CAS: 5332-52-5; 1-Undecanethiol

该化合物是一个直链脂色硫醇,其特点是由11个碳原子组成的长期碳氢链.其分子分子式为C11H24S,表明有硫醇功能组(-SH)附于烷链终端碳.该化合物一般是一种无色至黄色的黄色液体,具有一种独特的大蒜或洋葱味的气味,在硫醇中很常见.1-Undecanethiol在有机溶剂中溶解,并且由于其含水的碳氢化合物尾巴在水中表现出溶性有限.它在有机合成中的应用,特别是在金属表面准备自组装的单层,以及作为各种化学反应中的试剂.此外,该硫醇组允许形成分解的混合物,使其在生物化学和材料中都很常见.在处理该化合物时,应当采取安全防范措施,因为其眼睛可以刺激皮肤和材料.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号2432-35-1 Thioacetic acid... | CAS号693-67-4 1-溴癸烷 | CAS号7289-44-3 1-methylsulfany... | CAS号79458-27-8 Disulfide, diundecyl | CAS号45164-10-1 undecane-1-sulf...

合成工艺路线路线简述

    📜1-溴十一烷置于甲醇,Sodium Disulfide体系中,化学反应生成 1-十一硫醇
    参考文献:Noller; Gordon,Journal Of The American Chemical Society,1933,Vol. 55,P. 1091
    标题:Noller; Gordon,Journal Of The American Chemical Society,1933,Vol. 55,P. 1091

    海关参考信息

    专利信息


    专利号:US-9790425-B2
    优先权日:2014-04-18
    标 题:Synthesis of quantum dots
    发明人:MCDANIEL HUNTER
    权利人:LOS ALAMOS NAT SECURITY LLC
    摘要:Common approaches to synthesizing alloyed quantum dots employ high-cost, air-sensitive phosphine complexes as the selenium precursor. Disclosed quantum dot synthesis embodiments avoid these hazardous and air-sensitive selenium precursors. Certain embodiments utilize a combination comprising a thiol and an amine that together reduce and complex the elemental selenium to form a highly reactive selenium precursor at room temperature. The same combination of thiol and amine acts as the reaction solvent, stabilizing ligand, and sulfur source in the synthesis of quantum dot cores. A non-injection approach may also be used. The optical properties of the quantum dots synthesized by this new approach can be finely tuned for a variety of applications by controlling size and/or composition of size and composition. Further, using the same approach, a shell can be grown around a quantum dot core that improves stability, luminescence efficiency, and may reduce toxicity.

    专利号:US-10730904-B2
    优先权日:2012-11-14
    标 题:Method for liquid-phase synthesis of nucleic acid
    发明人:NONOGAWA MITSURU; NAGATA TOSHIAKI; SAITO HIDEKI; YASUMA TSUNEO
    权利人:TAKEDA PHARMACEUTICALS CO
    摘要:In this method, an oligonucleotide represented by formula (II) [wherein Y 1 , Q, Base, r and r′ are each as defined in claim 1 ] is prepared by using, as a synthesis unit, a novel nucleoside monomer compound represented by formula (I) [wherein X, R 1 , Y, Base, Z, Ar, R 2 , R 3 and n are each as defined in claim 1 ]. The novel nucleoside monomer compound is a nucleoside, the base moiety of which is substituted with an aromatic-hydrocarbon-ring-carbonyl or -thiocarbonyl group having at least one hydrophobic group. The method can dispense with column-chromatographic purification in every reaction, and enables base elongation not only in the 3′-direction but also in the 5′-direction, thus attaining efficient liquid-phase mass synthesis of an oligonucleotide.

    专利号:US-2006286379-A1
    优先权日:2002-08-13
    标题 :Magnetic nanoparticle supports
    发明人:GAO YONG
    权利人:GAO YONG
    摘要:Coated magnetic nanoparticles and their compositions used for labeling, detecting, sorting, and isolating biological, organic and inorganic molecules, and for medical therapies, and as a platform for organic, biological and physical transformations. An oxidation approach for fabricating iron oxide nanoparticles, methods for the synthesis of magnetic compositions comprising a magnetic core associated with a functional molecule or molecular complexes, and methods for the synthesis of water-soluble magnetic particles/compositions.

    专利号:WO-2023113033-A1
    优先权日:2021-12-16
    标题 :Gas diffusion electrode
    发明人:KONDO SHOICHI; MAEDA SHINICHI; SHIGA NORIHITO
    权利人:NISSAN CHEMICAL CORP
    摘要:[Problem] The present invention addresses the problem of increasing the rate of reaction by controlling ammonium ions, which are generated by ammonia as the objective of the electrolytic synthesis of ammonia and protons that are supplied to the cathode, by means of the cathode and the cathode catalyst layer. [Solution] The present invention provides a gas diffusion electrode which is integrated with a catalyst layer that uses a material selected from the group consisting of cathode catalyst layer materials. Examples of the cathode catalyst layer materials include a fired body and an ionic liquid.

    专利号:EP-0713488-B1
    优先权日:1993-08-10
    标题 :[1,3,4]triazolo [1,5-al]pyridines used as intermediate products for the synthesis of dyes

    专利号:US-8951400-B2
    优先权日:2007-10-17
    标题:Chemistry used in biosensors
    发明人:AHRENS MICHAEL; BERTIN PAUL A; GRAY HARRY B; MEADE THOMAS J
    权利人:AHRENS MICHAEL; BERTIN PAUL A; GRAY HARRY B; MEADE THOMAS J; OHMX CORP
    摘要:The invention relates to novel compositions of disubstituted bipyridyl osmium complexes useful for the synthesis of labeled proteins, nucleic acids, and for the modification of electrodes.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Drabowicz, J.; Krasowska, D.; Wicha, J., Science of Synthesis, (2009) 48, 249.
    摘要:Zimmer, R.; Trawny, D., Science of Synthesis Knowledge Updates, (2013) 4, 204.
    摘要:Witt, D., Science of Synthesis Knowledge Updates, (2011) 3, 275.
    摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 1985. Acute oral toxicity and repellency of 933 chemicals to house and deer mice. Archives of Environmental Contamination and Toxicology 14:111-129.
    参考文献:10.2116/analsci.22.521
    摘要:Kado S, Murakami T, Kimura K. Effect of intramonolayer hydrogen bonding of carboxyl groups in self-assembled monolayers on a single force with phenylurea on an AFM probe tip. Anal Sci. 2006 Apr;22(4):521–7. doi: 10.2116/analsci.22.521.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知