CAS: 16836-95-6; Silver P-Toluenesulfonate

该化合物是有机硅化合物,其特点是存在银化(Ag+)和电相阴离子(TsO),一般是白色的白色和白外固体,在极地有机溶剂中以其溶解性著称,该化合物经常用于有机合成,特别是用于涉及核生殖替代的反应,因为其具有同化细胞的优良分泌特性.银相片可以作为各种化学反应中银离子的来源,包括需要银催化的化学反应.它也因其抗微生物特性而引人注目,因此对医药化学具有兴趣.然而,与许多银化合物一样,在处理时,应注意潜在的毒性和环境关切.建议采取适当的安全措施,包括使用个人防护设备,在与该物质打交道时,包括使用个人防护设备.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

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    专利号:US-9938297-B2
    优先权日:2014-08-04
    标 题:Process for the synthesis of everolimus and intermediates thereof
    发明人:RAO DHARMARAJ RAMACHANDRA; MALHOTRA GEENA; PULLELA VENKATA SRINIVAS; ACHARYA VINOD PARAMESHWARAN
    权利人:CIPLA LTD; CIPIA LTD
    摘要:The present invention relates to a novel process for the synthesis of everolimus of formula (I): n nand intermediates thereof.

    专利号:US-5286901-A
    优先权日:1990-03-09
    标题:Prescursors for and synthesis of mono- and difunctionalized acetylenes and difunctional 1,3-diynes
    发明人:STANG PETER J; CRITTELL CHARLES M; WILLIAMSON BOBBY L; ZHDANKIN VIKTOR
    权利人:UNIV UTAH RES FOUND
    摘要:Precursors and methods for the synthesis of mono- and difunctionalized acetylenes are described. The invention includes novel tricoordinate iodonium transfer reagents and novel alkynyldi(phenyliodonium) salts, both of which are precursors for the functionalized acetylenes. The iodonium transfer reagents take the general form of mixed iodonium sulfonates PhI + (X)OSO 2 R f , where X may be OAc, NHAc, NCO, or CN. These mixed iodonium sulfonates are produced by reaction of iodosobenzene with certain substituted trimethylsilanes. n To make the alkynyldi(phenyliodonium) salt PhI + C.tbd.CI + Ph•2 R f SO 3 - ,a mixed iodonium sulfonate is reacted with a bistin acetylene of the kind R' 3 SnC.tbd.CSnR' 3 . Alternatively, the reaction may be performed with disubstituted tin diacetylenes to produce PhI + C.tbd.C-C.tbd.CI + Ph•2 R f SO 3 - to produce a dialkynyldi(phenyliodonium) salt. Subsequent reaction of a nucleophile with the alkynyldi(phenyl-iodonium) salt or dialkynyldi(phenyliodonium) salt produces a difunctional acetylene or a difunctional 1,3-diyne, respectively.

    专利号:US-10421873-B2
    优先权日:2015-05-25
    标 题 :Method for in-site synthesis of transparent conductive coating of poly(3,4-ethylenedioxythiophene)/nano silver
    发明人:LI JIANXIONG; MA YAXIAO; LIU ANHUA
    权利人:UNIV SOUTH CHINA TECH
    摘要:A method for in-site synthesis of transparent conductive coating of poly(3,4-ethylenedioxythiophene)/nano silver hybrid on transparent substrate is provided. Transparent substrate with oxidant coating containing silver salt is immersed into 3,4-ethylenedioxythiophene (EDOT) solution. The oxidant turns EDOT monomer to poly(3,4-ethylenedioxythiophene) (PEDOT) coating on the transparent substrate; meanwhile, the silver salt itself is reduced to nano silver by the EDOT monomer, resulting in a nano silver-doped PEDOT coating. Thereby, a transparent conductive film made of PEDOT/nano silver coating on transparent substrate is obtained. The transparent conductive film with PEDOT/nano silver coating prepared in the present invention possesses the advantages of high electrical conductivity, optical transparency and environmental stability.

    专利号:US-2016317682-A1
    优先权日:2015-04-30
    标题:PREPARATION OF Ag18F AND ITS USE IN THE SYNTHESIS OF PET RADIOTRACERS
    发明人:SCOTT PETER J H; BROOKS ALLEN F; ICHIISHI NAOKO; SANFORD MELANIE S
    权利人:UNIV MICHIGAN REGENTS; THE REGENTS OFTHE UNIV OF MICHIGAN
    摘要:Copper-catalyzed radiofluorination of aryl iodides using Ag 18 F, methods of preparing Ag 18 F, and compounds obtained by copper-catalyzed radiofluorination of aryl iodides using Ag 18 F are disclosed. Diagnostic and therapeutic methods involving such compounds also are disclosed.

    专利号:US-9822053-B2
    优先权日:2016-01-28
    标题:Single step conversion of N-butyraldehyde to 2-ethylhexanal
    发明人:BOPPANA Venkata Bharat; HAMPTON JR KENNETH WAYNE; LIU ZHUFANG; SUMNER JR CHARLES EDWAN; TUSTIN GERALD C; STEINMETZ GUY RALPH; STEFFEY MELISSA PAGE
    权利人:EASTMAN CHEM CO
    摘要:Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.

    专利号:US-2012301720-A1
    优先权日:2009-11-16
    标题 :Metal island coatings and method for synthesis
    发明人:KOBAN WIELAND; PEUKERT WOLFGANG; KLUPP TAYLOR ROBIN; DISTASO MONICA; BAO HUIXIN; VASYLYEV SERHIY
    权利人:KOBAN WIELAND; PEUKERT WOLFGANG; KLUPP TAYLOR ROBIN; DISTASO MONICA; BAO HUIXIN; VASYLYEV SERHIY; BASF SE
    摘要:The present invention relates to methods for synthesis of metallic island coatings with tunable island coverage and morphology on a variety of substrates. Particularly, the present invention relates to substrates coated with one or more metal islands and the use of said island-coated substrates.
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    合成参考文献


    摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 77.
    摘要:Weibel, J.-M.; Blanc, A.; Pale, P., Science of Synthesis Knowledge Updates, (2018) 1, 21.
    摘要:Campbell, M. J.; Toste, F. D., Science of Synthesis Knowledge Updates, (2012) 1, 135.
    摘要:Weibel, J.-M.; Blanc, A.; Pale, P., Science of Synthesis Knowledge Updates, (2018) 1, 26.
    摘要:Campbell, M. J.; Toste, F. D., Science of Synthesis Knowledge Updates, (2012) 1, 152.
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