CAS: 137897-99-5; 1,2-Bis(3,5-Dichlorophenyl)Disulfane

该化合物是一种具有有机合成和材料科学应用的氯化芳香脱硫化合物,其高氯含量和脱硫联系有助于其稳定性和反应性,使其成为生产专门聚合物,阻燃剂和含硫化合物的中间体.对称的四氯化合物结构增强了其热抗力和化学抗药性,而脱硫结合允许在交叉连接或再氧化过程中有控制的再活动.该化合物因其精确的分子结构而特别受到重视,这种结构能够对先进的材料配方进行量身修改.由于在特定条件下它具有潜在的再活动性和稳定性,需要适当处理.

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相似化合物

1142-19-4 31121-19-4 882-33-7

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上下游产品

CAS号705-21-5 3,5-二氯苯磺酰氯 | CAS号17231-94-6 3,5-二氯苯硫酚 | CAS号705-21-5 3,5-二氯苯磺酰氯 | CAS号137897-90-6 6-(3,5-dichloro...

合成工艺路线路线简述

    📜3,5-二氯苯磺酰氯置于氢溴酸,溶剂黄146,苯酚体系中,用77.5%的收率获得3,3',5,5'-四氯二苯二硫醚
    参考文献:芳族二硫化物合成芳基全氟烷基硫化物
    标题:芳族二硫化物合成芳基全氟烷基硫化物
    摘要:在二芳基二硫化物存在下,氙 (II) 双(全氟烷烃羧酸盐)的热解通过 Ss 键断裂发生,形成二卤代-,卤代硝基-和卤代二硝基苯基全氟烷基硫化物.后一类化合物是首次获得.主要的副过程是芳环的全氟烷基化.
    Doi:10.1023/b:Rucb.0000030820.47938.Ab

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    专利信息


    专利号:US-9908846-B2
    优先权日:2014-02-21
    标题:Composition, synthesis, and use of new arylsulfonyl isonitriles
    发明人：FLEMING FRASER FERGUSSON; LUJAN MONTELONGO JESUS ARMANDO
    权利人:DUQUESNE UNIV OF THE HOLY GHOST; UNIV HOLY GHOST DUQUESNE
    摘要:This invention relates to novel isonitriles, including arylsulfonyl isonitriles, and methods for their synthesis. The isonitriles include a conjugated ring system. The structure is designed with the flexibility to have multiple substitution patterns. The isonitriles may be used in applications including, but not limited to, pharmaceutical compositions.

    专利号:CN-115028641-A
    优先权日:2022-07-19
    标题:A method for cobalt-catalyzed synthesis of 5,8-difunctional substituted imidazo[1,2-a]pyrazine compounds

    专利号:US-2015239833-A1
    优先权日:2014-02-21
    标题:Composition, synthesis, and use of new arylsulfonyl isonitriles

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    主要参考文献

    参考标题:Green Aerobic Oxidation Of Thiols To Disulfides By Flavin-Iodine Coupled Organocatalysis
    作者:Hiroki Iida,Marina Oka,Ryo Kozako |发布日期:2021.7
    摘要:Molecular Iodine Successfully Promoted The Aerobic Oxidation Of Thiols To Disulfides Under Metal-Free Mild Conditions. The Activation Of Molecular Oxygen Occurred Smoothly At Room Temperature Through The Transfer Of Electrons From The Iodine Catalyst To The Biomimetic Flavin Catalyst, Forming The Basis For A Green Oxidative Synthesis Of Disulfides From Thiols.

    合成参考文献


    摘要:Silva, V. L. M.; Pinto, D. C. G. A.; Santos, C. M. M.; Rocha, D. H. A., Science of Synthesis Knowledge Updates, (2022) 3, 361.
    摘要:Kwiatkowska, M.; Kiełbasiński, P., Science of Synthesis: Knowledge Updates, (2024) 3, 442.
    摘要:Kwiatkowska, M.; Kiełbasiński, P., Science of Synthesis: Knowledge Updates, (2024) 3, 422.
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