CAS: 108-82-7; 2,6-Dimethylheptan-4-Ol

该化合物是含有分子式C9H20O的分链脂醇,通常用作有机合成的中间体和工业应用中的溶剂,化合物的受严重阻碍结构有助于其稳定性和低挥发性,使其适合高温过程,其疏水特性和中度极性允许有效用于需要受控溶解的配方.此外,2,6-二甲基-4-七酚与树脂,涂料和催塑剂的兼容性良好,提高了特殊化学应用的性能.产品保持纯度和定义明确的物理特性,确保实验室和工业环境中的可靠性能.

结构式图片

相似化合物

14898-80-7 16404-54-9 51079-52-8

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

phorone diisobutyl ketone isobutylmagnesium bromide isovaleraldehydephenyl-acetic acid-(1-isobutyl-3-methyl-butyl ester) (+/-)-2-methyl-3-(p-methoxyphenyl)propanol 2,6-dimethyl-hept-3-ene 2,6-dimethyl-2-heptene Alcohols ( acetic acid (+)-β-citronellene Dihydromyrcenol acetyl chloride

合成工艺路线路线简述

  • 合成目标产物 Diisobutylcarbinol 主要起始原料 2,6-Dimethyl-4-Heptanone
  • (文献来源)合成步骤主要原料 2,6-Dimethyl-4-Heptanone
二异丁基酮置于氢气体系中,150.0 °C,1.3 Mpa 条件下,以95%的收率获得二异丁基甲醇
参考文献:丙酮衍生的c6,C9和c12碳支架的合成,用于化学和燃料应用
标题:丙酮衍生的c6,C9和c12碳支架的合成,用于化学和燃料应用
摘要:描述了一种简单,廉价的催化剂体系(amberlyst 15和ni / Sio 2-Al 2 O 3),用于将丙酮升级为一系列化学药品和潜在燃料.产生的酮的逐步加氢脱氧可产生支链的醇,烯烃和烷烃.提供了对这些产品的分析,表明该方法可以提供有价值的生物产品和潜在生物燃料的产品概况.
Doi:10.1002/cssc.201600936

专利信息


专利号:WO-2014059961-A1
优先权日:2012-10-15
标 题 :Method for the synchronous absorption of carbon dioxide from flue gas and synthesis of dialkyl carbonates and alkylene carbonates
发明人:BÜTTNER HERMANN; Müller Jürgen; JONKER RAPHAEL; DOEDT SEBASTIAN; BOSSE TOBIAS; MAKRAN SEBASTIAN
权利人:BÜTTNER HERMANN
摘要:The invention relates to a synchronous CCU method (carbon dioxide capture and utilisation) for the absorption of carbon dioxide from flue gas and other CO 2 -containing substance sources and simultaneous synthesis of dialkyl carbonates and alkylene carbonates. The general subject matter of the invention is, in terms of a 'carbon dioxide capture' on the one hand, the absorption of CO 2 from flue gas and other CO 2 -containing substance sources with ammonia and/or amines to form ammonium carbamates or ammonium hydrogen carbonates or ureas or urea intermediates and, in terms of a 'carbon dioxide utilisation' on the other hand, the reaction of ammonium carbamates or ammonium hydrogen carbonates or ureas or urea intermediates with aliphatic, alicyclic or unsaturated alcohols, and including unsaturated aromatic alcohols to give dialkyl carbonates or alkylene carbonates in such a form that the CO 2 n absorption agent is re-released and fed back into the repetitive process again. A repetitive process control is extremely energy and CO 2 n efficient.

专利号:US-2014245658-A1
优先权日:2013-02-08
标 题 :Synthesis of ethanol and higher alcohols by hydrogenation of ketene
发明人:HENRI JOHN T; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT
权利人:PIONEER ENERGY INC
摘要:Ketene chemistry and hydrogenation reactions are used to synthesize fuels and chemicals. Ketene from acetic acid is hydrogenated to form fuels and chemicals; acetic acid can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc. In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass.

专利号:US-9296665-B2
优先权日:2012-12-13
标题:Synthesis of drop-in liquid fuels and chemicals from methanol, ethanol or syngas using mixed catalysts
发明人:KORTAN ADAM M; KELLY MICHAEL T; ROSE HEATHER A; ZUBRIN ROBERT M
权利人:Pioneer Energy; PIONEER ENERGY INC
摘要:The present invention discloses a system for converting methanol or synthesis gas to liquid hydrocarbons with comparable energy content to gasoline within a mixed bed single reactor or double reactor systems. Varying catalyst composition and temperature profiles allow for significant tailoring of reaction conditions to the specific feedstocks or the desired products.

专利号:US-9080119-B2
优先权日:2011-11-10
标 题:Synthesis of high caloric fuels and chemicals including pentanol from coal, natural gas, and biomass
发明人:HENRI JOHN; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT
权利人:PIONEER ENERGY INC; Pioneer Energy
摘要:In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.

专利号:US-9611186-B2
优先权日:2011-11-10
标 题 :Synthesis of high caloric fuels and chemicals via ketene and diketene intermediates
发明人:HENRI JOHN; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT
权利人:PIONEER ENERGY INC; Pioneer Energy
摘要:In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.

专利号:WO-9526975-A1
优先权日:1994-03-30
标题 :Acyclic aliphatic branched alkyl groups as constituents of protective groups bound to side chains of amino-acid moieties, and their use in the preparation of peptide, polypeptide or protein structures
发明人:UNDEN ANDERS
权利人:UNDEN ANDERS
摘要:A protective group bound to a side chain of an amino-acid moiety, which group is an aliphatic acyclic branched alkyl group protecting a thiol, hydroxyl, or carboxyl group or an aliphatic acyclic branched alkoxycarbonyl group protecting an amino group or heterocyclic nitrogen, wherein the alkyl and alkoxy entities have from 6 to 18 carbon atoms and have at least two identical alkyl chains, is described. Further, the use of such a protective group bound to a side chain of an amino-acid moiety in the synthesis of peptides, polypeptides and proteins is disclosed.
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✅ COA系统入驻 | 共享模式

主要参考文献


1: Zhang F, Bartels MJ, Clark AJ, Staley JL, Lardie TS, Markham DA, Hughes BJ, Ball NS. Comparative metabolism and pharmacokinetics of diisobutyl ketone and diisobutyl carbinol in male SD rats. Toxicol Lett. 2015 Jan 5;232(1):175-81. doi: 10.1016/j.toxlet.2014.10.027. Epub 2014 Nov 6. doi: 10.1016/j.jcis.2012.07.028. Epub 2012 Jul 20. doi: 10.1021/ic300856h. Epub 2012 Jun 11. doi: 10.1016/j.fct.2010.05.037. Review.

合成参考文献


摘要:Treacy, S. M.; Zhang, X.; Rovis, T., Science of Synthesis, (2021) , 627.
摘要:Journal of Industrial Hygiene and Toxicology., 31(60), 1949
摘要:Weast, R.C. and M.J. Astle. CRC Handbook of Data on Organic Compounds. Volumes I and II. Boca Raton, FL: CRC Press Inc. 1985., p. V1 692
参考文献:10.1016/j.fct.2019.110603
摘要:Api AM, Belsito D, Botelho D, Bruze M, Burton GA, Buschmann J, Dagli ML, Date M, Dekant W, Deodhar C, Francis M, Fryer AD, Jones L, Joshi K, La Cava S, Lapczynski A, Liebler DC, O'Brien D, Patel A, Penning TM, Ritacco G, Romine J, Sadekar N, Salvito D, Schultz TW, Sipes IG, Sullivan G, Thakkar Y, Tokura Y, Tsang S. RIFM fragrance ingredient safety assessment, 4-heptanol, 2,6-dimethyl-,acetate, CAS Registry Number 10250-45-0. Food Chem Toxicol. 2019 Dec;134 Suppl 1():110603. doi: 10.1016/j.fct.2019.110603.
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