专利号:WO-2014059961-A1 优先权日:2012-10-15 标 题 :Method for the synchronous absorption of carbon dioxide from flue gas and synthesis of dialkyl carbonates and alkylene carbonates 发明人:BÜTTNER HERMANN; Müller Jürgen; JONKER RAPHAEL; DOEDT SEBASTIAN; BOSSE TOBIAS; MAKRAN SEBASTIAN 权利人:BÜTTNER HERMANN 摘要:The invention relates to a synchronous CCU method (carbon dioxide capture and utilisation) for the absorption of carbon dioxide from flue gas and other CO 2 -containing substance sources and simultaneous synthesis of dialkyl carbonates and alkylene carbonates. The general subject matter of the invention is, in terms of a 'carbon dioxide capture' on the one hand, the absorption of CO 2 from flue gas and other CO 2 -containing substance sources with ammonia and/or amines to form ammonium carbamates or ammonium hydrogen carbonates or ureas or urea intermediates and, in terms of a 'carbon dioxide utilisation' on the other hand, the reaction of ammonium carbamates or ammonium hydrogen carbonates or ureas or urea intermediates with aliphatic, alicyclic or unsaturated alcohols, and including unsaturated aromatic alcohols to give dialkyl carbonates or alkylene carbonates in such a form that the CO 2 n absorption agent is re-released and fed back into the repetitive process again. A repetitive process control is extremely energy and CO 2 n efficient.
专利号:US-2014245658-A1 优先权日:2013-02-08 标 题 :Synthesis of ethanol and higher alcohols by hydrogenation of ketene 发明人:HENRI JOHN T; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT 权利人:PIONEER ENERGY INC 摘要:Ketene chemistry and hydrogenation reactions are used to synthesize fuels and chemicals. Ketene from acetic acid is hydrogenated to form fuels and chemicals; acetic acid can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc. In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass.
专利号:US-9296665-B2 优先权日:2012-12-13 标题:Synthesis of drop-in liquid fuels and chemicals from methanol, ethanol or syngas using mixed catalysts 发明人:KORTAN ADAM M; KELLY MICHAEL T; ROSE HEATHER A; ZUBRIN ROBERT M 权利人:Pioneer Energy; PIONEER ENERGY INC 摘要:The present invention discloses a system for converting methanol or synthesis gas to liquid hydrocarbons with comparable energy content to gasoline within a mixed bed single reactor or double reactor systems. Varying catalyst composition and temperature profiles allow for significant tailoring of reaction conditions to the specific feedstocks or the desired products.
专利号:US-9080119-B2 优先权日:2011-11-10 标 题:Synthesis of high caloric fuels and chemicals including pentanol from coal, natural gas, and biomass 发明人:HENRI JOHN; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT 权利人:PIONEER ENERGY INC; Pioneer Energy 摘要:In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.
专利号:US-9611186-B2 优先权日:2011-11-10 标 题 :Synthesis of high caloric fuels and chemicals via ketene and diketene intermediates 发明人:HENRI JOHN; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT 权利人:PIONEER ENERGY INC; Pioneer Energy 摘要:In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.
专利号:WO-9526975-A1 优先权日:1994-03-30 标题 :Acyclic aliphatic branched alkyl groups as constituents of protective groups bound to side chains of amino-acid moieties, and their use in the preparation of peptide, polypeptide or protein structures 发明人:UNDEN ANDERS 权利人:UNDEN ANDERS 摘要:A protective group bound to a side chain of an amino-acid moiety, which group is an aliphatic acyclic branched alkyl group protecting a thiol, hydroxyl, or carboxyl group or an aliphatic acyclic branched alkoxycarbonyl group protecting an amino group or heterocyclic nitrogen, wherein the alkyl and alkoxy entities have from 6 to 18 carbon atoms and have at least two identical alkyl chains, is described. Further, the use of such a protective group bound to a side chain of an amino-acid moiety in the synthesis of peptides, polypeptides and proteins is disclosed.
1: Zhang F, Bartels MJ, Clark AJ, Staley JL, Lardie TS, Markham DA, Hughes BJ, Ball NS. Comparative metabolism and pharmacokinetics of diisobutyl ketone and diisobutyl carbinol in male SD rats. Toxicol Lett. 2015 Jan 5;232(1):175-81. doi: 10.1016/j.toxlet.2014.10.027. Epub 2014 Nov 6. doi: 10.1016/j.jcis.2012.07.028. Epub 2012 Jul 20. doi: 10.1021/ic300856h. Epub 2012 Jun 11. doi: 10.1016/j.fct.2010.05.037. Review.
合成参考文献
摘要:Treacy, S. M.; Zhang, X.; Rovis, T., Science of Synthesis, (2021) , 627. 摘要:Journal of Industrial Hygiene and Toxicology., 31(60), 1949 摘要:Weast, R.C. and M.J. Astle. CRC Handbook of Data on Organic Compounds. Volumes I and II. Boca Raton, FL: CRC Press Inc. 1985., p. V1 692 参考文献:10.1016/j.fct.2019.110603 摘要:Api AM, Belsito D, Botelho D, Bruze M, Burton GA, Buschmann J, Dagli ML, Date M, Dekant W, Deodhar C, Francis M, Fryer AD, Jones L, Joshi K, La Cava S, Lapczynski A, Liebler DC, O'Brien D, Patel A, Penning TM, Ritacco G, Romine J, Sadekar N, Salvito D, Schultz TW, Sipes IG, Sullivan G, Thakkar Y, Tokura Y, Tsang S. RIFM fragrance ingredient safety assessment, 4-heptanol, 2,6-dimethyl-,acetate, CAS Registry Number 10250-45-0. Food Chem Toxicol. 2019 Dec;134 Suppl 1():110603. doi: 10.1016/j.fct.2019.110603.