CAS: 5069-23-8; 2,5-Diethylthiophene

该化合物是一种代用硫苯衍生物,其特点是在环环环的2和5个位置上存在乙基组,该化合物主要用作有机合成的中间体,特别是用于开发同质聚合物,电子材料和药品,其结构特征有助于提高溶性和可金枪鱼电子特性,使其在光电子和材料科学的应用中具有价值.乙基替代成分还提高了稳定性和可处理性,而无替代硫苯则具有明确界定的分子结构,2,5-二乙基苯提供了持续的再活动性,促进了其在受控聚合和功能反应中的使用.

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MSDS等安全信息

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    CAS号2955-65-9 3,6-辛二酮 | CAS号1629-58-9 1-戊烯-3-酮 | CAS号872-55-9 2-乙基噻吩 | CAS号10504-06-0 2,5-diethylfuran | CAS号33252-91-4 2-ethyl-5-iodot... | CAS号75-03-6 碘乙烷 | CAS号18761-46-1 1-(5-乙基-2-噻吩)-乙酮 | CAS号111-65-9 正辛烷 | CAS号872-55-9 2-乙基噻吩 | CAS号107112-13-0 2,3,5-triethyl-... | CAS号58620-26-1 2,4-diethylthiophene | CAS号188290-36-0 Thiophene(SIV) | CAS号1795-01-3 3-乙基噻吩 | CAS号75-15-0 二硫化碳

    合成工艺路线路线简述

      📜2-乙基噻吩置于四氯化锡,一水合肼,苯体系中,化学反应生成 2,5-二乙基噻吩
      参考文献:Steinkopf Et Al.,Justus Liebigs Annalen Der Chemie,1941,Vol. 546,P. 180,194
      标题:Steinkopf Et Al.,Justus Liebigs Annalen Der Chemie,1941,Vol. 546,P. 180,194

      海关参考信息

      专利信息


      专利号:US-2003064979-A1
      优先权日:2001-06-29
      标题 :Method of inhibiting PTP 1B and /or T-cell PTP and/or other PTPases with an Asp residue at position 48
      发明人:HANSEN THOMAS KRUSE; OLSEN OLE HVILSTED; PETERSEN ANDERS KLARSKOV; LAU JESPER; ANDERSEN HENRIK SUNE; MOLLER NIELS PETER HUNDAHL
      摘要:This invention relates to oxalylamide inhibitors of Protein Tyrosine Phosphatase 1B (PTP1B) and/or T-cell Protein Tyrosine Phosphatase (TC-PTP) and/or Protein Tyrosine Phosphatases (PTPases) having an aspartic acid (Asp) in position 48 (PTP1B numbering, Chernoff et al, Proc Natl Acad Sci USA 87: 2735-2789 (1989)) and a method of inhibiting such PTPases by exposing the enzyme to inhibitor compounds of formula 1 n n n This invention also relates to (I) the design and selection of inhibitors, which bind to the active site of PTP1B and/or TC-PTP and/or PTPases having an aspartic acid (Asp) in position 48 (II) the synthesis of said inhibitors, methods for their preparation and (III) to compositions comprising the inhibitor compounds.

      专利号:US-9663594-B2
      优先权日:2014-05-15
      标 题 :Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports
      发明人:HLAVINKA MARK L
      权利人:CHEVRON PHILLIPS CHEMICAL CO LP; CHEVRON PHILIPS CHEMICAL COMPANY LP
      摘要:Disclosed herein are methods of making bis(phenol) ligand compounds and transition metal bis(phenolate) compounds. The transition metal bis(phenolate) compounds can be used as components in catalyst systems for the polymerization of olefins.

      专利号:US-11332462-B2
      优先权日:2012-02-08
      标 题 :Heteroaryl compounds and methods of use thereof
      发明人:CAMPBELL JOHN EMMERSON; CAMPBELL UNA; HANANIA TALEEN G; SHAO LIMING
      权利人:SUNOVION PHARMACEUTICALS INC; PGI DRUG DISCOVERY LLC
      摘要:Provided herein are thiophene compounds, methods of their synthesis, pharmaceutical compositions comprising the compounds, and methods of their use. The compounds provided herein are useful for the treatment, prevention, and/or management of various neurological disorders, including but not limited to, psychosis and schizophrenia.

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      合成参考文献


      参考文献:10.1007/bf00953011
      摘要:Ryashentseva MA, Minachev KM, Belanova EP, Bogdanov VS. Reactivity of C6-C8 alkanes in forming alkylthiophenes and aromatic hydrocarbons in the presence of H2S on a Cr-containing catalyst. Russian Chemical Bulletin. 1985 Dec;34(12):2489–92. doi: 10.1007/bf00953011.
      参考文献:10.1007/pl00021990|10.1007/s10975-005-0013-z|10.1007/s10975-005-0050-7|10.1007/s10975-005-0051-6
      摘要:Tsodikov MV, Kugel’ VY, Yandieva FA, Kliger GA, Glebov LS, Mikaya AI, Zaikin VG, Slivinskii EV, Plate NA, Gekhman AE, Moiseev II. Reductive dehydration of alcohols: A route to alkanes. Kinetics and Catalysis. 2004 Nov;45(6):854–66. doi: 10.1007/s10975-005-0013-z.
      参考文献:10.1007/bf00903389
      摘要:Danyushevskii YL, Marakatkina MA, Gol'dfarb YL. Synthesis in the furan series from organolithium compounds. Russian Chemical Bulletin. 1968 Nov;17(11):2397–404. doi: 10.1007/bf00903389.
      参考文献:10.3103/s0361521917060076
      摘要:Romadenkina SB, Sverchkov AA, Zemlyakov AY, Lobankov EV, Ilyasov VS. Chemical composition and physicochemical characteristics of shale tar from the Kotsebinskoe deposit. Solid Fuel Chemistry. 2017 Nov;51(6):355–7. doi: 10.3103/s0361521917060076.
      参考文献:10.1007/bf00479935
      摘要:Ryashentseva MA, Afanas'eva YA, Minachev KM. Catalytic methods for obtaining thiophene and alkylthiophenes from petroleum refining products and sulfur-containing organic compounds. Chemistry of Heterocyclic Compounds. 1971 Oct;7(10):1215–26. doi: 10.1007/bf00479935.
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