CAS: 2181-42-2; Trimethylsulfonium Iodide
该化合物是一种四氟铵盐,其特点是三甲基硫化二氮酸盐和碘化硫化硫酸离子.它一般是白色晶状固体,在水和酒精等极溶剂中溶解.该化合物以其血压特征而著称,这意味着它吸收空气的湿度.三甲基硫化硫碘化物经常被用作有机合成的试剂,特别是用于形成硅化磺酰胺,这是各种化学反应中的宝贵中间体,包括通过维蒂格反应合成烷.碘化离子的存在也具有一定的再活性,使其在核细胞替代反应中有用.此外,这种化合物显示出典型的四氟化铵盐的特性,例如是一种良好的阶段转移催化剂.在处理时,应当采取安全防范措施,因为潜在的刺激效应,许多化学物质都是如此.
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;;;; - InChIKey: VFJYIHQDILEQNR-UHFFFAOYSA-M
- InChI=1S/C3H9S.HI/c1-4(2)3;/h1-3H3;1H/q+1;/p-1
- 计算化学: 氢键受体数*氢键供体数0可旋转键数0
相似化合物
3084-53-5 676-88-0物理性质
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CAS号75-18-3 二甲基硫 | CAS号74-88-4 碘甲烷 | CAS号75-11-6 二碘甲烷 | CAS号74-93-1 甲硫醇 | CAS号592-88-1 二烯丙基硫醚 | CAS号23973-54-8 METHALLYLSULPHIDE | CAS号291-21-4 S-三聚硫代甲 | CAS号857954-23-5 (fluoren-2-yl-p... | CAS号624-92-0 二甲基二硫醚 | CAS号3658-80-8 二甲基三硫 | CAS号104953-00-6 4-(2-甲基氧基-2-基)苯甲腈 | CAS号111991-17-4 2-[4-(trifluoro... | CAS号106776-17-4 Trimethylsulfon... | CAS号4427-96-7 乙烯基碳酸乙烯酯 | CAS号32017-76-8 2-(4-溴苯基)环氧乙烷 | CAS号5063-65-0 1,2-环氧庚烷 | CAS号4393-06-0 1-苯基-2-丙烯-1-醇 | CAS号6006-81-1 β-甲烯基苯乙醇 | CAS号4938-52-7 1-庚烯-3-醇 | CAS号171361-65-2 乙基 1-恶螺[2.5]辛烷-6-羧酸酯合成工艺路线路线简述
- 合成目标产物 Trimethylsulfonium Iodide 主要起始原料 Dimethyl Sulfide And Iodomethane
- (文献来源)合成步骤主要原料 Dimethyl Sulfide 和 Iodomethane
📜碘甲烷置于三苯基胂硫化物体系中,用 丙酮 用作溶剂,化学反应生成三甲基碘化锍
参考文献:Kamai,G.Kh. Et Al.,Journal Of General Chemistry Of The Ussr,1971,Vol. 41,P. 2036-2040
标题:Kamai,G.Kh. Et Al.,Journal Of General Chemistry Of The Ussr,1971,Vol. 41,P. 2036-2040
海关参考信息
- 2930909099-其他有机硫化合物
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-4339388-A
优先权日:1980-04-22
标题 :Synthesis of periplanone-B
发明人：STILL W CLARK
权利人:STILL W CLARK
摘要:A synthesis of periplanone-B, a female sex pheromone of the American cockroach, P. americana, is described. Novel compounds which are useful as intermediates in the synthesis of periplanone-B are described including the precursor alcohol, periplanol-B.
专利号:WO-8400363-A1
优先权日:1982-07-12
标题 :Synthesis of periplanone-b
发明人：STILL W CLARK
权利人:HERCULITE PRODUCTS INC
摘要:A synthesis of periplanone-B, a female sex pheromone of the American cockroach, P. americana. Novel compounds which are useful as intermediates in the synthesis of periplanone-B are described including the precursor alcohol, periplanol-B.
专利号:US-10392361-B2
优先权日:2016-01-21
标题:Process for the synthesis of intermediates of Nebivolol
发明人：BARTOLI SANDRA; MANNUCCI SERENA; GRISELLI ALESSIO; STEFANINI ALESSIO
权利人:MENARINI INT OPERATIONS LUXEMBOURG SA
摘要:The present invention relates to a novel process for the synthesis of the intermediate compounds constituted by chromanyl haloketones of formula III and 6-fluoro-2-(oxiran-2-yl)chromans of formula I. n The intermediates thus obtained can be used for the synthesis of Nebivolol.
专利号:US-2012203004-A1
优先权日:2009-08-13
标题 :process for the synthesis of alkyl/aralkyl (2s)-2-(tert-butoxycarbonyl)-amino-2-[-8-azabicyclo[3.2.1]oct-3-yl]-exo-acetate and analogs thereof: key intermediates for the preparation of dppiv inhibitors
发明人：ROY BHAIRAB NATH; KAMBOJ RAJENDER KUMAR; GOERGE SHAJI K; VENUGOPAL SPINVIN C; SHANMUGVADIVELU MUTHU KUMARAN; SINHA NEELIMA
权利人:ROY BHAIRAB NATH; KAMBOJ RAJENDER KUMAR; GOERGE SHAJI K; VENUGOPAL SPINVIN C; SHANMUGVADIVELU MUTHU KUMARAN; SINHA NEELIMA; LUPIN LTD
摘要:An improved process for the synthesis of intermediates like Alkyl/Aralkyl (2S)-2-(tert-butoxycarbonyl)-amino-2-[-8-azabicyclo[3.2.1]oct-3-yl]-exo-acetate and analogs thereof which are useful in the synthesis of Dipeptidyl peptidase-IV (DP-PIV) inhibitors.
专利号:US-9809566-B2
优先权日:2012-09-06
标题:Organocatalytic process for asymmetric synthesis of decanolides
发明人：RAWAT VARUN; DEY SOUMEN; SHELKE ANIL MARUTI; SURYAVANSHI GURUNATH MALLAPPA; SUDALAI ARUMUGAM
权利人:COUNCIL SCIENT IND RES
摘要:The present invention discloses organocatalytic process for asymmetric synthesis of highly enantioselective decanolide compounds in high yield with >99% ee. Further, the present invention disclose cost effective, improved organocatalytic process for asymmetric synthesis of highly enantioselective decanolides compounds from non-chiral, cheap, easily available raw materials.
专利号:US-2007122842-A1
优先权日:2005-11-30
标题 :Massively parallel synthesis of proteinaceous biomolecules
发明人：RAJASEKARAN JOHN J; TIWARI GUNJAN; CABEZAS EDELMIRA; FIDANZA JACQUELINE A; SUNDARARAJAN NARAYAN
权利人:RAJASEKARAN JOHN J; TIWARI GUNJAN; CABEZAS EDELMIRA; FIDANZA JACQUELINE A; SUNDARARAJAN NARAYAN
摘要:Methods for fabricating dense arrays of polymeric molecules in a highly multiplexed manner are provided using semiconductor-processing-derived lithographic methods. Advantageously, the methods are adaptable to the synthesis of a variety of polymeric compounds. For example, arrays of peptides and polymers joined by peptide bonds may be fabricated in a highly multiplexed manner.
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主要参考文献
[参考文献]: C M Kerchove, Et Al. Evaluation Of The Cholinomimetic Actions Of Trimethylsulfonium, A Compound Present In The Midgut Gland Of The Sea Hare Aplysia Brasiliana (Gastropoda, Opisthobranchia). Braz J Med Biol Res. 2002 Apr;35(4):485-91.[参考文献]: E Klein, Et Al. Simultaneous Derivatization Of Acyl And S-Alkyl Moieties Of Acyl Thioesters By Using Trimethylsulfonium Hydroxide For Gas Chromatographic Analysis. Lipids. 2000 May;35(5):575-7.
[参考文献]: Erin L Pflaster, Et Al. A High-Throughput Fatty Acid Profiling Screen Reveals Novel Variations In Fatty Acid Biosynthesis In Chlamydomonas Reinhardtii And Related Algae. Eukaryot Cell. 2014 Nov;13(11):1431-8.
[参考文献]: H P Nalik, Et Al. Rapid Identification Of Legionella Species From A Single Colony By Gas-Liquid Chromatography With Trimethylsulphonium Hydroxide For Transesterification. J Med Microbiol. 1992 Jun;36(6):371-6.
[参考文献]: K Vosmann, Et Al. Reaction Of Lipids Containing Hydroxy Groups With Trimethylsulfonium Hydroxide: Formation Of O-Methyl Derivatives. Lipids. 1996 Mar;31(3):349-52.
合成参考文献
摘要:Chang, C.-S.; Wu, Y.-T., Science of Synthesis, (2010) 45, 978.
摘要:Hong, J., Science of Synthesis Knowledge Updates, (2012) 1, 284.
摘要:Mlostoń, G.; Heimgartner, H., Science of Synthesis Knowledge Updates, (2014) 4, 417.
摘要:Johnson, J. B., Science of Synthesis: Stereoselective Synthesis, (2011) 3, 795.
摘要:Toxicology and Applied Pharmacology., 20(135), 1971 []
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