1-壬醇置于cyp153A16体系中,化学反应 4.0H,反应生成1,9-壬二醇 参考文献:Regioselective ω-Hydroxylation Of Medium-Chain N-Alkanes And Primary Alcohols By Cyp153 Enzymes From Mycobacterium Marinum And Polaromonas Sp. Strain Js666 标题:Regioselective ω-Hydroxylation Of Medium-Chain N-Alkanes And Primary Alcohols By Cyp153 Enzymes From Mycobacterium Marinum And Polaromonas Sp. Strain Js666 摘要:饱和烃的氧官能化是基础和应用化学中的一个重要目标.生物催化剂如细胞色素p450酶可以以非常选择性的方式将氧引入多种分子中,这可以用于精细化学品和大宗化学品的合成.来自cyp153A亚家族的细胞色素p450酶被描述为具有高末端区域选择性的烷烃羟化酶.在这里,我们报告了由来自海洋分枝杆菌(cyp153A16)和极地单胞菌(cyp153A P. Sp.)的cyp153A酶催化的c5-c12烷烃和醇氧化反应的产物产率.对于所有反应,副产物的形成进行了详细描述.经过在大肠杆菌中克隆和表达后,纯化的单氧化酶的活性与变色龙还原蛋白(cama)和变色龙还原酶(camb)重新结合.尽管这两种酶系统都产生初级醇和α,ω-烷二醇,但它们对烷烃的氧化模式却有所不同.对于cyp153A P. Sp.,观测到主要的ω-羟化活性,而cyp153A16则具备催化ω-羟化和α,ω-二羟化反应的能力. Doi:10.1039/c1Ob05565H
专利号:WO-2023102600-A1 优先权日:2021-12-06 标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom 发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI 权利人:NEWSOUTH INNOVATIONS PTY LTD 摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.
专利号:US-8053522-B2 优先权日:2006-02-28 标题 :Synthesis of polyester-graft-poly(meth)acrylate copolymers 发明人:LOEHDEN GERD; BALK SVEN; BRAND THORSTEN; BRENNER GABRIELE; ARNOLD THOMAS; BAUMANN CORNELIA 权利人:EVONIK ROEHM GMBH 摘要:The present invention relates to a novel synthesis of (meth)acrylate-grafted polyesters and their action as compatibilizers.
专利号:US-10730994-B2 优先权日:2015-06-08 标 题:Synthesis of polycarbonate siloxane diols 发明人:MAGUIRE FRANCIS P; VENKATARAMANI SRIRAM 权利人:AORTECH INT PLC; MAGUIRE FRANCIS P; VENKATARAMANI SRIRAM 摘要:The present invention provides silicon-based polycarbonates, processes for their preparation and their use in the synthesis of copolymers, in particular segmented copolymers such as polyurethanes for biomedical applications.
专利号:US-9611352-B2 优先权日:2014-09-17 标 题:Synthesis and molecular weight control of aliphatic polyester diols 发明人:NARINE SURESH; LI SHAOJUN; JOSE JESMY; SHETRANJIWALLA SHEGUFTA; BOUZIDI LAZIZ 权利人:UNIV TRENT 摘要:The synthesis of certain polyester diols (PEDs) is disclosed. This application also discloses the purification and polymerization kinetics of lipid based PEDs. Molecular weight and distribution controls were achieved by initial and induced stoichiometric imbalance and optimization of the purification protocol. Thermal degradation and thermal transition behavior of the PEDs were also investigated by TGA and DSC.
专利号:US-2009318592-A1 优先权日:2005-10-11 标 题 :Process for the Synthesis of Amine Ethers 发明人:FREY MARKUS; BROENNIMANN VALERIE 权利人:CIBA GEIGY CORP 摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.
专利号:US-2007191516-A1 优先权日:2004-03-15 标题 :Process for the synthesis of amine ethers 发明人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS 权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS 摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.
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合成参考文献
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