CAS: 827616-50-2; 3,5-Diiodoisonicotinonitrile

化学文摘社编号为827616-50-2,便于识别和检索有关其安全,处理和监管状况的信息.与许多卤化合物一样,在使用和处置过程中必须考虑环境和健康影响.

英文名称3,5-Diiodoisonicotinonitrile
中文名称3,5-二碘异烟腈
IUPAC名称3,5-diiodoisonicotinonitrile
其它别名4-氰基-3,5-二碘吡啶; 4-Cyano-3,5-Diiodopyridine
CAS编号827616-50-2
MFCD编号:MFCD09037450
分子式:C6H2I2N2分子量:355.9
产品CID: 1817860
产品分类有机原料→分子砌块→芳杂环类化合物→吡啶类化合物

相似结构搜索
InChIKey: CKTZXTXSOCLOBD-UHFFFAOYSA-N
InChI=1S/C6H2I2N2/c7-5-2-10-3-6(8)4(5)1-9/h2-3H
计算化学: 氢键受体数2.0氢键供体数*可旋转键数*

相似化合物

38749-96-1 908279-56-1 10386-28-4

MSDS等安全信息

GHS符号GHS06
警示词Danger
危险描述H301-H311-H331
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P361+P364-P405-P501
危险等级6.1
UN编号3439.0
危险品标志Xi
包装等级Ⅲ

上下游产品

pyridine-4-carbonitrile

合成工艺路线路线简述

📜4-氰基吡啶置于碘体系中,用四氢呋喃作为反应溶剂,化学反应 1.5H,反应生成 4-氰基-3,5-二碘吡啶
参考文献:Synthesis Of Ortho-Substituted Cyanopyridines Through Lithio Intermediate Trapping
标题:Synthesis Of Ortho-Substituted Cyanopyridines Through Lithio Intermediate Trapping
摘要:Ortholithiation Of 4-Cyanopyridine Using 2,2,6,6-Tetramethylpiperidide (Litmp) And Trapping The Lithio Intermediate With Electrophiles Represents An Efficient And Straightforward Access To Ortho-Substituted-4-Cyanopyridines. The Cyano Group Can Be Used As An Ortho-Directing Group And Allows The Preparation Of 3-Halogeno-4-Cyanopyridines. Reactivity Of 2-And 3-Cyanopyridines Is Also Investigated And Seems To Give Similar Results. (C) 2004 Elsevier Ltd. All Rights Reserved.
DOI:10.1016/j.Tetlet.2004.11.021