专利号:US-11685712-B2 优先权日:2019-12-30 标 题 :Synthesis of monofunctional thiuram accelerator 发明人:SPILKER THOMAS FRANKLIN; Jin ji yang; FEHER FRANK J 权利人:GOODYEAR TIRE & RUBBER 摘要:The present invention provides a route for synthesizing monofunctional thiuram compounds that is safe, environmentally friendly, and cost effective. This method specifically involves synthesizing a monofunctional thiuram by (1) reacting a tetraorganylthiuram disulfide with an organyl mercaptan to produce the monofunctional thiuram and a dithiocarbamate metal salt or a dithiocarbamate metalloid salt under basic conditions, (2) separating the monofunctional thiuram in an organic phase from the dithiocarbamate metal salt or the dithiocarbamate metalloid salt in an aqueous phase, and (3) recovering the monofunctional thiuram from the aqueous phase. The monofunctional thiuram compounds made in accordance with this invention are of particular value as accelerators for use in the vulcanization of rubber. The use of these monofunctional thiuram compounds as accelerators provides good cure rates and as well as good scorch safety.
专利号:WO-2014118073-A1 优先权日:2013-01-29 标 题 :Polysulfide polyols, their production and use in the synthesis of polyurethanes 发明人:BALBO BLOCK MARCO; RHUDY KEVIN; FLECKENSTEIN CHRISTOPH 权利人:BASF SE 摘要:The present invention relates to sulfur containing polyols, a process for their production by reaction of at least one unsaturated alcohol A with elemental sulfur, wherein the unsaturated alcohol A has only one carbon-carbon double bond-unsaturation per molecule. The sulfur containing polyols are used in the production of polyurethanes, in particular rigid foam polyurethanes, for high-temperature pipe insulation applications.
专利号:US-11098145-B2 优先权日:2015-05-12 标题:Method for the synthesis of a copolymer, copolymer, rubber mixture, and use thereof 发明人:HERZOG KATHARINA; MUELLER LENA; RECKER CARLA; PRUSS NOA; CONRAD CATHRIN SONJA; VANA PHILLIPP 权利人:CONTINENTAL REIFEN DEUTSCHLAND GMBH 摘要:Disclosed are processes for preparing a copolymer, a copolymer prepared by the process, a sulfur-crosslinkable rubber mixture, and the use of the sulfur-crosslinkable rubber mixture for production of motor vehicle tires. In one embodiment, the monomer has the formula: A-S-P, wherein A is a chemical group containing at least one aliphatic double bond, S is a sulfur atom, and P is a protecting group.
专利号:US-10494336-B2 优先权日:2015-05-12 标题:Monomer for copolymerization with alkenes, dienes, vinyl compounds and/or vinylidene compounds, method for the synthesis of a copolymer, copolymer, rubber mixture and use thereof 发明人:HERZOG KATHARINA; MUELLER LENA; RECKER CARLA; PRUSS NOA; CONRAD CATHRIN SONJA; VANA PHILLIPP 权利人:CONTINENTAL REIFEN DEUTSCHLAND GMBH 摘要:Disclosed are monomers for copolymerization with alkenes, dienes, vinyl compounds, and/or vinylidene compounds, a process for preparing a copolymer, a copolymer prepared by the process, a sulfur-crosslinkable rubber mixture, and the use of the sulfur-crosslinkable rubber mixture for production of motor vehicle tires. In one embodiment, the monomer has the formula A-S—P, wherein A is a chemical group containing at least one Câ•?C aliphatic double bond, S is a sulfur atom, and P is a protecting group.
专利号:US-2023029068-A1 优先权日:2019-12-30 标题:Synthesis of monofunctional thiuram accelerator
专利号:EP-3845520-B1 优先权日:2019-12-30 标题:Synthesis of monofunctional thiuram accelerator
参考标题:Cerium Ammonium Nitrate-Catalyzed Aerobic Oxidative Coupling Of Dithiocarbamates: Facile Synthesis Of Thioureas And Bis(Aminothiocarbonyl)Disulfides 作者:Tian-Tian Li,Xiang-Hai Song,Mei-Shuang Wang,Ning Ma 摘要:Diverse Disubstituted And Trisubstituted Thioureas Were Synthesized By The Condensation Of Dithiocarbamate Tea (Or Dabco) Salts And Amines Using Cerium Ammonium Nitrate (Can) As A Catalyst In High Yields At Room Temperature. It Is A One-Pot Method And It Is Unnecessary To Isolate Isothiocyanates. This Reaction Probably Took Place Through Nucleophilic Addition Of Amines To Isothiocyanates, Which Were Generated By Oxidative Coupling Of Dithiocarbamates And The Following Decomposition Of Bis(Aminothiocarbonyl)Disulfides. When Secondary Amines And Cs2 Served As The Reactants, Bis(Aminothiocarbonyl)Disulfides Were Obtained Via Tandem Nucleophilic Addition/oxidative Coupling Reactions In Moderate To Excellent Yields. In All The Coupling Reactions, The Oxidant Was Air And Can Possibly Acted As An Set Catalyst.
合成参考文献
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198