CAS: 96422-53-6; Goniodiol 7-Monoacetate
该化合物是一个复杂的有机化合物,其特征是其特定的立体化学和功能组.该化学物质具有一个有六人组成的圆锥体,其中含有氧和碳基,有助于其再活性和潜在的生物活动.乙基氧组和苯乙基细胞的存在表明它可能具有有趣的药理特性,可能与自然产品的结构相似性有关.由(R)和(S)配置表示的立体化学化学学表明,该化合物可能在生物系统中有特定的相互作用,影响其功效和安全特征.此外,该化合物的溶解性,稳定性和再活性可受到其功能组的影响,使其成为在医药和相关领域进行进一步研究的候选对象.
- 英文名称Goniodiol 7-Monoacetate
- 中文名称7-乙酸房角二醇酯
- 其它别名2H-Pyran-2-one,6-[1-(acetyloxy)-2-hydroxy-2-phenylethyl]-5,6-dihydro-, [6S-[6R*(1R*,2R*)]]-; (+)-Goniodiol 7-acetate; (+)-Goniodiol monoacetate; 7-Acetylgoniodiol; Goniodiol 7-acetate; Goniodiol monoacetate
- CAS编号96422-53-6
- MFCD编号:MFCD23103605
- 分子式:C15H16O5分子量:276.28
- 产品CID: 2017374
- 产品分类天然产物 → 酚类
MSDS等安全信息
上下游产品
acetic anhydride (6S,7S,8S)-(-)-goniodiol goniodiol diacetate (1R,2R)-1-phenyl-but-3-ene-1,2-diol goniodiol diacetate goniotriol triacetate 7,8-di-O-acetyl-goniodiol合成工艺路线路线简述
- 473980-95-9 = 96422-53-6
反应条件:1.1 Reagents: Triethylamine Catalysts: 4-(Dimethylamino)Pyridine1.2 Reagents: Tetrabutylammonium Fluoride Solvents: Tetrahydrofuran
标题:A Short And General Approach To The Synthesis Of Styryllactones: (+)-Goniodiol,Its Acetates And β-Trifluoromethyl Derivative,(+)-7-Epi-Goniodiol And (+)-9-Deoxygoniopypyrone
作者:Chen,Jian; Lin,Guo-Qiang; Wang,Zhi-Min; Liu,Han-Quan
参考文献:Synlett 日期:2002 卷标:(8) 页码:1265-1268]
= 96422-53-6 [标题:Reaction Conditions
标题:Enantioselective Synthesis Of (+)-Goniodiol And Of Its Naturally Occurring Acetylated Analogs
作者:Surivet,Jean-Philippe; Gore,Jacques; Vatele,Jean-Michel
参考文献:Tetrahedron 日期:1996 卷标:52(47) 页码:14877-14890
📜(1R,2R)-1-Phenylbut-3-Ene-1,2-Diol置于双(乙腈)氯化钯(II) 4-二甲氨基吡啶,Ad-Mix-β,四丁基氟化铵,4-甲基苯磺酸吡啶,三乙胺体系中,用 四氢呋喃,二氯甲烷,水,N,N-二甲基甲酰胺,甲苯 作为反应溶剂,化学反应 26.0H,反应生成 7-乙酸房角二醇酯
参考文献:A Short And General Approach To The Synthesis Of Styryllactones:(+)-Goniodiol,Its Acetates And β-Trifluoromethyl Derivative,(+)-7-Epi-Goniodiol And (+)-9-Deoxygoniopypyrone
标题:A Short And General Approach To The Synthesis Of Styryllactones:(+)-Goniodiol,Its Acetates And β-Trifluoromethyl Derivative,(+)-7-Epi-Goniodiol And (+)-9-Deoxygoniopypyrone
摘要:(+)-Goniodiol 及其醋酸盐和δ-三氟甲基衍生物,(+)-7-Epi-Goniodiol 和 (+)-9-Deoxygoniopypyrone 是苯乙烯内酯的代表,这些化合物已通过简短而通用的方法合成.关键步骤包括环状烯丙基碳酸酯与乙烯基三丁基锡的区域选择性不对称二羟基化和钯催化交叉耦合.
DOI:10.1055/s-2002-32977
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2902600000-乙苯
2905122000-异丙醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Enantioselective Synthesis Of (+)-Goniodiol And Of Its Naturally Occurring Acetylated Analogs作者:Jean-Philippe Surivet,Jacques Goré,Jean-Michel Vatèle |发布日期:1996.11
摘要:A Novel Route To Enantioenriched (+)-Goniodiol And Its Natural Acetylated Derivatives, Potent Cytotoxic Compounds, Is Described. The Main Features Of This Synthesis Are Transfer Of The Asymmetric Information Of The Scalemic Allenic Alcohol 5 To The α- And β- Carbons Through Highly Diastereoselective Reactions And Introduction Of The α,β-Unsaturated Lactone Moiety By The Ghosez' Methodology.
合成参考文献
参考文献:10.1016/0031-9422(88)84116-5
摘要:Talapatra SK, Basu D, Chattopadhyay P, Talapatra B. Aristololactams of Goniothalamus sesquipedalis wall. Revised structures of the 2-oxygenated aristololactams. Phytochemistry. 1988 Jan;27(3):903–6. doi: 10.1016/0031-9422(88)84116-5.
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