CAS: 323-09-1; 2-Fluoronaphthalene

相似化合物

321-38-0 324-41-4 59079-69-5

上下游产品

CAS号3857-83-8 三氟甲烷磺酸2-萘酯 | CAS号90-13-1 1-氯代萘 | CAS号575-08-6 6-氟萘-1-羧酸 | CAS号91-20-3 萘 | CAS号75-43-4 二氯氟甲烷 | CAS号95-13-6 茚 | CAS号612-55-5 2-碘萘 | CAS号580-13-2 2-溴萘 | CAS号18052-85-2 2-(TRIMETHYLSIL... | CAS号1523-11-1 乙酸-2-萘酯 | CAS号93-44-7 苯甲酸-2-萘酯 | CAS号325-09-7 6-氟萘-2-磺酰氯 | CAS号108981-94-8 2-phenylnaphtha... | CAS号2178-02-1 3-phenyl-2-naph... | CAS号85679-03-4 1-phenylnaphtha... | CAS号117-17-9 2-Ethoxy-1-nitr... | CAS号82128-49-2 2-Fluoro-1-naph... | CAS号21597-61-5 3-氟-2-萘甲醛 | CAS号703-47-9 2-fluoro-1-meth...

📜2-碘萘置于copper (II)-Fluoride,四甲基乙二胺体系中,用 Hmpa (Hexamethylphosphoramide) 用作溶剂,化学反应 3.0H,反应生成2-氟萘
参考文献:Processes For Preparing Fluoroarenes From Haloarenes
标题:Processes For Preparing Fluoroarenes From Haloarenes
摘要:提供了制备氟芳烃的过程.这些过程包括将具有未活化芳基的化合物与氟化物或双氟化物的来源在过渡金属和配体存在下接触.

专利信息

专利号:US-2010016607-A1
优先权日:2006-12-11
标题:Process for the Synthesis of Highly Active Binary Metal Fluoride as a Fluorinating Agent for Aromatics
发明人：DOLBIER JR WILLIAM R; JANMANCHI KRISHNA MURTHY
权利人:UNIV FLORIDA
摘要:The subject invention relates to a process for the synthesis of highly active binary metal fluoride system for the fluorination of aromatic compounds. Fluorinated aromatic compounds are valuable synthons for the chemical synthesis of pharmaceutical drugs and novel polymers. Fluorobenzene is used to control carbon content in steel manufacturing, is an intermediate for pharmaceuticals, pesticides and other organic compounds. Fluorobenzene is typically produced by the reaction of aniline and sodium nitrite in the presence of hydrogen fluoride. The present invention relates to a process for the synthesis of highly active binary metal fluoride system consists of copper (II) fluoride and aluminum (III) fluoride for the fluorination of aromatic compounds in gas phase and recycling of the reagent, in situ, using O 2 and HF.

专利号:US-4031106-A
优先权日:1973-12-19
标题:Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
发明人：DELPESCO THOMAS WAYNE
权利人:DU PONT
摘要:An improved process is provided for producing an aromatic amine from ammonia and an aromatic compound which comprises reacting the aromatic compound with ammonia at a temperature of from about 150 DEG C. to about 500 DEG C. and at a pressure of from about 10 to about 1000 atmospheres in the presence of a conditioned nickel/nickel oxide/zirconium oxide cataloreactant containing an oxide of lanthanum, samarium, holmium, europium, erbium, yttrium, praseodymium, neodymium, terbium, ytterbium, dysprosium or a mixture of any of them.

专利号:US-3929889-A
优先权日:1971-02-16
标 题 :Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
发明人：SQUIRE EDWARD NOONAN
权利人:DU PONT
摘要:An improved process for producing an aromatic amine is provided in which an aromatic compound is reacted with ammonia in the presence of a conditioned nickel/nickel oxide cataloreactant at a temperature of from about 150*C. to about 500*C. and at a pressure of from about 10 to about 1000 atmospheres.

专利号:US-4001260-A
优先权日:1973-12-19
标 题:Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
发明人：DEL PESCO THOMAS W
权利人:DU PONT
摘要:An improved process is provided for producing an aromatic amine from ammonia and an aromatic compound which comprises reacting the aromatic compound with ammonia at a temperature of from about 150° C. to about 500° C. and at a pressure of from about 10 to about 1000 atmospheres in the presence of a conditioned nickel/nickel oxide/zirconium oxide cataloreactant which has been treated with ammonia prior to introduction of the cataloreactant to the amination reactants.

专利号:US-9895454-B2
优先权日:2014-07-03
标题:Metal oxide catalyzed radiofluorination
发明人：SERGEEV MAXIM; MORGIA FEDERICA; VAN DAM ROBERT MICHAEL; LAZARI MARK
权利人:UNIV CALIFORNIA
摘要:Inter alia, the first titania-catalyzed [ 18 F]-radiofluorination in highly aqueous medium is provided. In embodiments, the method utilizes titanium dioxide, 1:1 acetonitrile-thexyl alcohol solvent mixture and tetrabutylammonium bicarbonate as a base. Radiolabeling may be directly performed with aqueous [ 18 F]fluoride without the need for drying/azeotroping step, which reduces radiosynthesis time while keeping high fluoride conversion. The general applicability of the synthetic strategy to the synthesis of the wide range of PET probes from tosylated precursors is demonstrated.

专利号:US-5491167-A
优先权日:1993-01-29
标题 :Hexahydronaphthalene ester derivatives, their preparation and their therapeutic uses
发明人：ISHIHARA SADAO; KOGEN HIROSHI; KOGA TEIICHIRO; KITAZAWA EIICHI; SERIZAWA NOBUFUSA
权利人:SANKYO CO
摘要:Compounds of formula (I): ##STR1## and their salts and esters have the ability to inhibit the synthesis of cholesterol, and can thus be used for the treatment and prophylaxis of hypercholesterolemia and of various cardiac disorders.