CAS: 96405-62-8; (5S,6R)-6-((1R,2R)-1,2-Dihydroxy-2-Phenylethyl)-5-Hydroxy-5,6-Dihydro-2H-Pyran-2-One

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上下游产品

-5,6-dihydropyran-2-one(5S,6R)-5-hydroxy-6-(1R,2R)-1,2-isopropylidenyloxy-2-phenylethyl-5,6-dihydropyran-2-one 4,6-O-Isopropylidene-7-C-phenyl-D-gluco-hept-2-enono-δ-lactone (5S,6R)-6-[(1S,2R)-1-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-ethyl]-5-hydroxy-5,6-dihydro-pyran-2-one -5-(methoxymethoxy)-5,6-dihydro-2H-pyran-2-one(5S,6R,7R,8R)-6-7,8-dihydro-8-hydroxy-7-(methoxymethoxy)styryl-5-(methoxymethoxy)-5,6-dihydro-2H-pyran-2-one(+)-goniofufurone

合成工艺路线路线简述

    📜(4R,5R)-2,2-Dimethyl-5-Phenyl-[1,3]Dioxolane-4-Carbaldehyde置于chromium(Vi) Oxide,叔丁基过氧化氢,正丁基锂,Bis(Acetylacetonate)Oxovanadium,三乙酰氧基硼氢化钠,三氟乙酸体系中,用 四氢呋喃,二氯甲烷,水 作为反应溶剂,化学反应 19.25H,反应生成 哥纳香三醇
    参考文献:Asymmetric Total Synthesis Of (+)-Goniotriol And (+)-Goniofufurone
    标题:Asymmetric Total Synthesis Of (+)-Goniotriol And (+)-Goniofufurone
    摘要:The Enantioselective Synthesis Of Two Antitumor Styryl Lactones,(+)-Goniotriol And (+)-Goniofufurone,Have Been Completed Starting From Cinnamyl Alcohol In Ten And Eleven Steps With An Overall Yield Of 21% And 12%,Respectively.
    DOI:10.1016/0040-4020(94)01025-U

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    主要参考文献

    参考标题:Stereoselective Synthesis Of (+)-Goniodiol, (+)-Goniotriol, (-)-Goniofupyrone, And (+)-Altholactone Using A Catalytic Asymmetric Hetero-Diels-Alder/allylboration Approach
    作者:Annaïck Favre,François Carreaux,Michael Deligny,Bertrand Carboni |发布日期:2008.10
    摘要:The Stereoselective Total Synthesis Of Several Members Of The Styryllactone Family Was Achieved Efficiently From Common Intermediate 8, Prepared By A Catalytic Asymmetric Inverse-Electron-Demand Hetero-Diels-Alder/allylboration Sequence. The Transformation Of 8 Into α,β-Unsaturated Lactone Led To The Preparation Of (+)-Goniodiol (1) In A Reduced Number Of Steps. The Epoxidation Reaction Was Used To

    合成参考文献


    参考文献:10.1055/s-0029-1219557
    摘要:Mohapatra D, Yadav J, Kumar B, Bhaskar K. First Total Syntheses of (+)-Garvensintriol and (+)-5-epi-Garvensintriol. Synlett. 2010 Feb 26;2010(07):1059–62. doi: 10.1055/s-0029-1219557.
    参考文献:10.1016/0031-9422(92)83645-f
    摘要:Wu Y, Chang F, Duh C, Wang S, Wu T. Cytotoxic styrylpyrones of Goniothalamus amuyon. Phytochemistry. 1992 Aug;31(8):2851–3. doi: 10.1016/0031-9422(92)83645-f.
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