CAS: 4551-16-0; Bis(Trimethylsilyl)Telluride

该化合物是含有的有机硅化合物,其特点是六甲基替代结构,该化合物因其独特的电子特性和作为化学蒸汽沉降(CVD)过程前体的潜力,对先进材料和半导体研究感兴趣,其分子稳定性和反应性使其适合用于薄膜沉积和光电子装置制造.六甲基组提高了其挥发性和处理效率,而中心则有助于其在铬基材料合成中的效用.由于对湿气和空气的敏感性,需要谨慎处理.

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合成工艺路线路线简述

    📜三甲基氯硅烷置于碲化氢,三乙基硼氢化锂体系中,用 四氢呋喃 作为反应溶剂,化学反应 6.0H,以53%的收率获得产物双三甲基硅基锑
    参考文献:Bis(Trialkylsilyl) Chalcogenides. 1. Preparation And Reduction Of Group Via Oxides
    标题:Bis(Trialkylsilyl) Chalcogenides. 1. Preparation And Reduction Of Group Via Oxides
    摘要:
    DOI:10.1021/jo00346A041

    专利信息


    专利号:US-2011229397-A1
    优先权日:2008-10-03
    标 题:Process and apparatus for continuous flow synthesis of nanocrystals
    发明人:BARTEL JOSEPH; MCKENZIE LALLIE
    权利人:LIFE TECHNOLOGIES CORP
    摘要:Novel reactor, systems and methods of preparing nanocrystals in a continuous flow-through process are provided. The novel reactor is highly configurable and can be modified to achieve desired reaction times of a flow through mixture. The reactor is designed to provide uniform, efficient heating of the reaction mixture.

    专利号:US-12163079-B2
    优先权日:2019-08-12
    标 题 :Synthesis of blue-emitting ZnSe1-xTex alloy nanocrystals with low full width at half-maximum
    发明人:NEWMEYER BENJAMIN; IPPEN CHRISTIAN; MA RUIQING
    权利人:SHOEI CHEMICAL IND CO
    摘要:The invention pertains to the field of nanotechnology. The invention provides highly luminescent nanostructures, particularly highly luminescent nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers. The nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers display a low full width at half-maximum and a high quantum yield. The invention also provides methods of producing the nanostructures.

    专利号:US-8507040-B2
    优先权日:2008-05-08
    标题:Binary and ternary metal chalcogenide materials and method of making and using same
    发明人:XIAO MANCHAO; LEI XINJIAN; YANG LIU
    权利人:XIAO MANCHAO; LEI XINJIAN; YANG LIU; AIR PROD & CHEM
    摘要:This invention discloses the synthesis of metal chalcogenides using chemical vapor deposition (CVD) process, atomic layer deposition (ALD) process, or wet solution process. Ligand exchange reactions of organosilyltellurium or organosilylselenium with a series of metal compounds having neucleophilic substituents generate metal chalcogenides. This chemistry is used to deposit germanium-antimony-tellurium (GeSbTe) and germanium-antimony-selenium (GeSbSe) films or other tellurium and selenium based metal compounds for phase change memory and photovoltaic devices.

    专利号:US-8765223-B2
    优先权日:2008-05-08
    标题 :Binary and ternary metal chalcogenide materials and method of making and using same
    发明人:XIAO MANCHAO; YANG LIU
    权利人:XIAO MANCHAO; YANG LIU; AIR PROD & CHEM
    摘要:This invention discloses the synthesis of metal chalcogenides using chemical vapor deposition (CVD) process, atomic layer deposition (ALD) process, or wet solution process. Ligand exchange reactions of organosilyltellurium or organosilylselenium with a series of metal compounds having neucleophilic substituents generate metal chalcogenides. This chemistry is used to deposit germanium-antimony-tellurium (GeSbTe) and germanium-antimony-selenium (GeSbSe) films or other tellurium and selenium based metal compounds for phase change memory and photovoltaic devices.

    专利号:US-11753587-B2
    优先权日:2018-05-30
    标 题:Method for synthesis of blue-emitting ZnSe1-xTEx alloy nanocrystals
    发明人:IPPEN CHRISTIAN; TRUSKIER JONATHAN; MANDERS JESSE
    权利人:NANOSYS INC
    摘要:The invention relates to highly luminescent nanostructures, particularly highly luminescent nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers. The invention also relates to methods of producing such nanostructures.

    专利号:US-9759727-B2
    优先权日:2010-03-23
    标 题:Ligands for semiconductor nanocrystals
    发明人:HAN HEE-SUN; LIU WENHAO; BAWENDI MOUNGI G
    权利人:HAN HEE-SUN; LIU WENHAO; BAWENDI MOUNGI G; MASSACHUSETTS INST TECHNOLOGY
    摘要:In this invention, polyimidazole ligands (PILs) incorporating pendant imidazole moieties for nanocrystal binding and either sulfonatebetaine, carboxybetaine, or phosphocholinebetaine moieties for water-solubilization have been developed. Greatly enhanced stability of nanocrystals (both over time and in wide pH range) was achieved by incorporating multi-dentate imidazole moieties which provide strong coordination of the ligand to the nanocrystal surface and prevent aggregation of nanocrystals. Synthesis of betaine PILs was developed by modifying the synthesis of recently developed PEG containing poly imidazole ligands (PEG PILs). These nanocrystals are compact, water soluble, and biocompatible.

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    合成参考文献


    摘要:Thornton, P., Science of Synthesis, (2003) 5, 93.
    摘要:Murai, T., Science of Synthesis, (2005) 22, 214.
    摘要:Polo, A.; Real, J., Science of Synthesis, (2008) 39, 1160.
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