甲苯中脱卤,制得4,4',4''-(1,3,5-三苯基苯三基)三[二(对-联苯基)甲基] 2.刚性甲苯玻璃中2的esr光谱显示存在d'= 53.5 G的四重态.2的高度稀释溶液服从居里定律.因此,温度相关的缔合平衡被排除在外.的溶解度低2次浓缩的溶液防止调查.2的电化学氧化产生三碳鎓7,它可以可逆地还原为2或三碳鎓8.自由基2与甲苯反应,反应生成氢原子键合于自由基中心的化合物.通过esr光谱鉴定并表征了在该反应中形成的自由基10和11.
    DOI:10.1016/s0040-4020(01)93354-X

    海关参考信息

    专利信息


    专利号:US-2022297083-A1
    优先权日:2019-08-27
    标 题 :Continuous Synthesis Of Porous Coordination Polymers In Supercritical Carbon Dioxide
    发明人:RASMUSSEN ELIZABETH G; KRAMLICH JOHN C; NOVOSSELOV IGOR V
    权利人:UNIV WASHINGTON
    摘要:This disclosure relates generally relates to methods and systems useful for continuous synthesis of materials in super-critical carbon dioxide (sCO 2 ). More particularly, this disclosure relates to methods and systems useful for continuous synthesis of coordination polymers, such as metal-organic frameworks (MOFs) and/or covalent organic frameworks (COFs), in sCO 2 .

    专利号:US-12263464-B2
    优先权日:2018-03-14
    标题 :Method for in-situ synthesis of metal organic frameworks (MOFs), covalent organic frameworks (COFs) and zeolite imidazolate frameworks (ZIFs), and applications thereof
    发明人:PAHWA DEEPAK; PAHWA VARUN; CHOUDHARY ANIL KUMAR; SONIA; JHA VIVEK KUMAR; CHAUHAN ANJALI; YADAV ANNU
    权利人:DESICCANT ROTORS INTERNATIONAL PRIVATE LTD
    摘要:The present invention relates to a method for the in situ synthesis of of MOFs (metal organic frameworks), COFs (covalent organic frameworks), and ZIFs (Zeolitic imidazolate framework), onto and within different types of porous substrates, and their applications. The present invention provides a unique and easy to utilize method by which a number of MOFs, COFs and ZIFs can be synthesized directly onto and within a porous substrate with high performance efficiency ensuring higher grammage in formation of adsorbent product onto and within the substrate.

    专利号:US-9951095-B2
    优先权日:2014-05-16
    标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks
    发明人:ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI
    权利人:TEXAS A & M UNIV SYS
    摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.

    专利号:US-2024190802-A1
    优先权日:2021-04-12
    标 题 :Direct and scalable synthesis of solution processable metal-organic framework nanosheets with variable functionalities
    发明人:ZHAO DAN; YUAN HONGYE
    权利人:NAT UNIV SINGAPORE
    摘要:Disclosed herein are metal organic framework (MOF) suspensions, and sols and compositions comprising MOF nanosheets. Also disclosed herein are their methods of preparation.

    专利号:US-11891406-B2
    优先权日:2019-03-14
    标题:Conductivity enhancement of MOFs via development of MOFpolymer composite material
    发明人:PEEDIKAKKAL ABDUL MALIK P; AL-BETAR ABDUL-RAHMAN; AL-MOUSA AMMAR HUSSAIN
    权利人:UNIV KING FAHD PET & MINERALS
    摘要:A method for enhancing the conductivity of MOF-5 by the development of an MOF-5 polymer composite material. The composite material incorporates a conductive polymer, preferably polyaniline, in the solvo-thermal synthesis pathway of MOF-5. The electrically conductive MOF-5 composite exhibits electric conductivity three orders of magnitude higher than that of MOF-5 while maintaining the crystallinity, robustness, and thermal stability of MOF-5.

    专利号:US-11905246-B2
    优先权日:2014-05-26
    标 题 :Design, synthesis and characterization of metal organic frameworks
    发明人:EDDAOUDI MOHAMED; XUE DONGXU; LUEBKE RYAN; GUILLERM VINCENT; PEEDIKAKKAL ABDUL MALIK PUTHAN; ADIL KARIM; WESELINSKI LUKASZ
    权利人:UNIV KING ABDULLAH SCI & TECH; KING ABDULLAH UNIV OF SCIENCE & TECHNOLOGY
    摘要:A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Seung Bin Baek, Et Al. High-Temperature In Situ Crystallographic Observation Of Reversible Gas Sorption In Impermeable Organic Cages. Proc Natl Acad Sci U S A. 2015 Nov 17;112(46):14156-61.

    合成参考文献


    参考文献:10.1007/978-981-15-5085-0_11
    摘要:Hisaki I, Ji Q, Takahashi K, Nakamura T. Layered Hydrogen-Bonded Organic Frameworks as Highly Crystalline Porous Materials. 2020. In: Advances in Organic Crystal Chemistry.
    参考文献:10.1007/978-981-15-4810-9_5
    摘要:Sáaedi A, Moradi M, Alkordi MH, Mahmoudian MR, Bordbar GH, Yousefi R. Graphene-Metal-Organic Framework Modified Gas Sensor. 2020. In: Materials Horizons: From Nature to Nanomaterials.
    参考文献:10.1055/s-0030-1259143
    摘要:Duan C, Dang D, Wu P, He C, Xie Z. Asymmetric Catalysis with MOFs Prepared via Chiral Induction Effect. Synfacts. 2010 Dec 21;2011(01):0105. doi: 10.1055/s-0030-1259143.
    参考文献:10.1007/978-3-031-20581-1_2
    摘要:Kaur N, Tiwari P, Kapoor KS, Sharma V. Synthesis and Sensing Applications of Peroxidase-Mimic Nanozymes. 2023. In: Environmental Chemistry for a Sustainable World.
    参考文献:10.1007/s00604-021-05023-5
    摘要:Si T, Lu X, Zhang H, Liang X, Wang S, Guo Y. Fabrication of two-dimensional metal-organic framework nanosheets/PDA composites as mixed-mode stationary phase for chromatographic separation. Mikrochim Acta. 2021 Oct 01;188(10):360. doi: 10.1007/s00604-021-05023-5.
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