CAS: 932-72-9; (Dichloroiodo)Benzene

结构式图片

相似化合物

591-50-4 104013-25-4 860585-01-9

上下游产品

CAS号591-50-4 碘苯 | CAS号71-43-2 苯 | CAS号536-80-1 亚碘酰苯 | CAS号1015765-81-7 iodosylbenzene | CAS号3240-34-4 碘苯二乙酸 | CAS号2712-78-9 [双(三氟乙酰氧基)碘]苯 | CAS号106266-43-7 N-phenyliodonio... | CAS号507-20-0 氯代叔丁烷 | CAS号101-84-8 二苯醚 | CAS号75-52-5 硝基甲烷 | CAS号536-80-1 亚碘酰苯 | CAS号7647-01-0 盐酸 | CAS号591-50-4 碘苯 | CAS号13898-47-0 chlorous acid | CAS号421-83-0 三氟甲烷磺酰氯 | CAS号434-90-2 全氟联苯 | CAS号637-87-6 对氯碘苯 | CAS号615-41-8 邻氯碘苯 | CAS号636-98-6 4-硝基碘苯 | CAS号609-73-4 邻硝基碘苯

合成工艺路线路线简述

  • 591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Hydrochloric Acid,Sodium Chlorite Solvents: Water; 10 Min; 3 H,Rt
    标题:Preparation Of Selenyl 1,3-Oxazines Via Phicl2/cu2O-Promoted Aminoselenation Of O-Homoallyl Benzimidates With Diselenides
    作者:Zhang,Linlin; Qi,Lin; Chen,Jia-Min; Dong,Wei; Fang,Zhuo-Yue; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2021 卷标:57(94) 页码:12655-12658]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Hydrochloric Acid,Sodium Chlorite Solvents: Water; 10 Min,Rt; 3 H,Rt
    标题:Iodobenzene Dichloride As A Stoichiometric Oxidant For The Conversion Of Alcohols Into Carbonyl Compounds; Two Facile Methods For Its Preparation
    作者:Zhao,Xue-Fei; Zhang,Chi
    参考文献:Synthesis 日期:2007 卷标:(4) 页码:551-557]

    = 932-72-9
    反应条件:1.1 Reagents: Chromium Trioxide,Iodine Solvents: Acetic Acid,Acetic Anhydride1.2 Reagents: Sulfuric Acid1.3 Reagents: Chromium Trioxide,Hydrochloric Acid Solvents: Water
    标题:One-Pot Procedures For Preparing (Dichloroiodo)Arenes From Arenes And Diiodine,With Chromium(Vi) Oxide As The Oxidant
    作者:Obeid,Nicolas; Skulski,Lech
    参考文献:Molecules [online Computer File] 日期:2001 卷标:6(11) 页码:869-874]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Acetic Acid,Sodium Persulfate1.2 Reagents: Hydrochloric Acid1.3 Solvents: Water1.4 Solvents: Carbon Tetrachloride
    标题:Liquid-Phase And Biphasic Chlorination Of Some Iodoarene To Form (Dichloroiodo)Arenes With Sodium Peroxodisulfate As The Oxidant
    作者:Baranowski,Andrzej; Plachta,Dariusz; Skulski,Lech; Klimaszewska,Marzena
    参考文献:Journal Of Chemical Research 日期:2000 卷标:(9) 页码:435-437]

    75-77-4 + 536-80-1 = 932-72-9
    反应条件:1.1 Solvents: Dichloromethane
    标题:General Method For Synthesis Of Aryliodoso Derivatives Under Aprotic Conditions By Reaction Of Iodosobenzene With Substituted Trimethylsilanes
    作者:Zefirov,N. S.; Safronov,S. O.; Kaznacheev,A. A.; Zhdankin,V. V.
    参考文献:Zhurnal Organicheskoi Khimii 日期:1989 卷标:25(8) 页码:1807-8]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Hydrochloric Acid,Hydrogen Peroxide Solvents: Water; 2 H,0 °C
    标题:On The Activation Of Phicl2 With Pyridine
    作者:Poynder,Tiffany B.; Chamorro Orue,Analia I.; Tania; Sharp-Bucknall,Lachlan; Flynn,Matthew T.; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2021 卷标:57(40) 页码:4970-4973]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Potassium Chloride,Potassium Peroxymonosulfate Sulfate (2Khso5.Khso4.K2So4) Solvents: Dichloromethane; 0 °C; 3 H,Rt
    标题:Halocarbocyclization Versus Dihalogenation: Substituent Directed Iodine(Iii) Catalyzed Halogenations
    作者:Stodulski,Maciej; Goetzinger,Alissa; Kohlhepp,Stefanie V.; Gulder,Tanja
    参考文献:Chemical Communications (Cambridge 日期:2014 卷标:50(26) 页码:3435-3438]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Chlorine Solvents: Dichloromethane; 1 H,0 °C; 1 H,Rt
    标题:A Practical Synthetic Method Of Iodoarene Difluorides Without Fluorine Gas And Mercury Salts
    作者:Sawaguchi,Masanori; Ayuba,Shinichi; Hara,Shoji
    参考文献:Synthesis 日期:2002 卷标:(13) 页码:1802-1803]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Chlorine Solvents: Hexane; 3 H,Rt
    标题:Conversion Of Aryl Iodides Into Aryliodine(Iii) Dichlorides By An Oxidative Halogenation Strategy Using 30% Aqueous Hydrogen Peroxide In Fluorinated Alcohol
    作者:Podgorsek,Ajda; Iskra,Jernej
    参考文献:Molecules 日期:2010 卷标:15 页码:2857-2871]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Boric Acid (H3Bo3),Sodium Salt Solvents: Acetic Acid,Acetic Anhydride1.2 Reagents: Hydrochloric Acid1.3 Solvents: Water
    标题:Novel Oxidative,Liquid-Phase Chlorination Procedures For The Preparation Of (Dichloroiodo)Arenes From Iodoarenes
    作者:Obeid,N.; Skulski,L.
    参考文献:Polish Journal Of Chemistry 日期:2000 卷标:74(11) 页码:1609-1615]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Chlorine Solvents: Chloroform; 2 H,Rt
    标题:Synthesis And Reactivity Of Fluorous And Nonfluorous Aryl And Alkyl Iodine(Iii) Dichlorides: New Chlorinating Reagents That Are Easily Recycled Using Biphasic Protocols
    作者:Podgorsek,Ajda; Jurisch,Markus; Stavber,Stojan; Zupan,Marko; Iskra,Jernej; Et Al
    参考文献:Journal Of Organic Chemistry 日期:2009 卷标:74(8) 页码:3133-3140]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Acetic Acid,Chromium Trioxide Solvents: Water1.2 Reagents: Hydrochloric Acid Solvents: Water
    标题:Oxidative Chlorination Of Various Iodoarenes To (Dichloroiodo)Arenes With Chromium(Vi) Oxide As The Oxidant
    作者:Kaimierczak,Pawet; Skulski,Lech; Obeid,Nicolas
    参考文献:Journal Of Chemical Research 日期:1999 卷标:(1) 页码:64-65]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Chlorine Solvents: Chloroform
    标题:Phenyliodine(Iii) Dichloride
    作者:Knight,David W.; Russell,Glen A.
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-4]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Chlorine Solvents: Dichloromethane; -3 - 4 °C
    标题:Large-Scale Preparation Of Iodobenzene Dichloride And Efficient Monochlorination Of 4-Aminoacetophenone
    作者:Zanka,Atsuhiko; Takeuchi,Hiroki; Kubota,Ariyoshi
    参考文献:Organic Process Research & Development 日期:1998 卷标:2(4) 页码:270-273]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Chlorine Solvents: Chloroform
    标题:Iodobenzene Dichloride
    作者:Lucas,H. J.; Kennedy,E. R.
    参考文献:Organic Syntheses 日期:1942 卷标:22 页码:69-70]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Hydrochloric Acid,Sodium Hypochlorite Solvents: Water; 5 Min,Rt; 5 Min,Rt
    标题:Iodobenzene Dichloride In The Esterification And Amidation Of Carboxylic Acids: In-Situ Synthesis Of Ph3Pcl2
    作者:Carle,Myriam S.; Shimokura,Grace K.; Murphy,Graham K.
    参考文献:European Journal Of Organic Chemistry 日期:2016 卷标:2016(23) 页码:3930-3933]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Sodium Hypochlorite; Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; 2 Min,Rt; 5 Min,Rt
    标题:Geminal Dichlorination Of Phenyliodonium Ylides Of β-Dicarbonyl Compounds Through Double Ligand Transfer From (Dichloroiodo)Benzene
    作者:Tao,Jason; Tuck,Tina N.; Murphy,Graham K.
    参考文献:Synthesis 日期:2016 卷标:48(5) 页码:772-782]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Hydrochloric Acid,Sodium Hypochlorite; > 1 Min,Rt; 5 Min,Rt
    标题:Synthesis Of 3,3-Dichloro-2-Oxindoles From Isatin-3-P-Tosylhydrazones And (Dichloroiodo)Benzene
    作者:Hepples,Charlotte; Murphy,Graham K.
    参考文献:Tetrahedron Letters 日期:2015 卷标:56(35) 页码:4971-4974]

    591-50-4 = 932-72-9
    反应条件:1.1 Reagents: Hydrochloric Acid,Sodium Hypochlorite Solvents: Water; > 1 Min,Rt; 5 Min,Rt
    标题:Synthesis Of 3,3-Dichloroindolin-2-Ones From Isatin-3-Hydrazones And (Dichloroiodo)Benzene
    作者:Coffey,Keith E.; Moreira,Ryan; Abbas,Farhana Z.; Murphy,Graham K.
    参考文献:Organic & Biomolecular Chemistry 日期:2015 卷标:13(3) 页码:682-685
📜苯置于chromium(Vi) Oxide,硫酸,碘,盐酸体系中,用 乙酸酐,溶剂黄146 作为反应溶剂,化学反应 2.0H,以95%的收率获得产物(二氯碘)-苯
参考文献:One-Pot Procedures For Preparing (Dichloroiodo)Arenes From Arenes And Diiodine,With Chromium(Vi) Oxide As The Oxidant
标题:One-Pot Procedures For Preparing (Dichloroiodo)Arenes From Arenes And Diiodine,With Chromium(Vi) Oxide As The Oxidant
摘要:十种代表性(双氯碘)芳烃 Aricl2 是从相应的芳烃和二碘在不同的无水混合物中制备而成,反应混合物为 Arh/i2/cro3/醋酸/醋酸酐/浓硫酸,随后加入浓盐酸作为氯的来源;aricl2 在有机合成中作为温和和选择性的氯化剂和/或氧化剂非常有用.
DOI:10.3390/61100869

专利信息


专利号:US-6528642-B1
优先权日:1997-08-29
标题:Mono-and di-derivatives of cyclodextrins, synthesis thereof and purification and use thereof in support
发明人:DUVAL RAPHAEL; LEVEQUE HUBERT
权利人:INST FRANCAIS DU PETROLE; CHIRALSEP SARL
摘要:Mono- and di-derivatives of cyclodextrins are completely defined, also a method for their synthesis and purification, functionalised cyclodextrins obtained from these derivatives, and the synthesis of supports comprising these cyclodextrin derivatives. Use of the supports for the preparation or separation of enantiomers, for asymmetric synthesis, for catalysis, for the preparation or separation of geometrical isomers or positional isomers, or for the preparation or separation of organic molecules with a hydrophobic nature is also described.

专利号:WO-2004087679-A1
优先权日:2003-04-01
标 题 :2, 4, 6-trisubstituted pyrimidine derivatives useful for the treatment of neoplastic and autoimmune diseases
发明人:OBRECHT DANIEL; ERMERT PHILIPP; LUTHER ANATOL; EBERLE MARTIN; BACHMANN FELIX
权利人:APONETICS AG; OBRECHT DANIEL; ERMERT PHILIPP; LUTHER ANATOL; EBERLE MARTIN; BACHMANN FELIX
摘要:The invention relates to substituted pyrimidines of formula (I) wherein V represents a bond or CR6R7, W represents a bond, NR8 or oxygen, X represents sulfur, or nitrogen substituted by hydrogen or R5, Y represents -CH2-, -CH2CH2-, -CO- or -CS-, R1 represents unsubstituted or substituted aryl or heteroaryl, and the substituents R2, R3, R4, R5, R6, R7 and R8 have the meanings given in the specification. These compounds are selectively inducing apoptosis in cancer cells and can be used for the treatment of neoplastic and autoimmune diseases. The invention relates also to methods of synthesis of such compounds, to their use as medicaments, to pharmaceutical compositions containing same, and to methods of treatment of neoplastic and autoimmune diseases using such compounds of formula (I) or of pharmaceutical compositions containing same.

专利号:US-10081610-B2
优先权日:2014-09-12
标题 :Efficient and scalable synthesis of 2-(1′h-indole-3′-carbonyl)-thiazole-4-carboxylic acid methyl ester and its structural analogs
发明人:SONG JIASHENG; ZHANG SUOMING; LI GUODONG; YANG LUQUING
权利人:ARIAGEN INC
摘要:Methods of synthesizing 2-(1′H-indole-3′-carbonyl)-thiazole-4-carboxylic acid methyl ester (ITE) and structural analogs thereof. The methods include condensation reactions or condensation and oxidation reactions to form the thiazoline or thiazole moiety of ITE or its structural analogs.

专利号:US-10385010-B1
优先权日:2018-03-28
标 题 :Expedient synthesis of oseltamivir and related compounds via direct olefin diazidation-diamidation reaction
发明人:XU HAO; LI HONGZE; SHEN SHOUJIE; ZHU CHENGLIANG
权利人:UNIV GEORGIA STATE RES FOUND
摘要:Disclosed herein are improved methods for the preparation of oseltamivir, and intermediates useful thereto.

专利号:US-4341706-A
优先权日:1980-10-10
标题 :Process for the preparation of carbapenem antibiotics
发明人:CHRISTENSEN BURTON G; SHIH DAVID H
权利人:MERCK & CO INC
摘要:Disclosed is a process for the synthesis of carbapenem antibiotics I and their pharmaceutically acceptable salts and esters from 1: wherein: R7, R6, R1, R2 and R8 are selected from hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, spirocycloalkyl, cycloalkylalkyl, alkylcycloalkyl, aryl, aralkyl, aralkenyl, aralkynyl, heteroalkyl, heteroaralkyl, heterocyclyl and heterocyclyalkyl.

专利号:US-4087465-A
优先权日:1976-02-25
标题:Process for the preparation of halogeno-acetals from enoxysilanes
发明人:DECOR JEAN-PIERRE
权利人:RHONE POULENC IND
摘要:Halogeno-acetals of ethylenic aldehydes are made by reaction of a corresponding enoxysilane compound with a halogen cation and an alcohol. The products are useful inter alia in the synthesis of retinal and other unsaturated aldehydes.

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合成参考文献


摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 62.
摘要:Chen, P.; Liu, G.; Engle, K. M.; Yu, J.-Q., Science of Synthesis Knowledge Updates, (2013) 2, 97.
摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 77.
摘要:Powers, D. C.; Ritter, T., Science of Synthesis Knowledge Updates, (2012) 4, 9.
摘要:Powers, D. C.; Ritter, T., Science of Synthesis Knowledge Updates, (2012) 4, 12.
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