CAS: 14221-00-2; Tetrakis(Triphenyl Phosphite)Nickel(0)

欧盟法规

[ECHA物质

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CAS号101-02-0 亚磷酸三苯酯 | CAS号3264-82-2 乙酰丙酮镍 | CAS号14653-44-2 dicarbonyl-bis-... | CAS号77450-60-3 Bis(acrylonitri... | CAS号1271-28-9 二茂镍 | CAS号7440-02-0 镍 | CAS号13463-39-3 羰基镍

📜亚磷酸三苯酯,Nickel(II) Nitrate Hexahydrate置于sodium Tetrahydroborate体系中,用 乙腈 用作溶剂,以46%的收率获得四(亚磷酸三苯酯)镍
参考文献:四面体镍(0)配合物的合成和发光性质
标题:四面体镍(0)配合物的合成和发光性质
摘要:四面体镍(0)络合物[nil 4 ],[ni(dppe)2 ]和[ni(co)2(sbph 3)2 ](l = Asph 3,Sbph 3,P(oph)3,Dppe = 1,通过在配体存在下在n 2或co气氛下用nabh 4还原nicl 2 .6H 2 O制备2-双(二苯基膦基)乙烷.Nicl 2 .6H 2 O / Sbph 3体系在铂金丝网上于-1.3 V(ag / Ag +)电解得到复合物[ni(sbph 3)4 ].(摩尔比= 1:4).这些复合物,无论是固态还是溶液,当被紫外线辐射激发时,在室温下均呈橙色发射.提出了[nil 4 ]配合物的定性分子轨道图.配合物的电子吸收光谱显示出在400 Nm附近的谱带,被指定为mlctπ∗ 2E <-d 2T2.建议在这些系统中观测到的发射具有1 A 1 <-3 T 1跃迁.根据时间分辨的发射光谱估算了微秒范围内的寿命.还研究了游离配体的光谱性质.
Doi:10.1016/s0020-1693(96)05335-2

专利信息

专利号:EP-0104197-B1
优先权日:1982-03-26
标题 :Process for the production of ethanol
摘要:Ethanol is produced by carbonylation of methanol by reaction with carbon monoxide in the presence of a carbonylation catalyst to form acetic acid which is then converted to an acetate ester followed by hydrogenolysis of the acetate ester formed to give ethanol or a mixture of ethanol and another alcohol which can be separated by distillation. Preferably the other alcohol or part of the ethanol recovered from the hydrogenolysis step is recycled for further esterification. Carbonylation can be effected using a CO/H2 mixture and hydrogenolysis can similarly be conducted in the presence of carbon monoxide, leading to the possibility of circulating gas between the carbonylation and hydrogenolysis zones with synthesis gas, preferably a 2:1 H2:CO molar mixture being used as make up gas.