CAS: 61995-20-8; Benzyl 3-Oxopiperidine-1-Carboxylate

上下游产品

CAS号95798-22-4 N-苄氧羰基-3-羟基哌啶 | CAS号501-53-1 氯甲酸苄酯 | CAS号50717-82-3 3-哌啶酮 | CAS号40114-49-6 1-苄基-3-哌啶酮 | CAS号6859-99-0 3-羟基哌啶 | CAS号5105-78-2 N-苄氧羰基-4-氨基丁酸 | CAS号50606-58-1 1-苄基-3-哌啶酮盐酸盐 | CAS号138163-15-2 1-哌啶甲酸3-亚甲基苯甲酯

N-苄氧羰基-4-氨基丁酸置于copper Acetylacetonate,Ro-Co-Cl (R = Bn Or I-Bu),三乙胺体系中,用 四氢呋喃,乙醚,苯 作为反应溶剂,化学反应 6.0H,反应生成 1-Cbz-3-哌啶酮
参考文献:Intramolecular N-h Insertion Of α-Diazocarbonyls Catalyzed By Cu(Acac)2: An Efficient Route To Derivatives Of 3-Oxoazetidines,3-Oxopyrrolidines And 3-Oxopiperidines
标题:Intramolecular N-h Insertion Of α-Diazocarbonyls Catalyzed By Cu(Acac)2: An Efficient Route To Derivatives Of 3-Oxoazetidines,3-Oxopyrrolidines And 3-Oxopiperidines
摘要:Cu(Acac)2被发现是羧烯体催化的分子内n-h插入反应的高效催化剂.在以cu(Acac)2为催化剂的重氮分解反应中,羧烯体的竞争性分子内c-h插入并不是一个问题.该反应以中到好的产率提供了3-氧杂环丁烷,3-氧杂环戊烷和3-氧杂环己烷的衍生物.
DOI:10.1039/a903722E

专利信息

专利号:CN-117486785-A
优先权日:2023-10-30
标题:A kind of synthesis method of chiral piperidinol derivatives

专利号:CN-118791425-A
优先权日:2024-06-18
标题:Synthesis method of 1-BOC-3-piperidone and similar cyclic ketone compounds thereof